中和共沉淀法形成铁氧体微晶及其对重金属离子的并合

本文对中和共沉淀法Fe_3O_4生成过程中重金属离子并合程度及其影响因素进行了研究,在实验条件下,发现重金属离子在Fe_3O_4晶格中的并合与其离子半径、电负性和外层电子分布等因素有关。并合程度为:Cu~(2+),CO~(2+),Fe~(2+)>Mn~(2+),Zn~(2+)>Ni~(2+),Cd~(2+),当Fe~(2+)/Fe~(3+)=0.5,pH=9.5±0.5时,对40mgCu~(2+),总铁量(Fe~(2+)+Fe~(3+))2.5g为最小投料量,其并合率可达99.7％以上,相同条件下CO~(2+)并合率大于99.7％,其它重金属离子由于本征特性影响,并合率各不相同,工艺条件适合于污水中Cu~(2+)和Co~(2+)的有效去除,对Mn~(2+),Zn~(2+)的去除也有一定效果,从沉渣的XRD物相分析可知,重金属离子在Fe_3O_4中的并合,是以尖晶石型结构取代式固溶体组成完成的。     

The Effect of Fragment Shape and Species' Sensitivity to Habitat Edges on Animal Population Size

Abstract:  Habitat fragmentation causes extinction of local animal populations by decreasing the amount of viable "core" habitat area and increasing edge effects. It is widely accepted that larger fragments make better nature reserves because core-dwelling species have a larger amount of suitable habitat. Nevertheless, fragments in real landscapes have complex, irregular shapes. We modeled the population sizes of species that have a representative range of preferences for or aversions to habitat edges at five spatial scales (within 10, 32, 100, 320, and 1000 m of an edge) in a nation-wide analysis of forest remnants in New Zealand. We hypothesized that the irregular shapes of fragments in real landscapes should generate statistically significant correlations between population density and fragment area, purely as a "geometric" effect of varying species responses to the distribution of edge habitat. Irregularly shaped fragments consistently reduced the population size of core-dwelling species by 10–100%, depending on the scale over which species responded to habitat edges. Moreover, core populations within individual fragments were spatially discontinuous, containing multiple, disjunct populations that inhabited small spatial areas and had reduced population size. The geometric effect was highly nonlinear and depended on the range of fragment sizes sampled and the scale at which species responded to habitat edges. Fragment shape played a strong role in determining population size in fragmented landscapes; thus, habitat restoration efforts may be more effective if they focus on connecting disjunct cores rather than isolated fragments.     

摩托车发动机活塞浇注模设计

根据实际生产的需要对摩托车发动机活塞的成形工艺进行分析 ,从而确定合理的浇注方案 ,然后详细地阐述活塞浇注模结构设计和工作原理 ,并介绍了模具的抽芯过程和型芯的典型加工工艺     

福建省“尤德地体”的成矿特征和找矿远景

“尤德地体”位于闽中裂谷带南端 ,与紫金山金矿处于同一成矿带。在“尤德地体”中 ,目前已发现元古界麻源群变质岩和侏罗系长林组、南园组 ,火山岩中均存在韧性剪切带型矿床和热液交代充填矿床。区域构造、地层含矿性、物化探重砂异常等表明其找矿前景很好。找矿工作重点应紧扣层控矿床 ,大断裂带 ,斑岩型金矿和红土型金矿     

铁氧体化法在重金属污染物解毒处理中的应用

综合介绍铁氧体化法在重金属污染物解毒处理方面的应用研究情况，提出毒害性污染物解毒处理的概念，并进一步指出开发降解性毒害污染物解毒处理工艺中值得注意的问题。     

常温铁氧体法处理电解锌厂废水试验研究

用常温铁氧体法对山西某电解锌厂废水进行了处理。经试验研究确定了处理该废水的工艺条件:Fe2+/M2+10,添加剂用量1.4g/L,M3+/M2+1.6,Zn2+/Cu2+33.3(废水初始Zn2+/Cu2+),所得磁性产物的饱和磁化率为45.9emu/g,回收率为85.0%。试验中还发现,金属离子的半径对铁氧体的生成有一定的影响。     

A nanocomposite of CoFe2O4-carbon microspheres for electrochemical energy storage applications

A carbon/CoFe₂O₄ composite was synthesized by precipitation method. The morphology of the composite was analyzed using scanning electron microscopy, X-ray diffraction, transmission electron microscopy, Fourier Transform Infrared Spectra, and vibrating sample magnetometry. The electrocapacitive behaviors of the composite has been studies by cycle voltammogram and galvanic charge/discharge. The size of the nanoparticles carbon composite of CoFe₂O₄ was uniform and 209 nm. Due to a high percent of carbon, electrochemical measurements showed electrical double layer mechanism. Specifically, the carbon/cobalt ferrite electrode exhibited high specific capacitance of 102.5 F g^?1 at a current density of 0.16 A g^?1, and high rate capability with 30% retention of capacitance even up to 20 A g^?1, and excellent cycling stability with 81.5% retention of the initial capacitance after 6000 charge/discharge cycles, supporting that the carbon cobalt ferrite composite electrode could be a potential candidate for supercapacitor application.     

Catalytic ozonation treatment of papermaking wastewater by Ag-doped NiFe2O4: Performance and mechanism

The catalytic ozonation treatment of secondary biochemical effluent for papermaking wastewater by Ag-doped nickel ferrite was investigated. Ag-doped catalysts prepared by sol-gel method were characterized, illustrating that Ag entirely entered the crystalline of NiFe₂O₄ and changed the surface properties. The addition of catalyst enhanced the removal efficiency of chemical oxygen demand and total organic carbon. The results of gas chromatography-mass spectrometer, ultraviolet light absorbance at 254 nm and three-dimensional fluorescence excitation-emission matrix suggested that aromatic compounds were efficiently degraded and toxic substances, such as dibutyl phthalate. In addition, the radical scavenging experiments confirmed the hydroxyl radicals acted as the main reactive oxygen species and the surface properties of catalysts played an important role in the reaction. Overall, this work validated potential applications of Ag-doped NiFe₂O₄ catalyzed ozonation process of biologically recalcitrant wastewater.     

荧光灯管芯柱玻璃中金属铅的机械化学硫化

以硫化钠为硫化剂,机械化学硫化荧光灯管芯柱玻璃中金属铅,实现金属铅向硫化铅快速转化.通过单因素实验,考察了不同机械化学硫化条件,即球磨时间、球磨转速和球料比对硫化率的影响,并通过XRD、SEM和粒度对硫化产物进行表征.结果表明,硫化率随球磨时间和球磨转速的增大而增大,随球料比的增大先增大后减小,当球磨转速为750r/min、球磨时间为120min、球料比为50：1g/g时,荧光灯管芯柱玻璃中金属铅的硫化率可达96.18%.XRD结果表明,荧光灯管芯柱玻璃中金属铅的机械化学硫化产物为PbS、SEM和粒度结果表明,荧光灯管芯柱玻璃的粒径随球磨转速和球磨时间的增加而减小.     

Assessment of cervical range of motion,cervical core strength and scapular dyskinesia in violin players

Background. Playing the violin can lead to asymmetric postures which can affect the cervical range of motion, cervical core strength and scapular stability. Objective. The objective of the study was to assess the cervical range of motion, cervical core strength and scapular dyskinesia in violin players and non-players of the same age group. Methods. An inclinometer was used to assess the cervical range of motion, pressure biofeedback was used to assess cervical core strength and scapular dyskinesia was also assessed in 30 professional violin players (18–40 years) compared with 30 age-matched non-players. Analysis was done using an unpaired t test. Results. Significant change was seen with respect to extension (p?=?0.051), cervical core strength (p?=?0.005), right (Rt) superior angle 0° (p?=?0.004), Rt superior angle 45° (p?=?0.015) and Rt inferior angle 90° (p?=?0.013). Conclusion. This study shows a significant difference in extension range of motion and cervical core strength of violin players. Also, there was scapular dyskinesia seen at 0° and 45° right-side superior angle of the scapula and 90° right-side inferior angle of the scapula.