氯离子对COD测定影响的探讨

研究含有高氯离子样品COD的测定,发现其中的白色沉淀为AgCl。实验结果证明,按照标准方法,当取样体积为20 mL时,按0.4 g HgSO4络合2 000 mg/L Cl-的比例投加掩蔽Cl-可以取得理想的效果。     

突发性灾难重大事件后公众对心理服务的认知和需求

为分析突发性灾难重大事件发生后公众对心理服务的认知和需求现状,采用随机抽样的方法在全国范围内抽取458名群众作为被试,使用“突发性灾难重大事件后公众心理服务认知和需求”调查问卷进行调查。结果显示:①不同性别人群、不同年龄阶段人群对“突发性灾难重大事件后心理服务”的认知存在显著差异(X^2=9.82,p<0.05;X^2=33.99,p<0.05)。②不同年龄阶段的人群对民众开展心理服务的必要性态度存在显著差异(X^2=15.84,p<0.05)。不同文化程度人群、不同性别人群对突发性灾难重大事件后心理服务活动的参与意愿存在显著差异(X^2=7.20,p<0.05;X^2=6.78,p<0.05)。③不同文化程度人群对心理服务知识和技能需求存在显著差异(X^2=28.65,p<0.05),在接受心理服务场所的选择上也存在显著差异(X^2=16.44,p<0.05)。不同年龄阶段人群对接受心理服务场所的选择上存在显著差异(X^2=21.52,p<0.05)。分析结果显示:在遭受突发性灾难重大事件时,公众对心理服务的了解程度一般,但参与意愿和需求强烈,因此,国家和社会应加快社会心理服务体系的建设,促进公众的心理健康。     

Syntrophic co-culture of Bacillus subtilis and Klebsiella pneumonia for degradation of kraft lignin discharged from rayon grade pulp industry

In order to search the degradability of kraft lignin, the potential bacterial strains Bacillus subtilis (GU193980) and Klebsiella pneumoniae (GU193981) were isolated, screened and applied in axenic and co-culture conditions. Results revealed that mixed culture showed better decolorization efficiency (80%) and reduction of pollution parameters (COD 73% and BOD 62%) than axenic culture. This indicated syntrophic growth of these two bacteria rather than any antagonistic effect. The HPLC analysis of degraded samples of kraft lignin has shown the reduction in peak area compared to control, suggesting that decrease in color intensity might be largely attributed to the degradation of lignin by isolated bacteria. Further, the GC–MS analysis showed that most of the compounds detected in control were diminished after bacterial treatment. Further, the seed germination test using Phaseolus aureus has supported the detoxification of bacterial decolorized kraft lignin for environmental safety. All these observations have revealed that the developed bacterial co-culture was capable for the effective degradation and decolorization of lignin containing rayon grade pulp mill wastewater for environmental safety.     

人工湿地氮转化与氧关系研究

应用N转化迁移模型分析廊道式人工湿地氮转化与氧供应的关系,验证目前湿地全程硝化反硝化脱氮机制的有效性.对各个廊道进出水NH₄⁺-N、NO₃^--N、TN、B₅、DO进行了测定和分析.在水力负荷5cm/d条件下,各廊道湿地有机氮矿化率为0.01～0.28g·(m²·d)^-1、氨氮硝化率0.50～1.54 g·(m²·d)^-1,反硝化率0.41～1.13 g·(m²·d)^-1(占总氮损失的3.4%～35.4%)、植物净吸收氮0.07～0.26 g·(m²·d)^-1(占总氮损失的7%～33%).硝化反硝化与有机质降解同时进行,在进水端最明显,这与传统认识相悖.按照全程硝化化学计量学得到的硝化需氧量(NOD)高于实际的表面复氧和植物根系放氧.最后对在高浓度有机质存在条件下,能减少对氧需求的2种新型脱氮机制进行了讨论.     

Mitigation of CO2 Emissions from the EU-15 Building Stock. Beyond the EU Directive on the Energy Performance of Buildings (9 pp)

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Goal Scope and Background. The European Directive on Energy Performance of Buildings which came into force 16 December 2002 will be implemented in the legislation of Member States by 4 January 2006. In addition to the aim of improving the overall energy efficiency of new buildings, large existing buildings will become a target for improvement, as soon as they undergo significant renovation. The building sector is responsible for about 40% of Europe's total end energy consumption and hence this Directive is an important step for the European Union in order that it should reach the level of saving required by the Kyoto Agreement. In this the EU is committed to reduce CO2 emissions relative to the base year of 1990 by 8 per cent, by 2010. But what will be the impact of the new Directive, how large could be the impacts of extending the obligation for energy efficiency retrofitting towards smaller buildings? Can improvement of the insulation offset or reduce the growing energy consumption from the increasing installation of cooling installations? EURIMA, the European Insulation Manufacturers Association and EuroACE, the European Alliance of Companies for Energy Efficiency in Buildings, asked Ecofys to address these questions.

Methods

The effect of the EPB Directive on the emissions associated with the heating energy consumption of the total EU 15 building stock has been examined in a model calculation, using the Built Environment Analysis Model (BEAM), which was developed by Ecofys to investigate energy saving measures in the building stock. The great complexity of the EU-15 building stock had to be simplified by examining five standard buildings with eight insulation standards, which are assigned to building age and renovation status. Furthermore, three climatic regions (cold, moderate, warm) were distinguished for the calculation of the heating energy demand. This gave a basic 210 building types for which the heating energy demand and CO2 emissions from heating were calculated according to the principles of the European Norm EN 832.

Results and Discussion

The model calculations demonstrates that the main contributor to the total heating related CO2 emissions of 725 Mt/a from the EU building stock in 2002 is the residential sector (77%) while the remaining 23% originates from non-residential buildings. In the residential sector, single-family houses represent the largest group responsible for 60% of the total CO2 emissions equivalent to 435 Mt/a.

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- The technical potential: If all retrofit measures in the scope of the Directive were realised immediately for the complete residential and non-residential building stock the overall CO2 emission savings would add up to 82 Mt/a. An additional saving potential compared to the Directive of 69 Mt/a would be created if the scope of the Directive was extended to cover retrofit measures in multi-family dwellings (200-1000m2) and non-residential buildings smaller than 1000m2 used floor space. In addition including the large group of single-family dwellings would lead to a potential for additional CO2 emission reductions compared to the Directive of 316 Mt/a.

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- Temporal mobilization of the potential: Calculations based on the building stock as it develops over time with average retrofit rates demonstrated that regulations introduced following the EPB Directive result in a CO2 emissions decrease of 34 Mt/a by the year 2010 compared to the business as usual scenario. Extending the scope of the EPB Directive to all residential buildings (including single and multi-family dwellings), the CO2 emission savings potential over the 'business as usual' scenario could be doubled to 69 Mt/a in the year 2010. This creates an additional saving potential compared to the Directive of 36 Mt/a.

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- Cooling demand: The analysis demonstrated that in warm climatic zones the cooling demand can be reduced drastically by a combination of lowering the internal heat loads and by improved insulation. With the reduction of the heat loads to a moderate level the cooling demand, e.g. of a terraced house located in Madrid, can be reduced by an additional 85% if the insulation level is improved appropriately.

Conclusions

This study demonstrates that the European Directive on Energy Performance of Buildings will have a significant impact on the CO2 emissions of the European building stock. The main saving potential lies in insulation of the existing building stock. Beyond this, CO2 emissions could, however, be greatly reduced if the scope of the Directive were to be extended to include retrofit of smaller buildings.

Recommendation and Perspective

The reductions should be seen in relation to the remaining gap of 190 Mt CO2 eq. per annum between the current emission levels of EU-15 and the target under the Kyoto-Protocol for the year 2010. The energy and industrial sector will probably contribute only a fraction of this reduction via the newly established EU emissions trading scheme and connected projects under the flexible mechanism. In addition, the traffic sector is likely to continue its growth path leading to a widening of the gap. Thus, there is likely to be considerable pressure on the EU building sector to contribute to the EU climate targets beyond what will be achieved by means of the current EPB Directive. Legislators on the EU and national level are therefore advised to take accelerated actions to tap the very significant emission reduction potentials available in the EU building stock.     

EVALUATING THE PERSISTENCE OF RESIDENTIAL WATER CONSERVATION: A 1992–1997 PANEL STUDY OF A WATER UTILITY PROGRAM IN DELAWARE1

This study systematically evaluates residential consumer responses to a utility conservation initiative based on an econometric analysis of a sample of 510 households served by Artesian Water Company, Inc. (New Castle County of Delaware). Using a panel study approach covering the period from 1992 to 1997, this study shows that Artesian's water conservation program has had statistically significant and persistent impacts on residential water consumption.     

Water Resource Potential in Northern India: Constraints and Analyses of Price and Non-Price Solutions

The paper examines the linkages between water depletion, continuous population growth and economic development viewed primarily as agricultural development. This is done within a framework of a dynamic simulation model of ecological-economic type over extended periods of time. It is found that intensive agriculture, driven by an increase in the cropping intensity as a result of increase in area under paddy crop, has led to an increased gap between the demand for and supply of water resources, in particular subsurface resources. The consequent fall in water table may lead to constraints in the use of water. This has strong inequity implications in the resource use as well as threats to future of agricultural development in the region. It is revealed that a mix of interventions based on price solutions, non-price solutions and institutional set up are decisive in bringing a sustainable development and use of resource. The paper concludes with emphasising the role of state/government in achieving the desired goal.     

ALTERNATIVE FUTURES USING THE WOLLMAN-BONEM MODELS1

Alternative futures are defined to be mutually consistent alternative combinations of assumed sets of future conditions. Alternative futures are employed in conjunction with the Wollman-Bonem model to project future water use. The model solutions under different alternative futures provide an indication of the direction and relative magnitude of changes in water use, both in quantity and quality, that may result from changes in policy-influenced variables, technology, and other data. The Wollman-Bonem model is employed in this paper as a tool to illustrate the alternative futures concept. The model can best be cast as an economic model. The model solutions are not given as a set of formal projections, but as various possible water-use-over-time curves. This should aid in disspelling the erroneous idea that it is possible to make distant projections of water use as a single curve. Multiple curves suggest that water use is really a function of many variables.     

APPLYING GRADIENT PROJECTION AND CONJUGATE GRADIENT TO THE OPTIMUM OPERATION OF RESERVOIRS1

The recent versions of nonlinear programming techniques such as the conjugate gradient and the gradient projection algorithms are used to obtain the optimal operating conditions of a multiple reservoirs system with multiple purposes. These algorithms are compared with other techniques in the literature. The conjugate gradient method incorporates the advantages of both the generalized Newton-Raphson, also known as the quasilinearization technique, and the gradient approach while avoiding their major drawbacks. To illustrate the technique, a water resources system with three reservoirs and a tabular objective function is solved by the two algorithms.     

RURAL RESIDENTIAL WATER DEMAND: AN ECONOMETRIC AND SIMULATION ANALYSIS1

ABSTRACT: This study proposes that demand management through pricing policies can be used in conjunction with supply management to solve water supply problems. Economic principles are shown to apply to rural residential water use. A demand function for water was developed based on cross-sectional water use data collected in Kentucky. Price was found to be a significant determinant of the quantity of water demanded. A constant price elasticity of -0.92 was found. The demand function was used in a simulation analysis to determine reservoir capacity needed to supply water needs of a rural community. The simulation revealed that price can significantly affect required reservoir storage.