合肥市区典型景观水体氮磷污染特征及富营养化评价

为掌握合肥市环城河水系水环境状况,于2012年9月~2013年7月,在城区选取6个典型景观水体测定水体理化指标和叶绿素浓度,开展水体氮磷污染特征分析及富营养化评价,结果表明:①各水体氮、磷污染较为严重,TN和TP月平均浓度均远超过国际认可的发生水体富营养化临界值;②南淝河、黑池坝和雨花塘水体氮浓度表现出显著的逐月变化性,南淝河水体TP和PO3-4-P一直在较高浓度状态下波动,而银河公园水体则呈现显著的上升趋势;③雨花塘与黑池坝水体TN/TP比平均值分别为104.7和158.3,包河公园、银河公园、逍遥津公园和南淝河水体分别为16.8、18.7、6.4和16.8,表明雨花塘、黑池坝水体处于磷限制性状态,逍遥津公园为氮限制性状态;④聚类分析将6个景观水体聚为两大类,即污染严重的黑池坝和南淝河归为一类,其余4个相对封闭的水体为另一类;⑤营养状态指数评价结果表明,所有水体均处于富营养化状态,且富营养化程度排序为:银河公园>黑池坝>南淝河>逍遥津公园>雨花塘>包河公园.     

Isolation and Identification of Antialgal Compounds from the Leaves of Vallisneria spiralis L. by Activity-Guided Fractionation (5 pp)

Background, Aims and Scope

Vallisneria spiralis Linn., a common, submerged macrophyte, is widely available in quiet waters of lakes, ponds, marshes and streams in Southeast Asia. V. spiralis plays a significant role not only in decreasing eutrophication of water body for its productivity, but also in inhibiting the growth of blue-green algae? The aim of the paper involves the isolation and identification of allelochemicals from extracts of V. spiralis by activity-guided fractionation and column chromatography.

Methods

Leaves of V. spiralis was washed free of debris, air-dried and refluxed in 95% EtOH. The extract was isolated using column chromatography and fractionation with antialgal activity. Potential allelochemicals were analyzed by high-resolution gas chromatography-mass spectrometry (HRGC-MS).

Results

Two fractions with strong antialgal activity were isolated using column chromatography and activity-guided fractionation from the extract of V. spiralis. 2-Ethyl-3-methylmaleimide, dihydroactinidiolide and 4-oxo-β-Ionone were identified in the first fraction, and 3-hydroxy-5,6-epoxy-β-ionone, loliolide, 6-hydroxy-3-oxo-α-ionone and an unknown compound in the second fraction. They had strong inhibitory effects on Microcystis aeruginosa Kütz.

Discussion

2-Ethyl-3-methylmaleimide is a byproduct of photooxidation of chlorophyll, and five other compounds identified were derivatives of β-carotene. HRGC-MS and derivatization technology were used to identify and confirm their molecular structures. The formula of the unknown compound was C16H19NO4. Metabolites of plant pigments had strong inhibitory activities on growth of algae.

Conclusions

Six compounds had been identified in V. spiralis, among them, 2-ethyl-3-methylmaleimide was the main allelochemical, and derivatives of ionone were also potential allelochemicals.

Recommendations and Perspective

. The results of our research could help us to study further mechanisms of inhibitory effect on algae and develop new potential antialgal substances.     

URBAN INFLUENCE ON PHOSPHORUS AND SEDIMENT LOADING OF WEST POINT LAKE,GEORGIA1

ABSTRACT: West Point Lake is a 10,360 ha mainstream impoundment of the Chattahoochee River located 95 kilometers downstream of Atlanta, Georgia. Origins and magnitude of external total phosphorus (TP) and total suspended solids (TSS) loads from the West Point Lake basin were estimated over a one-year period. Partitioning the drainage basin allowed the sources of these loads to be determined. The upper subbasin area, from Franklin, Georgia, to the headwaters of the Chattahoochee River, contributed 96 percent of the discharge and 97 percent of the TP and TSS loads into West Point Lake. The lower subbasin area, from Franklin to West Point Lake dam, only contributed 3 percent of the TP and TSS loads. Ninety-one percent and 87 percent of the TP and TSS loads, respectively, from the upper subbasin originated from the Atlanta area. Point sources discharged 70 percent and 3 percent of the upper subbasin TP and TSS loads, respectively. A large portion (66 percent) of the TP from the upper subbasin was in the bioavailable form.     

MASS BALANCE MODEL ESTIMATION OF PHOSPHORUS CONCENTRATIONS IN RESERVOIRS1

ABSTRACT: Mass balance models have been common tools in lake quality management for some years. However, verification for use on reservoirs, especially in the Western United States, has been seriously lacking, In this study, such a verification is attempted using data from the U.S EPA National Eutrophication Survey. Several models from the literature are compared for accuracy in application to the western reservoir data. Model standard error and correlation between estimated and observed reservoir phosphorus concentrations are the Criteria used for comparison. Standard errors am further used to calculate uncertainty of trophic state classification based on estimated phosphorus concentration. The model proposed by Dillon and Rigler (1974) proved most accurate, with a correlation coefficient of 0.86 and standard error of 0.2, based on logarithmic transformed values. Deficiencies in the other models appear to & from coefficients fit to lake data and from inappropriate model formulation.     

CHANGE IN LAKE TROPHIC STATE AND INTERNAL PHOSPHORUS RELEASE AFTER ALUMINUM SULFATE APPLICATION1

ABSTRACT: Recovery of eutrophic lakes after nutrient diversion may be delayed if the lake experiences significant internal phosphorus (p) loading to the water column. A maximum dose of aluminum sulfate, defined herein, was applied to the anaerobic sediments of the hypolimnia of two dimictic Ohio lakes following septic tank diversion, with the objective of attaining long term control of the release of phosphorus to the water column from these sediments. The results were compared to a similar, downstream, untreated lake. Total phosphorus concentration declined sharply after treatment and has remained so through 1980 for both lakes, a period of 5 and 6 years of control, respectively. Internal P loading from anaerobic, hypolimnetic sediments was partially controlled by the treatment but there are other important sources, perhaps in the littoral zone, in these lakes. Algal biomass is Smaller and water transparency has increased. Both lakes became mesotrophic after treatment, as described by the Carlson (1977) trophic state index, and remain in that improved condition to date. No deleterious side effects were observed, although one lake experienced a significant decrease in diversity of planktonic microcrustacea and a lakeward extension of the macrophyte community. This method appears to be an effective and lasting means of accelerating the recovery of a eutrophic lake following nutrient diversion.     

PHOSPHATE IN WATERS: I. REDUCTION USING NORTHERN LIGNITE FLY ASH1

Fly ashes fiom lignite coal fixed steam electric plants contain appreciable amounts of materials that can, in principle, decrease the phosphorus concentration in surface waters. Typical samples of un-weathered fly ash were used to test efficacies of removal of phosphorus from standard phosphate solutions and actual lake water samples. The effects of changing parameters such as contact time, pH, fly ash/water ratios, and solution temperature are presented. Water soluble and insoluble factors in the ash both appear to be reactive constituents. Trials with municipal waste waters showed near quantitative removal of ortho-phosphate.     

上海市主要园林景观水体富营养化调查与评价

2004年8月,调查了上海市游人量超过200万人/年的7个公园中8个小型景观水体,调查结果表明,所有被调查的公园均已经达到富营养化状态,但是水体中营养盐的贡献度随景观水体的功能和管理而有一定的差异.因此科学的分析水体污染状况,采取相应措施加强对景观水体的管理,控制水体的进一步恶化已经到了刻不容缓的地步.     

Organic Nitrogen in Precipitation Across the United Kingdom

The concentration of water-soluble organic nitrogen (WSON) in precipitation has been measured at seven sites across the United Kingdom, over a period of 1–2 years, using protocols developed in a pilot study. Samples were collected over 1–2 weeks in continuously open funnels made of stainless steel, draining to a glass bottle, and were preserved during and after collection by the addition of thymol. After chemical analysis, samples were excluded from the long-term average if they showed signs of contamination (significant concentrations of K⁺ or PO₄ ^3–). Two methods of measuring total dissolved N were used, persulphate oxidation and high-temperature chemiluminescence. The latter generally gave the larger values, and has been used to asses the organic component of dissolved N. The long-term data set confirms the original results from the pilot study - organic N contributes between 24 and 40% to the total annual wet deposition of dissolved N across the United Kingdom. The fraction of WSON was greatest at western sites, and was strongly correlated with ammonium concentrations. However, the seasonal pattern across all sites showed a late spring maximum for ammonium and nitrate, but a late summer maximum for WSON. The magnitude of the contribution of WSON to wet-deposited N has implications for the setting and assessment of critical loads for N deposition.     

LONG-TERM EQUILIBRIUM PHOSPHORUS CONCENTRATIONS IN THE EVERGLADES AS PREDICTED BY A VOLLENWEIDER-TYPE MODEL1

ABSTRACT: Anthropogenic phosphorus loading, mainly from the Everglades Agricultural Area (EAA), is believed to be the primary cause of eutrophication in the Everglades. The state of Florida has adopted a plan for addressing Everglades eutrophication problems by reducing anthropogenic phosphorus loads through the implementation of Best Management Practices (BMPs) in agricultural watersheds and the construction of stormwater treatment areas (STAs). Optimizing the effectiveness of these STAs for reducing phosphorus concentrations from agricultural runoff is a critical component of the District's comprehensive Everglades protection effort. Therefore, the objective of this study was to develop a simple tool that can be used to estimate STAs’performance and evaluate management alternatives considered in the Everglades restoration efforts. The model was tested at two south Florida wetland sites and then was used to simulate several management alternatives and predict ecosystem responses to reduced external phosphorus (P) loadings. Good agreement between model predictions at the two wetland sites and actual observations indicated that the model can be used as a management tool to predict wetlands’response to reductions in external phosphorus load and long-term P levels in aquatic ecosystems. Model results showed that lowering P content of the Everglades Protection Area (EPA) depends on reducing P loads originating from EAA discharges, not from rainfall. Assuming no action is taken (e.g., no BMPs or STAs implemented), the steady state model predicted that the average concentration within the modeled area of the marsh would reach 20 μg L^?1 within five years. With an 85 percent reduction in P loading, the steady-state model predicted that Water Conservation Area 2A (WCA-2A) P concentration will equilibrate at approximately 10 μ L^?1, while elimination of all loadings is projected to further reduce marsh P to values less than 10 μg L^?1.     

乌江水污染调查

乌江是长江上游重要的支流之一。对比多年乌江水质监测结果 ,乌江水质总体能满足地表水 类水质要求。经调查 ,乌江近几年春季多次发生水体变黑 ,通过对乌江 2 0 0 1年 3月发生的水污染调查表明 ,总磷浓度从乌江上游到下游有逐渐降低的趋势 ,水体变黑的主要原因可能是由于城区江段有较高的 N、P背景 ,而乌江上游水库排水造成 ,水体中 chl-a含量按 OECD标准评价达到富营养化水平