存在多种化学有害物质作业场所危害性评价

作业场所同时存在多种化学有害物质的情形并不少见,如何对这类作业场所的危害性进行科学合理的综合评价是一个重要的课题。本文针对这类作业场所提出了一种简便可行的危害性评价方法,该方法以危害物质自身的危害特性如毒性、危害器官、吸收途径、致癌性和检测浓度为评价依据,较全面地反应了有害物质的危害性,对同时存在多种化学有害物质的作业场所的危害性评价与职业危害治理具有一定的现实意义。     

离子色谱分析法用于化学防护服材料渗透性能检测的研究

渗透性能是化学防护服最重要的防护性能指标之一。本文采用PTC200型渗透测试池、蠕动泵、超滤装置和离子色谱分析仪,构建了测试化学防护服渗透性能的装置,并利用该装置对一系列化学防护服面料对浓硫酸和NaOH溶液的渗透性能进行了检测。结果表明,利用该装置可以方便准确地实现服装面料渗透性能测试,是一种具有重要应用价值的检测方法。该方法的开发为规范我们国家化学防护服装及相关产品防护性能检测方式,提高检测结果的准确度和一致性,具有重要的意义。     

油码头、液体化学品码头安全风险问题的探讨

本文讨论了油码头与液体化学品码头选址、油码头总平面布置、码头管线腐蚀、港口运营风险标准与风险评估方法等问题,提出了相应的对策措施。     

职业危害因素混合接触综合评价方法概述

作业场所同时接触多种职业危害因素的综合危害性日益引起广泛关注,如何对其进行科学的评价成为职业危害研究者面临的重要课题。本文对不同危害因素的混合危害作用的评价方法进行了系统的总结与归纳,探讨了混合作用的描述方法,分析了毒理学、流行病学、风险评价三大类方法应用于混合危害作用评价时的基本原理、核心思路和实施流程,此外对三种方法的特点进行了对比分析。     

植物油烟组分的色质联机分析

将植物油烟采集在玻璃纤维滤筒中 ,用环己烷处理样品 ,样品经过净化处理 ,然后进行色质联机分析。对油烟化学成分的分析有助于人们研究油烟对人体健康的影响     

气溶胶中有机物的研究进展和前景

首先指出了气溶胶中有机物的研究意义 ,接着介绍了目前对气溶胶中有机物的化学组成、来源和成因、环境和健康效应的认识 ,综述了分析测试方法的研究现状 ,并评述了其研究前景     

Alternative soil quality indices for evaluating the effect of intensive cropping, fertilisation and manuring for 31 years in the semi-arid soils of India

Soil quality assessment provides a tool for evaluating the sustainability of alternative soil management practices. Our objective was to develop the most sensitive soil quality index for evaluating fertilizer, farm yard manure (FYM), and crop management practices on a semiarid Inceptisol in India. Soil indicators and crop yield data from a long-term (31 years) fertilizer, manure, and crop rotation (maize, wheat, cowpea, pearl millet) study at the Indian Agricultural Research Institute (IARI) near New Delhi were used. Plots receiving optimum NPK, super optimum NPK and optimum NPK + FYM had better values for all the parameters analyzed. Biological, chemical, and physical soil quality indicator data were transformed into scores (0 to 1) using both linear and non-linear scoring functions, and combined into soil quality indices using unscreened transformations, regression equation, or principal component analysis (PCA). Long-term application of optimum inorganic fertilizers (NPK) resulted in higher soil quality ratings for all methods, although the highest values were obtained for treatment, which included FYM. Correlations between wheat (Triticum aestivum L.) yield and the various soil quality indices showed the best relationship (highest r) between yield and a PCA-derived SQI. Differences in SQI values suggest that the control (no NPK, no manure) and N only treatments were degrading, while soils receiving animal manure (FYM) or super optimum NPK fertilizer had the best soil quality, respectively. Lower ratings associated with the N only and NP treatments suggest that one of the most common soil management practices in India may not be sustainable. A framework for soil quality assessment is proposed.     

Factor analysis and linear regression model (LRM) of metal speciation and physico-chemical characters of groundwater samples

An approach is described for viewing the interrelationship between different variables and also tracing the sources of pollution of groundwater of north Chennai (India). The data set of 43 variables which include major ions, minor ions and trace metal speciation (Cu, Pb, Cd and Zn) collected during the pre-monsoon and post-monsoon seasons of the year 2000–2001, was subjected to R-mode factor analysis to comprehend the distribution pattern of the said variables. It was found that first factor measures salinity and hardness which explained 19.12% of the total variance (comprised of variables EC, TDS, Na⁺, K⁺, Ca²⁺, Mg²⁺, total hardness, Cl⁻ and SO₄ ²⁻) during pre-monsoon, while it was 25.08% during post-monsoon. The second and third factors were attributed to speciation of zinc and copper ions during both pre-monsoon and post-monsoon. Although there were two more factors, loaded with speciation parameters of lead and cadmium, the variance of them were less than 10%. From this study it is seen that sea water intrusion, municipal solid waste disposal are the identified sources of component of pollution. The importance of metal ions is taking a secondary role and the anthropogenic origin-industrial activity, is the reason in the evaluation of pollution status as they come in the second, third, fourth and fifth factors. As the trace metal speciation was grouped in separate factors, linear regression model (LRM) with correlation analysis was applied to check its validity for prediction of speciation and to apply LRM for rapid monitoring of water pollution.     

洞庭湖湿地稻区化肥环境影响评估

研究采用时间序列分析法,预测洞庭湖区2010年2、020年人口将分别达到1 396.38×104人、1 492.31×104人,稻谷总需求量分别为5 002.17×103t,5 284.79×103t,化肥投入实物量将分别为1 466.91×103t,1 549.79×103t。在总结国内外化肥投入影响环境研究基础上建立了化肥环境影响评估模型,预计2010,2020年洞庭湖区区水稻生产因化肥带来环境成本将分别达到2.2×108元、2.32×108元,占稻谷销售效益的3.4%和3.13%,稻田生态系统和社会将难以承受,建议政府在化肥过量施用的地区征收化肥环境税。     

Detailed and reduced chemistry for hydrogen autoignition

Reaction-rate parameters are given for the detailed chemistry of gas-phase hydrogen combustion, involving 21 reversible elementary steps. It is indicated that, when attention is restricted to specific combustion processes and particular conditions of interest, fewer elementary steps are needed. In particular, for calculating autoignition times over a wide range of pressures for temperatures between about 1000 and 2000 K, five irreversible elementary steps suffice, yielding a remarkable reduction in complexity. It is explained that, from a mathematical viewpoint, in terms of global reaction-kinetic mechanisms, the hydrogen–oxygen system in principle comprises only six overall steps. Rational reduced chemical mechanisms for hydrogen combustion therefore necessarily must have fewer than six overall steps. For autoignition over the range of conditions specified above, ignition times can be determined accurately by considering, in addition to an elementary initiation step and an elementary termination step, at most three overall steps for reaction intermediaries, which reduce to two for very fuel-lean conditions and to one for stoichiometric or fuel-rich conditions. The resulting reductions can simplify computations that need to be performed in risk analyses for hydrogen storage and utilization.