苏皖交界河网区浮游植物群落结构及其与环境因子关系的研究

苏皖交界处的石臼湖是长江下游唯一的通江淡水湖,通过青弋江和姑溪河直接与长江相连,形成了复杂的河网水系。为探讨这种复杂的河网水系中浮游植物种群结构特征,2012年平水期和枯水期分别对石臼湖及其周边入湖支流进行了浮游植物调查,研究河网水系中河网与湖区浮游植物的种类组成、季节变化及与环境因子的关系。结果显示:共采集到浮游植物105种,平水期与枯水期种类数差别不大,两次调查均出现的种类约有70%相同;浮游植物丰度最高可达1×108cell/L,达到了水华暴发的标准。优势种类主要绿藻门和蓝藻门为主,但是从生物量来看硅藻门占优。排序分析显示河网区域浮游植物季节演替明显,且河网与湖区浮游植物群落结构差异明显,进一步分析则表明影响浮游植物主要的环境因子是氮、磷等营养元素。     

山地农业种植结构演变特征及其调控途径分析——以贵州省为例

为分析山地农业种植结构的演变特征及其主要驱动因子,制定种植结构的调控途径,采用C-PCA耦合模型(典型主成分分析)对贵州省1949~2013年种植结构演变的15个驱动因子进行分析。结果表明:(1)贵州省1949~2013年种植结构逐渐向市场导向型转变,经济作物比重上升,粮食作物比重下降,粮食作物和经济作物产量分别以7.24%和2.95%的速率增长;(2)通过C-PCA耦合模型的贡献率得出种植结构演变的主要驱动因子为总人口、城市化水平、仓储运输业比重、年均气温、年降水量和农业人口比重,其对应累计贡献率达86.04%;(3)调控山地农业种植结构,不仅需要发展山地高效复合型农业,提高种植系统抗灾能力,还需借助农产品生产、加工、销售云平台实现农业的可持续发展,从而为山地农业经济的发展提供重要支撑。     

淮河干流大型底栖动物群落结构及水质生物学评价

2011年3月、6月、9月和12月对淮河干流大型底栖动物群落进行了取样调查,共采集到大型底栖动物4门41科94种。结果分析表明,淮河干流大型底栖动物群落结构具有一定的时空变化。在时间尺度上,生物密度呈极显著的季节性变化(p=0.002),其最大值332.5 ind./m2出现在6月,最小值96.6 ind./m2则出现在9月;生物量的变化趋势与生物密度不同步,其最大值155.8 g/m2出现在9月,最小值40.0 g/m2则出现在3月,且季节性差异不显著。冗余分析(RDA)结果表明,溶解氧、盐度、溶解性总固体、水温和底质类型是影响底栖动物群落结构的主要环境因子。Shannon-Wiener多样性指数的季节性变化不显著,Margalef丰富度指数的季节性差异极显著(p=0.000);自上游至下游,这2个指数的变化规律表现出高度的一致性,其水质评价结果表明淮河干流水质总体上处于中度污染的水平。     

Polyoxometalates for photocatalytic degradation of aqueous dyestuff solutions and quantitative structure–property relationship study on photolysis rate constants

Polyoxometalate, K₆TiW₁₁O₃₉Sn·7H₂O (TiW₁₁Sn), was synthesized and characterized. TiW₁₁Sn and K₆ZrW₁₁O₃₉Sn·12H₂O (ZrW₁₁Sn) were evaluated for their photocatalytic degradation of triarylmethane (brilliant green and acid blue 9), bisazo (C.I. reactive black 5), and monoazo dyestuffs (C.I. reactive red 24, C.I. reactive red 194, and C.I. reactive orange 5) with natural sunlight in homogeneous aqueous solutions. TiW₁₁Sn and ZrW₁₁Sn effectively and photocatalytically decolorized the dyestuffs. The TiW₁₁Sn- and ZrW₁₁Sn-mediated photocatalytic degradation of the dyestuffs involved a pseudo-first-order reaction and was modeled by Langmuir–Hinshelwood-type kinetics. The observed pseudo-first-order rate constants (K^/) of triarylmethane dyestuffs were generally bigger than that of the azo dyestuffs. Quantitative structure–property relationship models of the K^/ of the dyestuffs were developed using partial least-square regression. The cumulative variance of the dependent variable explained by the partial least-square components was > 0.753 for each optimal model. This value indicated that the model had good predictive ability and robustness. The K^/ values of the dyestuffs were related to the energy of the lowest unoccupied molecular orbital, and the most positive net atomic charges on a sulfur atom of dyestuffs. The linear correlation coefficients between the predicted and experimental values were all > 0.9950.     

36种典型除草剂对绿藻的毒性研究

近年来,农药对生态系统的初级生产者——藻类的毒性及其生态毒理学研究引起了国内外学者的广泛关注。除草剂在生产中广泛应用,对藻类的毒性作用最强,其毒性效应远高于杀虫剂和杀菌剂。论文选择市场上具有典型代表性的36种除草剂原药,分析解读除草剂在国内的登记情况,以及在作物、旱田和水田的使用情况;明晰对藻类生长抑制急性毒性效应。结果表明:1)除草剂的作用方式和化学类别对绿藻毒性影响显著;对于抑制植物细胞分裂和作用于植物叶绿体的除草剂对绿藻毒性均较高,以人工合成植物生长素为代表的除草剂对绿藻毒性均较低;2)相同作用方式,不同化学类别的除草剂,对单一绿藻的毒性差异明显。在水稻上获得登记的除草剂对藻类毒性整体低于在旱田获得登记的除草剂对藻类的毒性。开展多种农药对水生生态毒性的研究,为农药的合理安全使用、农药在淡水环境中的生态效应评价以及保护淡水生态系统提供科学依据。     

Fabrication and characterization of electrospun porous cellulose acetate nanofibrous mats incorporated with capric acid as form-stable phase change materials for storing/retrieving thermal energy

Electrospun cellulose acetate (CA) nanofibrous mats incorporated with capric acid was studied to fabricate form-stable phase change materials (PCMs) for storing/retrieving thermal energy. Electrospun CA nanofibrous mats with different porous structures and specific surface areas were firstly prepared through regulating the volume ratio of mixture solvent of acetone/dichloromethane (DCM). Effects of different volume ratio of mixture solvent and mat thickness on the morphological structure, specific surface area, and absorption capacity of CA nanofibrous mats were systematically investigated. The results indicated that CA nanofibrous mats were highly porous on the surface; hence, they were capable of absorbing a large amount of capric acid. The maximum absorption capacity of CA mats via electrospinning with volume ratio of acetone/DCM being 5/5 was ~95.8 wt%, due to its higher specific surface area of ~17.1 m²/g. The specific surface area and capric acid absorption capacity of CA nanofibrous mats increased with the increases of mat thickness. As the thickness of nanofibrous mats increased from 10 to 85 μm, the corresponding specific surface area and capric acid absorption capacity of mats increased respectively from 7.2 to 29.0 m²/g and 92.1 to 98.5%. Morphological structures, as well as the properties of thermal energy storage and thermal insulation of the fabricated form-stable PCMs, were studied by scanning electron microscopy, differential scanning calorimetry, and measurement of freezing times, respectively. The results indicated that the resulting form-stable PCMs could well maintain their phase transition characteristics and demonstrated great thermal energy storage capability and temperature regulation ability.     

山岳景区依托型乡村旅游就业吸附的空间特征

乡村振兴战略和乡村产业转型发展背景下,休闲旅游产业在乡村地域的兴起扰动了当前就业人口由乡村向城镇流动的宏观趋势,乡村旅游就业吸附正从微观上改变着城乡间劳动力空间流动的格局和过程。为科学理解乡村旅游就业吸附引起城乡劳动力空间流动发生变化的特征与机制,文章基于在浙晋山岳景区依托型乡村旅游地深度访谈的一手数据,分析了乡村旅游就业人口流动的空间分布特征、就业吸附的空间模式和过程机制。结果表明:①山岳景区依托型乡村旅游就业吸附呈现距离衰减和空间层级结构的特征,0~4 km为核心层、4~12 km为过渡层、12 km以上为外缘层;但在不同社会经济发展环境下该特征存在区域差异,欠发达地区乡村旅游就业吸附的空间集中性,比发达地区更加明显。②研究从城乡地域空间系统的视角,基于人口转移“推—拉”理论对乡村旅游就业人口空间流动特征和影响机制进行分析,发现山岳景区依托型乡村旅游就业吸附呈现以城镇、乡村为就业吸附极,以城乡接合部为吸附效用“分水岭”的空间模式;其中,连接城乡间的便捷交通是乡村旅游就业吸附实现的关键介质。③基于乡村旅游就业吸附空间适用性,文章针对性提出了“空间围栏效应”的概念。文章不仅从微观尺度上丰富了乡村旅游就业人口空间流动特征、过程、模式等的理论认识,而且对切实指导乡村地域在乡村旅游开发实践中理性理解乡村旅游的就业促进作用,提升乡村旅游开发规划和投资的效率具有积极意义。     

上海浦东新区农业发展环境规划研究

基于在发展农业的同时有效地控制农业环境污染的目的,综合环境、经济和社会等方面的因素,建立了浦东新区农业结构优化调整的灰色线性规划模型。该模型将农业结构调整与经济预测、化肥与农药的流失控制以及畜禽粪便污染联系起来,动态地分析规划年份的浦东新区农业生产结构,确定了农业内部结构调整的方针。     

酸化水体中的藻类研究

为研究酸沉降对水生生态系统的影响,1991年至1992年间,对地处我国重酸雨区域的重庆市郊6个水体中的藻类进行了比较研究,结果表明,绿藻门的种类最多,占种类总数的50％以上,其次是蓝藻或硅藻。藻类的细胞密度、生物量和叶绿素ａ,在酸化水体中（pH值<5.0）分别为23.3～49.9万个/L,0.59～1.05mg/L和0.65～3.01mg/m3;在轻度酸化水体（6.0＞pH值＞5.0）分别为433.9～680.0万个/L,6.6～21.75mg/L和14.66～25.19mg/m3。三项指标均随水体酸度的增加而减少。酸化水体中的藻类生长潜力（AGP）很弱,低pH值和可给态磷的不足是造成AGP低的主要限制因素。     

砼芯水泥土复合桩在基坑支护工程中的应用与研究

砼芯水泥土复合桩是一种新型的基坑支护方法,即在水泥土搅拌桩中插入钢筋混凝土预制小方桩,形成一种新的复合桩体,兼有受力和止水的双重作用,并采用两排中间用圈梁相连的门型结构提高了支护结构的受力特性。该支护方案在南京某深基坑工程中得到了成功应用。本文分析了该新方法的结构特点、简要介绍了其设计计算方法,并结合有限元数值模拟和实际的监测数据与排桩方案进行分析比较。研究结果表明,该新型基坑支护形式取得了良好的支护和经济效果,具有重要的应用前景。