电捕法在炭素焙烧炉烟气净化中的应用

针对炭素焙烧炉的烟气特点,采用雾化水预处理和电捕焦油技术,对炭素厂焙烧炉烟气进行治理,达到高效净化有害气体—沥青烟的目的。     

污泥水煤浆在3.2MW卧式锅炉中的燃烧特性研究

在3.2MW卧式炉中对污泥水煤浆和大同烟煤水煤浆进行对比燃烧试验,研究了煤浆的着火、温度场及燃烧效率等特性,并考察了污泥水煤浆工业应用的可行性.结果表明,掺混10%污泥的水煤浆着火容易,炉膛主燃烧区域火焰温度可达到1200～1300℃;污泥水煤浆燃烧时炉膛火焰分布均匀,火焰充满度较好;水分析出使颗粒表面分布大量气孔,有...     

钢铁渣粉对混凝土中钢筋的保护作用

钢渣和矿渣是冶炼钢、铁过程中产生的固体废物.由于其矿物组成与水泥熟料相似,具有水硬胶凝性能,所以被用作混凝土掺合料.钢铁渣粉是钢渣粉和矿渣粉接一定的比例混合而成的.试验表明,钢铁渣粉的使用能够保留钢渣粉和矿渣粉单掺时的优点,弥补单掺时的缺点,对钢筋起到很好的保护作用.     

高炉风口漏损分析与控制措施探讨

本文通过分析高炉风口损坏的形式和原因,探讨了目前常用的风口检漏技术和方法;根据高炉运行管理实践,介绍了风口漏损的主要表现形式,并针对风口的漏损程度提出了应采取的处理和维护措施,以及延长高炉风口寿命的建议性措施.     

Development of novel absorbents for CO2 capture from blast furnace gas

In order to establish energy-saving technology for CO₂ capture from blast furnace gas, novel absorbents were developed in the laboratory and evaluated at a 1 t_CO2/d test plant. At first, CO₂ absorption and desorption behaviors of single-component amine solvents for simulated blast furnace gas (CO₂/N₂ = 20%/80%) were investigated through a screening test using a small scrubbing bottle. These amine solvents were additionally analyzed using nuclear magnetic resonance (¹³C NMR) spectroscopy and reaction calorimetry. The results of the laboratory experiments showed that there was a trade-off between absorption rate and enthalpy of absorption but some absorbents had unique features. For example, 2-isopropylaminoethanol (IPAE) had high absorption rate and small enthalpy of absorption. Then, new IPAE-based amine solvents (RITE solvents: RITE-A and RITE-B) were formulated and evaluated at the 1 t_CO2/d test plant. CO₂ regeneration energies of the RITE solvents were 3.3 and 3.1 GJ/t_CO2, respectively. With certain process conditions and plant specifications optimized, RITE-B was estimated to have the potential to achieve 2.5 GJ/t_CO2.     

高炉矿渣对铝电解废旧阴极炭焚烧中氟化物的迁移转化行为影响

废旧阴极炭（Spent potlining）是铝电解行业产生的一种高无机氟含量危险废物.本研究以高炉矿渣（Blast furnace slag）为添加剂与废旧阴极炭混合焚烧,模拟计算有关反应的吉布斯自由能,研究焚烧过程中氟化物的转化和稳定化行为.结果表明,高炉矿渣中的钙基化合物可促进废旧阴极炭中的NaF和Na₃AlF₆转化为稳定的CaF₂. 在850 ℃、焚烧1 h的条件下,废旧阴极炭和高炉矿渣混合样（4/6,质量比）水溶性氟浸出率降低42.27%;同时,减少HF释放可使氟化物保留率提高3.85%.高炉矿渣的掺入将其中93.50%的氟化物固定于底渣中,显著降低了废旧阴极炭的浸出毒性.高炉矿渣中的SiO₂和Al₂O₃促进了NaF向CaF₂的热转化行为,高炉矿渣参与焚烧使得焚烧底渣颗粒更加疏松、分散,底渣的 氟化物主要以Ca₄Si₂O₇F₂形态存在,表明高炉矿渣具有协同处置废旧阴极炭的良好性能.     

炉内配风方式对锅炉燃烧特性影响的数值模拟

为了了解不同配风工况对煤粉燃烧过程的影响,本文以四角切圆燃烧煤粉锅炉为研究对象,采用k-ε-f-g即混即燃气相燃烧模型与煤的双挥发反应热解模型对不同工况下炉内流动、燃烧等过程进行了数值模拟。其结果表明：当机组负荷一定时,适当减少一次风率使整个炉膛火焰充满度大大得到改善,火焰长度与煤粉着火距离有所缩短;采用倒宝塔型二次风配风方式对于较差煤种的稳定着火较为有利;而停止三次风时,炉膛温度水平较高,煤粉燃烧完全,锅炉效率有所提高。     

探索气井生产过程中水套炉的节能化改造

水套炉是天然气开采、加工和运输过程中避免水合物形成的一种常见设备。现场水套炉应用过程中,往往会片面的认为水套炉温度越高越利于防治水合物生成。通过对某气井流体流程和水套炉自用系统进行分析后发现,过高的水套炉的温度会导致分离器分离效果变差,从而导致水套炉自用气含水量增多,由于自由水增多,在相同压力降下,更容易形成水合物,造成管线堵塞。通过在水套炉出1：7处增加一个针型阀或者调压切断阀,可最大限度地利用水套炉对气流的加热温度,达到控制水合物生成和降低水套炉能耗的目的。     

Synthesis of TiO2 visible light catalysts with controllable crystalline phase and morphology from Ti-bearing electric arc furnace molten slag

TiO₂ visible light catalysts with different crystalline phases and morphologies were synthesized from titanium-bearing electric arc furnace molten slag (Ti-bearing EAF slag) by using a simple acidolysis process. The effects of the pH of the HCl solution, liquid to solid ratio (R_L/S, HCl solution to the residue ratio, mL/g) and acidolysis time on the micro-morphology and crystalline phase of as-prepared TiO₂ photocatalysts were systematically investigated. The results indicated that with decreasing pH in the HCl solution and increasing R_L/S, the crystalline phase and micro-morphology of the obtained TiO₂ nanostructures tended to transform from anatase type TiO₂ with spherical nanoparticle structures to rutile type TiO₂ with needle-like nanorod structures. The acidolysis time had little influence on the crystalline phase but great impact on the size of the obtained TiO₂. The growth mechanism of TiO₂ from Ti-bearing EAF slag during the acidolysis process was also discussed. In addition, the influence of R_L/S on the photocatalytic properties of the synthesized nanostructured TiO₂ was studied. The results showed that the photodegradation efficiency for Rhodamine B solution could reach 91.00% in 120 min when the R_L/S was controlled at 50:1.     

Stimulatory e ects of biosurfactant produced by Pseudomonas aeruginosa BSZ-07 on rice straw decomposing

Biosurfactant,produced by Pseudomonas aeruginosa BSZ-07,was added to the dee straw decomposing process to enhance the production of reducing sugars.Observed by Fourier Transform InfraRed(FT-IR)and Nuclear Magnetic Resonance(NMR)analysis, the purified biosurfactant was considered as a mixture of RL1 and RL2,which are two different types of rhamnolipids.Two different adding methods,adding the purified rhamnolipid and the on-site production of it were compared.The results showed that 0.5 g/L was the optimum...