CODcr测定中氯离子的影响及消除

根据油田采出水中氯离子含量高，对COD_(Cr)测定影响较大的特点，通过实验探讨高含氯对测定污水CODCr的影响及消除其影响的方法。实验结果表明，对高含氯、低CODCr的污水用国标方法测定CODCr时会产生较大误差，且误差随氯离子含量的增加而增大；采用不掩蔽氯离子测污水CODCr总量，再用CODCr总量减去氯离子产生CODCr量的方法，则能反映污水的真实CODCr值，误差小一些。     

Energy futures and green chemistry: competing for carbon

Global energy demand is expected to increase from the current 400 ExaJ per year to as much as 700–1,000 ExaJ per year by the middle of this century. If fossil carbon resources continue to make up the bulk of the energy supply, not only will atmospheric carbon dioxide increase to levels not seen for the past 30–35 million years, but depleting fossil carbon resources will become increasingly less available for other purposes, particularly the production of chemicals on which society now depends. The chemical process industries are heavily dependent on the availability of low-price petroleum as a feedstock. Recent life-cycle analyses suggest that pursuing both strategies of renewable energy sources and renewable feedstocks (i.e. biomass) will be required to meet these competing demands. Reducing the global use of both energy and manufactured chemicals will be a challenge for sustainable development. Education of the next generation of chemists and chemical engineers will have to change significantly from its current emphasis on petrochemical-based manufacturing to include a much greater emphasis on renewable resources and bio-based processes.Brief accounts of this work were presented at the 7th International Symposium on Green Chemistry in China (Zhuhai, People’s Republic of China, May 2005) and at the Joint US–China Green Chemistry Workshop (Beijing, People’s Republic of China, May 2005; this workshop was supported by US National Science Foundation grant CHE-0522369).     

ALTERNATIVE DEMAND MODEL ESTIMATORS FOR BLOCK RATE PRICING1

ABSTRACT: Three alternative demand model estimators for water sold under block rate tariffs are examined. The models are conceptually discussed and empirically estimated using cross-section and time-series data from Tucson, Arizona. While all three techniques produce plausible elasticity estimates, the ordinary least squares and censored sample techniques are shown to produce statistically biased results.     

FEASIBILITY OF SEASONAL WATER PRICING CONSIDERING METERING COSTS1

ABSTRACT: Efficiency implications of seasonal pricing, uniform pricing, and optimal seasonal pricing with metering costs are analyzed qualitatively using classical optimization technique. The first two schemes are special cases of the last pricing scheme. A nonlinear-integer programming model is formulated for a case study application to Salt Lake City to examine the feasibility of seasonal pricing. The analysis indicates that uniform pricing is preferable unless metering costs are substantially lower than present levels.     

石家庄市主要农作物灌溉节水潜力研究

利用田间作物灌溉试验数据，对作物单产产量与需水量的关系进行了模拟，并据此以县域为单元，计算了1984～2001年石家庄市主要农作物冬小麦、夏玉米和棉花获得逐年实际产量的理论总需水量、理论灌溉总需水量、实际灌溉用水量，测算了3种作物灌溉节水的空间。结果表明，1984～2001a。按照节水高效试验所得的产量需水模式。获得石家庄市3种主要作物产量的理论需水总量为23-29亿m^3／a，理论灌溉需水总量为8．8-13．8亿m^3／a，实际灌溉用水量平均约为17亿m^3／a，农业年均超采地下水5．67亿m^3／a。按照目前的种植结构和产量水平，石家庄市今后作物灌溉节水的理论上限为9亿m^3／a。即使加大节水投入，实现最大节水潜力的一半。仍不能弥补目前地下水的超采量。在2010年实现南水北调，部分城市用水归还农业用水，且实现最大节水潜力的一半的情况下，水资源方能勉强维持平衡。因此，石家庄市今后应一方面加大农业节水投入和管理。另一方面，也应根据水资源承载力适当减少高耗水的冬小麦播种面积，同时全面建设节水型社会，方能实现可持续发展。     

金融危机下我国废钢供求回顾与展望

国际金融危机对我国废钢市场影响巨大,市场需求萎缩,价格急剧下跌。总结回顾了2008年我国废钢市场回收、消费概况及其主要特点,并对2009年我国废钢回收量、价格走向以及再生资源增值税政策的调整实施等相关问题进行分析讨论。     

仪征市水环境承载力研究

基于仪征市水资源利用现状,利用供需平衡法计算仪征市水资源承载力;通过对仪征市水环境容量的计算,推算仪征市容量承载力。建立＂可利用用水量—废水排放量—废水目标排放量＂关系式,确定仪征市水环境承载力。     

基于极化SAR的河流有机物污染监测研究

选择我国南方水质变化梯度较为明显的典型河流为对象,分析基于C波段极化合成孔径雷达(极化SAR)的河流水污染监测评估技术.引入了随机粗糙面电磁散射理论对污染水域的散射特性进行了建模,研究了水体污染可能对散射模型及参数的影响,分析了同步得到的极化SAR数据与水体常用污染指标的监测数据.通过比较19个采样点的后向散射系数与同步监测的水质指标,发现化学需氧量(COD)与HH和VV通道的后向散射系数比成正相关性,这与由电磁理论建立的散射模型及水体污染对散射模型参数影响的分析相符.利用最小二乘法,拟合得到了利用HH与VV通道后向散射系数比来反演化学需氧量的公式,拟合结果的相关系数达到0.90.本研究建立了利用极化SAR的HH与VV通道后向散射系数比监测水体有机物污染的模型,该模型主要通过分析同步监测数据获得,基于电磁散射理论的分析支持了该模型的有效性.     

Differential fate of metabolism of a disperse dye by microorganisms Galactomyces geotrichum and Brevibacillus laterosporus and their consortium GG-BL

The present work aims to evaluate Brown 3 REL degrading potential of developed microbial consortium GG-BL using two microbial cultures, Galactomyces geotrichum MTCC 1360 (GG) and Brevibacillus laterosporus MTCC 2298 (BL). Microbial consortium GG-BL showed 100% decolorization of a dye Brown 3 REL, while individually G. geotrichum MTCC 1360 and B. laterosporus MTCC 2298 showed 26% and 86% decolorization under aerobic condition (shaking) respectively. Measurements of biochemical oxygen demand (BOD) (76%) and chemical oxygen demand (COD) (68%) were done after decolorization by consortium GG-BL. No induction in activities of oxidoreductive enzymes found in G. geotrichum while B. laterosporus showed induction of veratryl alcohol oxidase, Nicotineamide adenine dinucleotide-dichlorophenol indophenol (NADH-DCIP) reductase and riboflavin reductase indicating their role in dye metabolism. Consortium GG-BL showed induction in the activities of laccase, veratryl alcohol oxidase, tyrosinase, NADH-DCIP reductase and riboflavin reductase. Two different sets of induced enzymes from G. geotrichum and B. laterosporus work together in consortium GG-BL resulting in faster degradation of dye. The degradation of Brown 3 REL was analyzed using high performance thin layer chromatography (HPTLC), high performance liquid chromatography (HPLC), Fourier transform infrared spectroscopy (FT-IR) and gas chromatography mass spectroscopy (GC-MS). Phytotoxicity study revealed that metabolites formed after degradation was significantly less toxic in nature.     

辽宁省环保产业人才需求趋势研究

通过多种渠道和方式,大量收集有关文献资料,结合国家和辽宁省历年开展环保及相关产业调查的实际数据,进行分析、对比,总结出辽宁省环保产业人才需求形势,探讨人才发展的趋势,分析环保产业人才发展存在的问题,提出具体建议。