Ce-Sn-W-O_x催化剂的配伍优化及脱硝影响因素

采用共混热解法制备系列Ce-Sn-W-Ox复合氧化物,用于NH3选择性催化还原NO。通过正交实验优化CeSn-W-Ox配方,采用环境扫描电镜(ESEM)、X-射线衍射仪(XRD)等表征分析催化剂的微观形貌和固相结构,确立Ce-Sn-WOx最佳配比及结构形貌。结果表明,以粒度为5~8 mm的堇青石瓷片担载分散Ce-Sn-W-Ox,进行NH3-SCR脱除NO,当Ce/Sn/W元素摩尔比为1∶0.8∶0.6时,Ce Sn0.8W0.6Ox/堇青石NH3-SCR脱除NO效果最好。当空速为7 200 h-1,催化剂在252~426℃内脱除NO效率均大于94%。重点考察了反应空速(GHSV)、水蒸气(H2O)、SO2等对Ce Sn0.8W0.6Ox/堇青石NH3-SCR脱除NO活性的影响。研究表明,空速低于10 000 h-1时,催化剂脱硝活性受空速影响小;单独通入5%H2O对催化剂脱硝活性基本没有影响;单独通入429 mg/m3SO2导致催化剂活性略有降低;同时通入429 mg/m3SO2和5%H2O,催化剂脱硝活性下降至85.33%,除去SO2和H2O后,催化剂活性又能明显回升。     

循环经济理论思索

循环经济是对近现代人类社会长期、大规模、高强度、未善待大自然的开发活动导致自然资源和生态环境逼近其耐受极限而进行反思的产物.从经济-社会-科技-自然多元复合人工自组织系统角度,研究了循环经济的科学内涵,指出循环经济是建立在组织结构协同基础上的物质循环与能量梯级利用,是集约经济的高级形态和理想模式.针对循环经济包含的若干属性特征,论述了5个基本理论问题,包括守恒与平衡、循环与协调、互动整合与倍增效应、聚集经济与产业集群、生态学基本原理应用和生态系统服务.并就生态工业系统规划设计涉及的基本方法、关键环节、人力投入等给出了政策建议.      

烟台市经济增长与环境污染关系实证研究——基于VAR计量技术的检验分析

利用烟台市1986～2003年问的3类环境污染指标和人均GDP数据,基于VAR计量技术,通过变量平稳性和协整检验,格兰杰因果检验,脉冲响应函数和预测方差分解分析,对经济增长与环境污染在时序维度的关系及其动态性进行了实证研究.结果显示:①人均GDP变化是导致污染物排放量变化的格兰杰原因,但污染物排放并不必然导致人均GDP变化,这与研究期间烟台市处于工业化中期阶段的事实吻合;⑦在烟台市的经济一环境系统内,倒U曲线不是一般规律,选取不同的污染指标呈现出经济-环境间关系的不同表现形式;③经济增长对环境污染的冲击影响的滞后期短且是非渐进的,而环境污染对经济增长产生显著影响的滞后期较长且是渐进的;④经济增长对环境污染指标的预测方差起着重要的作用,而环境污染指标对经济增长的预测方差的贡献度较小.建议要加强政府对环境的监控,建立起有效的产权保护体系与市场交易机制,注重环境保护和经济的可持续发展.     

工业节水综合效益的分析

应用费用效益比的方法分析了工业节水带来的综合效益,并根据大量实际数据研究了节水设施的投资与经济效益之间的规律,建立了节约单位水量的投资与万元产值取水量间的数学模型。     

常温袋除尘在电石炉除尘工程的研究与应用

新华结晶硅有限公司2×10 000kVA电石炉除尘项目是一项污染治理项目,该项目结合内蒙古当地的气象条件,利用较少的投资,解决了困扰多年的电石炉烟尘污染问题,同时回收的粉尘又有较高的利用价值,取得了较好的经济效益.     

Fatal pedestrian crashes on interstates and other freeways in the United States

Introduction: More than 800 pedestrians die annually in crashes on interstates and other freeways in the United States, but few studies have examined their characteristics. Method: Data from the Fatality Analysis Reporting System on pedestrians fatally injured during 2015–2017 were analyzed. Chi-square tests compared characteristics of pedestrians killed on interstates and other freeways with those that died on other roads, and across crash types among freeway deaths. Land use characteristics of locations where pedestrians were killed while crossing freeways in a large state (California) were identified using Google Earth. Results: A larger proportion of pedestrians killed on freeways died on dark and unlit roads (48% vs. 32%), were male (78% vs. 68%), or were ages 20–44 (55% vs. 32%) compared with pedestrians killed on other roads. Crossing (42%) was the most common crash type among pedestrian deaths on freeways, followed by disabled-vehicle-related crashes (18%). Pedestrians who died while crossing more often had blood alcohol concentrations ≥ 0.08 g/dL (40%) than those in disabled-vehicle-related (22%) or other crashes (34%). Deaths in crossing crashes were more likely than other freeway deaths to occur on urban roads (81%), at speed limits ≤50 mph (13%), or between 18:00 and 23:59 (49%), and 58% of crossing crashes analyzed for land use were located between residential and other (e.g., commercial, recreational) uses. Over a third (37%) of deaths in disabled-vehicle-related crashes occurred at speed limits ≥70 mph. Conclusions: A surprising proportion of pedestrian deaths occur on controlled-access roads not designed for walking. Countermeasures for these crashes need to be implemented to see meaningful reductions in pedestrian fatalities overall. Practical applications: Improving roadway and vehicle lighting, requiring reflective warning devices for marking disabled vehicles, constructing pedestrian overpasses and underpasses in areas frequently crossed, and promoting alternative means of traveling between residential and commercial areas could help.     

Environmental pollution,hydropower and nuclear energy generation before and after catastrophe: Bathtub-Weibull curve and MS-VECM methods

In this paper, the life span of hydro and nuclear energy generations and the relationship between hydro and nuclear energy generations, environmental pollution, and economic growth were investigated for Japan covering the period of 1960–2018 by employing the Bathtub-Weibull curve and Markov switching-vector error correcting (MSVEC) method, respectively. According to the Bathtub-Weibull curve analysis, a rising failure rate for nuclear energy was found, indicating that the life of nuclear energy has expired, but a decreasing failure rate for hydroelectric energy has been detected. Then two different MSVEC models were used. The MSVEC method, unlike traditional approaches, determines the relationship between variables under different regimes. The results of MSVEC methods indicate three important points. First, regime-dependent asymmetry and regime changes are crucial for policy recommendations. Second, the shocks to hydropower and nuclear energy generations cause temporary deviations from the long-run growth path in both regimes. Lastly, the increase in hydropower generation leads to a decrease in environmental pollution and an increase in GDP, and an increase in nuclear power generation increases pollution and growth in both regimes.     

建筑安全风险因素分级排序的风险矩阵法

为减少风险分级排序时产生的风险结,在引入施工安全事故频率的基础上,采用单元格细化和Borda序值法改进原有的风险矩阵法。改进后的方法使得风险等级数量增加,风险结数量减少。将该方法应用于脚手架工程的风险因素的分级与排序,风险等级分为6级,且实现了12个因素的明确排序。     

Monitoring of a Coastal Mediterranean Area: Culturable Bacteria, Phytoplankton, Environmental Factors and their Relationships in the Southern Adriatic Sea

Culturable heterotrophic bacterial and phytoplanktonic densities were investigated at four sites in the Southern Adriatic Sea (Brindisi, S. Cataldo, Otranto and S. M. di Leuca) over an annual cycle. The main phytoplankton groups, the bacterial biodiversity, as well as the faecal contamination indicators were determined. Culturable bacterial numbers averaged 4.8 ± 0.2 log CFU ml⁻¹ whereas phytoplankton numbers averaged 2.1 ± 0.4 log cells ml⁻¹. Relationships between culturable bacteria, phytoplankton and the environmental factors were established. Bacterial and phytoplankton densities usually depended significantly on temperature, dissolved oxygen, phosphate and nitrite only in the S. Cataldo transect. In all the examined transects phytoplankton showed a bloom during the January–February period followed by a bacterial peak during the February–March period. Thus we can suppose that the phytoplankton winter bloom is responsible for the availabily of organic matter for bacterial populations in the following months in this oligotrophic ecosystem.     

Assessing Respiratory Morbidity Through Pollution Status and Meteorological Conditions for Delhi

The study focuses on assessing the status of respiratory morbidity in Delhi over a four years period from 2000–2003. An attempt was made to investigate the role of important pollutants (SO₂, NO₂, SPM and RSPM) and various meteorological factors (temperature minimum & maximum, relative humidity at 0830 and 1730 hrs. and wind speed) in being responsible for respiratory admissions on account of COPD, asthma and emphysema. The study showed that winter months had greater exposure risk as pollutants often get trapped in the lower layers of atmosphere resulting in high concentrations. Statistical analysis revealed that two pollutants have significant positive correlation with the number of COPD cases viz., SPM (r = 0.474; p < 0.01) and RSPM (r = 0.353; p < 0.05), while a meteorological factor temperature (minimum) has a significant negative correlation (r = −0.318; p < 0.05) with COPD. Stepwise multiple regression analysis was performed for COPD as dependent variable and R² value of 0.33 was obtained indicating that SPM and RH(1730) were able to explain 33 percent variability in COPD. The partial correlation of SPM and RH(1730) on COPD was higher than any other combination and therefore they can be regarded as important contributing variables on COPD.