Release of hexachlorocyclohexanes from historically and freshly contaminated soils in China: implications for fate and regulation

Hexachlorocyclohexanes (HCHs) were produced and used in large quantity worldwide and are common soil pollutants. In this study, desorption of α-HCH and γ-HCH from two soil samples collected from a historical pesticide plant in Tianjin, China, was examined. As a comparison, desorption of freshly sorbed γ-HCH was examined, using five typical Chinese soils. Strong resistant desorption was observed for both historically contaminated and freshly contaminated soils, and desorption results were well modeled with a biphasic desorption isotherm. The unique thermodynamic characteristics associated with the desorption-resistant fraction indicated that physical constraint within soil organic matrices was likely the predominant mechanism controlling resistant desorption. Resistant desorption could have significant effects on fate and exposure of HCHs in soil environment. More accurate biphasic desorption models that take into account of the resistant desorption can be used to facilitate regulating, management and remediation of HCH-contaminated sites.     

THE EFFECTS OF CLIMATE CHANGE AND IRRIGATION ON CRITERION LOW STREAMFLOWS USED FOR DETERMINING TOTAL MAXIMUM DAILY LOADS1

ABSTRACT: This paper addresses the possible impacts of global climate change on low streamflows in the Midwest, both directly, through lower precipitation, and indirectly, by rendering irrigation profitable in areas where it has found little application in the past. In the analysis presented here, streamflow data are altered to represent the effect of climate change and stream-supplied irrigation, and then used to estimate new values for two low-flow criteria, the one- and seven-day-ten-year low flows (₇Q₁₀ and ₁Q₁₀) under 20 climate change and irrigation scenarios. Additionally, the frequencies of violation of these two criteria, and multiple violations in a three-year period, are determined. Results show that the potential impact of the assumed climate change scenarios on low flow standards is substantial. A 25 percent decrease in mean precipitation results in a 63 percent reduction in design flow, even in the absence of irrigation. With irrigation, the reduction can be as much as 100 percent. The frequency of single violations of low flow criteria is found to increase several fold with irrigation. The frequency of multiple violations of low flow criteria in a three-year period is sensitive to climate change, increasing from around 20 percent to nearly 100 percent as the climate change becomes more severe.     

物联网感知安全应用的研究与展望

为拓展物联网行业应用、加快发展中国物联网产业,基于提前感知,超前防范对安全科学与工程的重要性,介绍物联网感知安全应用的研究现状,深入分析物联网感知安全行业应用所需要的关键技术和研究方向;在分析国内外物联网发展路径的差异、现有标准及新标准制定的基础上,研究顶层设计、资源部署、应用标准建设等感知安全应用系统建设亟待解决的问题;提出物联网应用示范研究的内容、目标;提出在公共安全和安全生产领域应用物联网技术,对防范重特大事故、安全监管、事故应急救援的重要现实意义。     

小型焦炉废气和废水处理方法

焦炉装煤和推焦烟气合用 1套收集系统。除尘废水经吸附后用于熄焦 ,熄焦水经吸附后用于湿式除尘 ,实现循环零排放。煤气洗涤水循环为废水中氨氮的处理提供了可行的方法     

Maximum permissible and negligible concentrations for some organic substances and pesticides

The aim of the paper is to provide interested parties the methods that were used for generic hazard assessment in The Netherlands, and the resulting so-called maximum permissible concentrations (MPCs) and the negligible concentrations (NCs) for approximately 150 organic substances and pesticides. The MPCs and NCs were derived for water, sediment, and soil. The concentration in the environment above which the risk of adverse effects was considered unacceptable to ecosystems is called the MPC. The MPCs take into account that the substances are distributed among the different environmental compartments, and are harmonized accordingly. The MPCs served as a basis for the Dutch government to set generic environmental quality standards (EQS) in The Netherlands (IWINS,[15]). EQS in turn are used by the Dutch Government to assess the environmental quality and for other environmental policy purposes. Concentrations in the environment below which the occurrence of adverse effects is considered to be negligible are called NCs. Hazards must be reduced when the environmental concentration of a substance exceeds its MPC. In-between this limits reduction of hazards is preferable. The MPC is a scientifically derived hazard limit. The NC is simply defined as 1% of the MPC. In general, there is a great demand for ecotoxicological data that currently limits a more reliable estimate of many MPCs. For water, approximately half of the MPCs are derived on the basis of four or more NOECs (no observed effect concentrations). For the other half, MPCs are based on only a few chronic or acute tests. For soil and sediment, however, almost no ecotoxicological data are available, and MPCs for those compartments have, in many cases, been derived from MPCs in water applying the equilibrium partitioning method (EqP-method), resulting in MPCs with greater uncertainty. Some of the methods and underlying assumptions that have been used may need improvement. For example, the factor between MPC and NC, the statistical extrapolation method, the method that is used for secondary poisoning, the role of the background concentrations of ‘naturally’ occurring substances, and the bioavailability and the EqP-method. There is a great need for hazard limits, and the present compilation tries to provide those as well as identifying research gaps.     

Control strategies for vehicular NOx emissions in Guangzhou, China

Guangzhou is a city in southern China that has experienced very rapid economic development in recent years. The city's air has very high concentrations of various pollutants, including sulphur dioxide (SO₂), oxides of nitrogen (NOx), ozone (O₃) and particulate. This paper reviews the changes in air quality in the city over the past 15 years, and notes that a serious vehicular-related emissions problem has been superimposed on the traditional coal-burning problem evident in most Chinese cities. As NOx concentrations have increased, oxidants and photochemical smog now interact with the traditional SO₂ and particulate pollutants, leading to increased health risks and other environmental concerns.
Any responsible NOx control strategy for the city must include vehicle emission control measures. This paper reviews control strategies designed to abate vehicle emissions to fulfill the city's air quality improvement target in 2010. A cost-effectiveness analysis suggests that, while NOx emission control is expensive, vehicular emission standards could achieve a relatively sizable emissions reduction at reasonable cost. To achieve the 2010 air quality target of NOx, advanced implementation of EURO3 standards is recommended, substituting for the EURO2 currently envisioned in the national regulations. Related technical options, including fuel quality improvements and inspection/maintenance (I/M) upgrades (ASM or IM240), are assessed as well.     

Environmental regulation: A new approach

Environmental regulations traditionally have been developed to limit pollution emitted to a single environmental medium at a time. This approach has been followed for a variety of reasons—political, legal, and informational, to name a few. However, more efficient environmental management could be achieved if environmental standards were issued simultaneously across all media. In this way multimedia pollutant tradeoffs could be utilized and regulatory uncertainty could be reduced.     

Regional reference sites: a method for assessing stream potentials

Field assessments of impacted streams require a control or at least an unbiased estimate of attainable conditions. Control sites, such as upstream/downstream or wilderness sites, have proven inadequate for assessing attainable ecological conditions where the control streams differ naturally from the impacted streams to a considerable degree or where different disturbances exist than those being studied. Relatively undisturbed reference sites with watersheds in areas having the same land-surface form, soil, potential natural vegetation, and land use as are predominant in large, relatively homogeneous regions are suggested as alternative control sites. These areas are considered typical of the region and therefore the sites also are considered typical of the region because their watersheds exhibit all the terrestrial variables that make that region a region. The logical basis for developing regional reference sites lies in the ability to group watersheds and common stream types into regions by integrating available maps of terrestrial variables that influence streams. Relatively undisturbed reference sites can be selected from typical areas of the regions and from transition zones where one or two of the terrestrial variables are not the predominant one(s) of the region. These reference sites are useful for estimating attainable conditions, for evaluating temporal and spatial changes in ecological integrity, for classifying attainable uses of streams, and for setting biological and environmental criteria.     

Ambient air quality standards in China

China recently announced ambient air quality standards. This article describes the standards and compares them with standards that exist in the Federal Republic of Germany, Japan, and the United States. An unusual feature of the Chinese standards is the establishment of different classes of standards, applicable in different types of areas. The present status of air pollution in several Chinese cities is examined. Data on the levels of suspended particulates, sulfur dioxide, and carbon monoxide in several Chinese cities are presented. Some of the difficulties involved in implementing the new standards are discussed.Work undertaken while at the Environment and Policy Institute, East-West Center, and School of Public Health, University of Hawaii, Manoa, Honolulu, HI 96822, USA.     

工业废水达标排放管理模式探讨

本文阐述了工业废水达标排放的重要意义,分析了工业废水达标排放的可能性,并提出改革污水处理运作模式的几点建议,对实现“一控双达标”月标具有一定的指导意义。