La/Fe共掺杂TiO2纳米管阵列光催化降解制糖废水

利用阳极氧化法在0.5％(质量分数)HF电解液中20V电压下,对抛光处理过的钛片进行阳极氧化20 min,制得有序的TiO2纳米管阵列.同时,以甲基橙为目标降解物,20 W紫外灯(λ=253.7 nm)为光源,探讨了制备La/Fe掺杂TiO2纳米管阵列的最优工艺条件,并利用SEM、XRD对La/Fe掺杂前后TiO2纳米...     

Effects of oxygen and water content on microbial distribution in the polyurethane foam cubes of a biofilter for SO2 removal

The performance of a biofilter for off-gas treatment relies on the activity of microorganisms and adequate O_2 and H_2O. In present study, a microelectrode was applied to analyze O_2 in polyurethane foam cubes(PUFCs) packed in a biofilter for SO_2 removal. The O_2 distribution varied with the density and water-containing rate(WCR) of PUFCs. The O_2 concentration dropped sharply from 10.2 to 0.8 mg/L from the surface to the center of a PUFC with 97.20%of WCR. The PUFCs with high WCR presented aerobic–anoxic–aerobic areas.Three-dimensional simulated images demonstrated that the structure of PUFCs with high WCR consisted of an aerobic "shell" and an anoxic "core", with high-density PUFCs featuring a larger anoxic area than low-density PUFCs. Moreover, the H_2O distribution in the PUFC was uneven and affected the O_2 concentration. Whereas aerobic bacteria were observed in the PUFC surface, facultative anaerobic microorganisms were found at the PUFC core, where the O_2 concentration was relatively low. O_2 and H_2O distributions differed in the PUFCs, and the distribution of microorganisms varied accordingly.     

沈阳市环境空气质量数据接收及监控系统的设计与应用

介绍了环境空气质量数据接收与监控系统的设计与功能。该系统能够适应不同的通讯方式,解决了偏远地区数据传输问题。     

地面运动最大幅值、到时的差动特性

利用ＳＭＡＲＴ－１台阵３次地震的水平分量加速度记录统计了局部场地上地震动加速度最大幅值、到时的变化特性。统计结果表明：在局部场地上，地震动加速度的最大幅值随土层厚度和测点坐标的变化是显著的，而到时变化仅依赖于测点坐标     

Optimization of a novel process for the ozonolysis of 2, 4‐dichlorophenol

An innovative process was studied for the destruction of 2,4‐dichlorophenol in water. The immiscible fluorinated solvent, inert and highly ozone soluble, was used as the solvent in the extraction‐ozonation system. Taguchi methods were applied in the design of experiments to identify the significant factors and establish the optimal combination of process parameters. The result indicate that this statistical technique can provide an extremely effective structured approach.     

固相萃取-超高效液相色谱法检测地表水中7种氯酚类化合物

建立了一种能够测定地表水中7种氯酚类化合物的固相萃取-超高效液相色谱方法。调节水样p H=2,经固相萃取柱富集后,用丙酮和二氯甲烷洗脱,浓缩定容后分析。以甲醇-水溶液(含0.2%乙酸)为流动相,柱温为30℃,紫外检测波长为分段检测(285、290、300、304 nm)。结果表明,检测方法对7种氯酚类化合物具有良好的线性相关性,相关系数≥0.999 7。当水样萃取体积为1 L,浓缩至1 m L,进样量为5μL时,方法检出限为12.7~32.1 ng/L,测定下限为50.8~128.4 ng/L;高低两组浓度的平均加标回收率为79.2%~108.4%,相对标准偏差为4.6%~13.3%。     

基于BP神经网络的污水格栅间气体监测

为实现对城市污水泵站格栅间内H₂S和CO有害气体浓度实时准确监测分析,设计气体传感器阵列监测系统,建立单隐层BP神经网络模型对气体浓度样本进行训练,确定网络隐含层数为9,训练函数为traindm,模型优化后输出的H₂S和CO气体浓度与实测值的平均相对误差分别为1.3%与0.4%。研究结果表明：采用BP神经网络模型对传感器阵列采集到的样本数据进行训练,可提高其测量精度,提升精度范围在57%～75%之间,能够满足对污水泵站有害气体监测的基本要求,所建立模型表现出良好效果。研究结果可为污水格栅间有害气体监测提供新方法。     

特丁硫磷原药生产废水的治理

针对特丁硫磷原药生产废水特点，提出了采用萃取-氧化-铝盐沉降法治理方案．并进行效益分析，结果表明，该治理方案具有良好的经济效益，社会效益和环境效益。     

我国典型制药厂污染场地中抗生素的污染特征及生态风险

为了解制药厂污染场地中抗生素的污染特征和生态风险，选取南、北方两个典型抗生素制药厂，采集表层土、土壤柱、工艺水、地下水和药渣等样品，采用超声提取-固相萃取-高效液相色谱串联质谱技术对87 种常见抗生素进行定量分析.结果显示，所有类型样品中共检出5类31 种抗生素，各采样点总抗生素在表层土、土壤柱、药渣中的含量最大值以及工艺水、地下水中的浓度最大值分别为420 ng·g^-1、595 ng·g^-1、139 ng·g^-1以及1 151 ng·L^-1、6.65 ng·L^-1；大部分抗生素赋存于表层土，随土壤柱深度呈现向下递减规律.生态风险评价表明，磺胺二甲嘧啶、磺胺喹喔啉、四环素、氯四环素和D-山梨醇等存在较高风险.提高制药废水中抗生素去除效率，预防生产车间泄漏，是控制制药厂抗生素向场地内及周边环境污染的有效手段.