Degradation of the herbicide imazapyr by Fenton reactions

The degradation of the herbicide imazapyr has been carried out by three advanced oxidation processes involving iron ions as catalysts: Fentons reagent, photo-Fenton and electro-Fenton. We show that all processes are rapid and efficient. The kinetic rate constant was found to be k=5.4×10⁹ M^–1 s^–1. The mineralization of imazapyr is almost complete using the photo-Fenton and electro-Fenton processes.     

Ecological and environmental water demand of the lakes in the Haihe-Luanhe Basin of North China

ＩｎｔｒｏｄｕｃｔｉｏｎＴｈｅＨａｉｈｅ ＬｕａｎｈｅＢａｓｉｎｉｓｔｈｅｄｉｓｔｒｉｃｔｆａｃｉｎｇｔｈｅｐｒｏｂｌｅｍｏｆｗａｔｅｒｃｒｉｓｉｓｉｎｔｈｅＮｏｒｔｈＣｈｉｎａ.Ｗａｔｅｒｐｏｌｌｕｔｉｏｎｉｓｓｕｅｓａｎｄａｎｔｈｒｏｐｏｇｅｎｉｃｄｉｓｔｕｒｂａｎｃｅａｒｅｖｅｒｙｓｅｒｉｏｕｓａｔｔｈｅｓａｍｅｔｉｍｅ .Ｗａｔｅｒｄｅｆｉｃｉｅｎｃｙ ,ｐｏｌｌｕｔｉｏｎａｎｄｏｖｅｒｐｏｐｕｌａｔｉｏｎｈａｖｅｒｅｓｕｌｔｅｄｉｎｏｂｖｉｏｕｓｅｃｏｌｏｇｉｃａｌｄｅｇｒａｄａｔｉｏｎａｎ…     

上海新港河道耗氧特性研究及其综合整治措施

通过实验室试验测定，得出了上海市新港河道水体和底泥的耗氧特性曲线，分析了水体和底泥耗氧的阶段历时、阶段耗氧特性及动力学过程。在缺乏河道水质模型的情况下，利用耗氧特性曲线可以估算各个阶段的耗氧量和河道的总耗氧量，为河道充氧设备的选择提供一定的理论指导。通过计算，上海新港河道的总耗氧量约为75．7kg／d。上海宏成实业发展有限公司采用充氧曝气、投加微生物、种植水生植物等措施对河道进行了治理，实践表明，这些措施可以使新港河道的水质有明显的改善。     

用标准基准投影法综合评价水体水质

投影法是一种多指标决策和评价的方法,可应用于水体水质间的比较与排序,但它不能定性评价水体水质,无法确定水体的污染情况.本文对谈模型作了改进,具体方法为将水质标准值设为虚拟评价对象与考察对象一同进行投影,以标准的投影值为基准,通过标准区间嵌入法确定水体水质等级值,根据各水质等级值进行评价及排序.以福州山仔水库为例,对水库的富营养化程度进行综合评价,评价结果与模糊隶属函数法基本相符,评价结果合理且方法简单明了.     

An improved product-process for cleaner chrome tanning in leather processing

Severe restrictions imposed by the pollution control authorities on the disposal of chromium, total dissolved solids and chlorides in tannery effluents have forced the tanners to look for low-waste, high exhaust chrome tanning salts. An improved chrome syntan with more than 90% uptake of chrome has been developed. The new product serves both as tanning and retanning agent and can be applied directly to delimed pelts thus eliminating the conventional pickling stage in the leather processing. This modified process helps to reduce the chemical oxygen demand (COD), total dissolved solids (TDS) and chlorides in the spent tan liquor by 51, 81 and 99%, respectively. The product offers full, soft leathers having shrinkage temperature comparable to conventional chrome tanned skins. Since the developed product is highly reactive, it saves time and reduces the water requirement when compared to the conventional chrome tanning method. Thus the novel product/process developed not only has advantages in reducing pollution loads but also seems to be techno-economically viable.     

CODcr 5分钟快速测定法与国家标准方法对比试验

国家标准方法中重铬酸钾法测定化学需氧量,准确度高,但操作时间长,试剂使用量大,耗电耗水.采用5分钟快速测定法后能大大缩短测定时间,同时能耗低.通过对比试验表明,5分钟快速测定法具有较好的抗氯性,精密度及准确度均能达到要求,且具有成本低特点,证明了方法的可行性,特别适于污水处理厂等需频繁监测点的快速测试.     

浅谈生物化学需氧量质控考核

简要概述了在环境监测质量控制考核中,如何保证生物化学需氧量测定的可靠性和准确性.     

TL-1(A)型污水COD速测仪在萝北企业污水排放监测中的应用

萝北县环境监测站采用TL-1(A)型污水COD速测仪测定企业排放污水中的化学需氧量,此法在强酸性介质中,复合催化剂存在下,恒温消解水样只需10分钟,操作简单,工作效率高,克服了重铬酸钾法耗时长,每次只能同时测定几个样品的缺点.通过与国家规定的标准方法进行对比实验,结果表明,仪器测定的结果与标准法测定的结果具有良好的可比性,COD速测仪在企业污水排放监测中具有实际意义.     

硫磺回收装置酸性气配风控制方案探讨

主要介绍采用克劳斯制硫工艺的硫磺回收装置制硫转化炉配风调节的几种控制方案以及气体分析仪对稳定操作。提高硫回收率所起的重要作用。     

珠江广州段化学耗氧量(COD)数值模型

本文提出了珠江广州段COD数值模拟的控制方程、计算格式、方法、步骤和程序,并结合野外实测资料进行了参数校正和验证计算。并根据计算和实测结果对珠江广州段COD污染的时空变化特点进行讨论。本文的主要特点是:(1)考虑了COD模型的各项影响,尤其是感潮河网涨退潮交替的不定常流影响;(2)提出了感潮河网不定常流条件下COD模型数值计算中的叉口处理,即关联任意个河段的叉口处受涨退潮影响的处理方法。