模糊综合评判法在渭河水质评价中的应用研究

渭河是陕西省的第一大河流,准确的水质评价是治理渭河水体污染的重要前提。本文采用模糊变换原理和最大隶属度原则,运用模糊综合评判法对渭河潼关吊桥断面2012年的监测数据进行了全面评价。结果表明该断面春、夏、秋、冬四个季度的水质污染级别分别为:Ⅴ类(严重污染)、Ⅰ类(未污染)、Ⅳ类(重污染)和Ⅴ类(严重污染),主要污染物为NH3-N。与传统的单因子评价法相比,该方法能更全面合理地反映水质情况。     

提高快速法测定C OD准确度及精密度的方法

介绍了用快速法测定COD分析中提高准确度及精密度的方法。     

应用模糊数学法综合评价营口石门水库水质级别

应用模糊数学法综合了5项主要污染指标评价了2008-2012年营口石门水库的水质级别,改变了仅凭单因子评价水质级别的方法,评价更合理,更符合实际情况。     

宝天高速公路沿线地表水环境现状评价的密切值法

以宝天高速公路为背景,讨论了公路建设对水体环境的主要影响,并利用改进的密切值法对公路沿线地表水进行水环境质量现状评价.通过评价表明:沿线地表水质量良好,基本达到地表水环境Ⅰ级标准;评价结果真实地反映了天宝高速公路沿线水体水质的基本情况,说明采用密切值法对水体进行评价是可行的;该方法概念清晰、计算简便实用,能较好地反映区域内各水体水环境质量的相对优劣,可为制定环境规划、进行环境决策、实施环境综合整治提供科学依据.     

基于GIS的可视化土质边坡稳定性分析系统研究

结合GIS空间数据分析能力与极限平衡法开发了可视化的土质边坡稳定性分析系统GiSlope,介绍了边坡几何模型、外荷载与加筋结构模型、滑动面及地下水位线模型等分析模型的可视化建立过程,阐述了计算分析的设定、任意形状滑动面土条条分方法以及计算参数的确定方法。通过对几个典型实例的分析与国内外商业软件计算结果的对比,验证了系统计算的正确性和可靠性。     

有机溶剂中温法溶出光伏组件封装材料乙烯-醋酸乙烯酯

采用有机溶剂邻二氯苯中温法溶出模拟光伏组件的封装材料乙烯-醋酸乙烯酯(EVA),探究了不同条件下EVA的溶出率及模拟组件的分离率,通过正交实验确定了有机溶剂中温法处理EVA的最佳条件.实验结果表明,在反应温度160℃、固液比(光伏组件个数与邻二氯苯体积之比,个/mL)4:100、搅拌转速800 r/min、反应时间24...     

水环境质量评价3种方法的应用对比

从众多水质评价方法中选取单项指数法、加权均值型指数法、模糊数学法进行介绍,并通过运用这3种方法对大汶河某年监测数据的平均值进行评价.经对比分析发现,加权均值型指数法是一种比较实用的水质评价方法,模糊数学法可以作为必要的补充.     

基于无人机多传感吊舱系统的火点实时定位方法

林火定位是林火智能监测设备的核心技术。提出了一种基于激光雷达、红外热像仪及组合惯导多数据融合的火点定位方法。首先设计了一个通用的无人机吊舱系统,并基于ROS框架实现数据采集、数据处理和数据传输等功能;其次提出了一个基于无人机吊舱系统的火点全局定位方案,根据红外热像仪成像特性识别火点,同时将密集点云与红外图像进行数据融合,估计出火点的三维空间位置;然后根据无人机位姿提出了一种基于墨卡托投影的火点全局定位方案,得到了火点的GPS位置。最后通过试验得到了该方案的全局定位精度：在实验中经度最大误差为2.36×10^-5°,纬度最大误差为1.84×10^-5°,高程最大误差为0.926 1 m,为其他林火定位方案提供了技术支持。     

Improvement of an efficient separation method for chemicals in diesel exhaust particles: analysis for nitrophenols

GOAL, SCOPE, AND BACKGROUND: Diesel exhaust is believed to consist of thousands of organic constituents and is a major cause of urban pollution. We recently reported that a systematic separation procedure involving successive solvent extractions, followed by repeated column chromatography, resulted in the isolation of vasodilatory active nitrophenols. These findings indicated that the estimation of the amount of nitrophenols in the environment is important to evaluate their effect on human health. The isolation procedure, however, involved successive solvent extractions followed by tedious, repeated chromatography, resulting in poor fractionation and in a significant loss of accuracy and reliability. Therefore, it was crucial to develop an alternative, efficient, and reliable analytical method. Here, we describe a facile and efficient acid-base extraction procedure for the analysis of nitrophenols. MATERIALS AND METHODS: Diesel exhaust particles (DEP) were collected from the exhaust of a 4JB1-type engine (ISUZU Automobile Co., Tokyo, Japan). Gas chromatography-mass spectrometry (GC-MS) analysis was performed with a GCMS-QP2010 instrument (Shimadzu, Kyoto, Japan). RESULTS: A solution of DEP in 1-butanol was extracted with aqueous NaOH to afford a nitrophenol-rich oily extract. The resulting oil was methylated with trimethylsilyldiazomethane and subsequently subjected to GC-MS analysis, revealing that 4-nitrophenol, 3-methyl-4-nitrophenol, 2-methyl-4-nitrophenol, and 4-nitro-3-phenylphenol were present in significantly higher concentrations than those reported previously. DISCUSSION: Simple acid-base extraction followed by the direct analysis of the resulting extract by GC-MS gave only broad peaks of nitrophenols with a poor detection limit, while the GC-MS analysis of the sample pretreated with (trimethylsilyl)diazomethane gave satisfactorily clear chromatograms with sharp peaks and with a significantly lowered detection limit (0.5 ng/ml, approximately 100 times). CONCLUSION: The present method involving an acid-base extraction, in situ derivatization, and GC-MS analysis has shown to be a simple, efficient, and reliable method for the isolation and identification of the chemical substances in DEP.     

Extended geometric method: a simple approach to derive adsorption rate constants of Langmuir-Freundlich kinetics

A new and simple equation has been presented here for calculation of adsorption and desorption rate constants of Langmuir-Freundlich kinetic equation. The derivation of new equation is on the basis of extension and correction to the geometric method which has been presented by Kuan et al. [Kuan, W.-H., Lo, S.-L., Chang, C.M., Wang, M.K., 2000. A geometric approach to determine adsorption and desorption kinetic constants. Chemosphere 41, 1741-1747] for the kinetics of adsorption/desorption in aqueous solutions. The correction is to consider that the concentration of solute is not constant and changes as adsorption proceeds. The extension is that we applied Langmuir-Freundlich kinetic model instead of Langmuir kinetic model to consider the heterogeneity and therefore it is more applicable to the real systems. For solving Langmuir-Freundlich kinetic model, some geometric methods and also Taylor expansion were used and finally a simple and novel equation was derived (Eq. (20)) for calculation of adsorption rate constant. This new method was named "extended geometric method". The input data of the obtained equation can be simply derived from initial data of adsorption kinetics. Finally the adsorption of methyl orange onto granular activated carbon was carried out at dynamic and equilibrium conditions and the capabilities of extended geometric method were examined by the experimental data.