头孢曲松氯化消毒转化产物鉴定及机理研究

以头孢曲松为目标化合物,探索其在氯消毒处理中的转化机理.结果显示头孢曲松在氯化处理中主要发生两种反应,一种为氧化反应,另一种为氯化反应.头孢曲松分子中的硫醚官能团经氧化生成亚砜产物,消毒剂中的氯原子与噻唑环中的4-C原子发生亲电取代反应生成氯代产物.更为重要的是,本研究还探讨了低浓度头孢曲松在环境水体基质中的氯化转化特征,结果表明,本文所推测的反应机理在含头孢曲松的实际环境水样的氯化处理中同样发生.     

Seven years from the first application of polyaluminium chloride in the Czech Republic – effects on phytoplankton communities in three water bodies

This study determines the efficiency of polyaluminium chloride application on phytoplankton species as a consequence of five reservoir restorations in the Czech Republic during the years 2005 and 2008, including the first ever large-scale application. Although polyaluminium chloride has been used in water treatment plants across the world, information about its application toward cyanobacterial blooms in nature is poor. Although the application of polyaluminium chloride did not cause any fundamental long-term changes in the composition of phytoplankton species or phosphorus load, instead causing fast and acute removal of the phytoplankton community, it may act as an algicidal compound with fast removal efficiency. All treated water bodies described in our study remained unaffected by cyanobacterial blooms and the hygienic limit for the purposes of recreation was not exceeded in any particular season. This article should serve as notice of the advantages and disadvantages of polyaluminium chloride application, and also warn against the uniform usage of this chemical as a method of reducing phytoplankton species in all types of water bodies where cyanobacteria are present. Moreover, data about the effects on non-target (invertebrates) species and microcystin release from cyanobacterial cells are also mentioned.     

Polychlorinated dibenzo‐p‐dioxins and dibenzofurans (PCDD/Fs) in dated environmental samples,and their connection to known sources

This article investigates available environmental data from measurements of the everywhere present contaminants polychlorinated dibenzo‐p‐dioxins and dibenzofurans (PCDD/F) in dated trends in sediment, soil and herbage from locales in Europe and North America. The PCDD/F data are examined in relation to potential major PCDD/F sources based on volume: wood and coal, example of natural combustion; pentachlorophenol (PnCP), example of chlorinated aro‐matics; and polyvinyl chloride (PVC) pyrolysis, example of chlorinated aliphatic. Collected PCDD/F data of congener sums and 2, 3, 7, 8‐substituted congener (PCDD/F profiles) have been investigated with multivariate methods: principal component analysis (PCA) and partial least squares projection to latent structures model (PLS). The results show that PCDD/F data from 12 locales can be separated in one to three independent profiles. Normally one profile is related to the PCDD/F found in PnCP and another to combustion. A subtype of the ‘PnCP’ and ‘combustion’ profiles indicates PCDD/F contributions from PVC‐related combustions. The environmental profiles exhibit some differences from the suggested sources. The relatively unprotected PCDD/F related to PnCP is suggested to have passed photolytic and/or thermal dechlorinations. Lower‐chlorinated congeners in environmental profiles related to combustion appear to have been influenced by environmental distribution processes. PCDD/F data before industrial production of chlorinated organics have only limited similarity to PCDD/F in technical PnCP profiles; an average 4.6% of the PCDD/F is related to PnCP. This suggests that PnCP similarity in recent deposition profiles cannot be a result of environmental transformation. The average proportion of PnCP‐related PCDD/F profile in recent depositions is 35% with North America high (average 57%) and Europe low (average 24%).     

Preconcentration of tin in environmental and biological samples by ion exchange using modified Amberlite XAD-2

Utilization of Amberlite XAD-2 surface modified by covalent immobilization of brilliant green through an azo spacer for adsorptive enrichment of Sn(II) from environmental and biological samples was highlighted. The resulting resin was characterized by Fourier transform infrared spectroscopy, elemental analysis, thermogravimetric analysis, and scanning electron microscopy. The resin retained Sn(II) ions at an optimum pH of 9.5 with a sorption capacity of 40 mg g^?1. The modified sorbent could be reused for 10 cycles without significant changes in sorption capacity. The recovery of Sn(II) was 98% when eluted with 0.1 mol L^?1 ethylenediaminetetraacetic acid. Scatchard analysis revealed that binding sites in the modified resin were homogeneous. The equilibrium adsorption data were analyzed using the Langmuir, Freundlich, Temkin, and Redlich–Peterson isotherm models. The method was applied with satisfactory results for determination of Sn(II) ions in human plasma and sea water.     

Mutagenic and carcinogenic effects of cadmium†

There is limited evidence to suggest that certain compounds of cadmium may be mildly mutagenic. Some compounds of cadmium have given rise to fibrosarcoma and rhabdomyosarcoma following subcutaneous or intramuscular injection in the rat and also to interstitial cell tumours of the testis as a sequel to cellular damage and testicular atrophy. Cadmium chloride aerosol inhalation has induced a high incidence of dose‐related lung cancer in the rat. Epidemiological observations suggest that mortality from prostatic and possibly from lung cancer has been increased in cadmium workers who had experienced the very high levels of cadmium, mainly as oxide dust or fume, which existed in the past. The more recent epidemiological studies have not added further evidence in support of the carcinogenic role of cadmium.     

青岛市城市绿地种子植物区系的构成特征

在资料分析和2013年夏秋二季进行的实地调查基础上研究了青岛市城市绿地种子植物区系的科属种构成、种的生活型构成、属的地理分布区类型构成,并比较了青岛市城市绿地种子植物区系与青岛崂山种子植物区系、中国种子植物区系属的地理分布区类型构成差异。结果表明,青岛市城市绿地种子植物区系有种子植物69科155属228种,有含5种及以上的12个较大科、124个单种属、183种木本植物和45种草本植物,有热带分布属32属、温带分布属95属、世界分布属14属和中国特有属14属。青岛市城市绿地种子植物区系有植物种类丰富多样,木本植物种类多,区系中属、种的分化程度高,属的地理分布区类型多样且具有很典型的温带特征和鲜明的中国特色等特点。     

The greener,the more cost efficient? An empirical study of international tourist hotels in Taiwan

Going ‘green’ is more than a mere fad in the hotel industry, and environment-friendly green hotels are becoming popular. The purpose of this study was to conduct an investigation into the link between ‘green’ and cost efficiency in the hotel industry. Empirical evidence supporting this investigation was gathered from the Taiwan hotel industry. Data were gathered from 68 international tourist hotels in Taiwan. Moreover, our finding differs from most of the earlier studies and indicates that ‘green’ is negatively and significantly associated with the cost efficiency of a hotel. In other words, ‘green’ renders a hotel ineffective. The implications of the findings have been discussed, and the limitations of the study as well as future research directions have been addressed.     

梅州城区植物群落的结构特征

2009年4—10月,采用群落调查法、主成分分析法对梅州城区5种绿地类型65个种植的植物群落进行研究,结果表明：1）各类植物共计43科105属147种（含变种）,其中乔木62种（42．17％）、灌木45种（30．61％）、草本植物31种（21．09％）、藤本植物9种（6．12％）;2）群落垂直结构为乔、灌、草3层复合结构者9个（13．85％）,为乔、草2层结构者34个（52．31％）,乔或草单层结构者12个（18．46％）;3）乔木树种平均胸径16．7cm,其中平均胸径〈10cm者23种（37．09％）,平均胸径10～20cm者29种（46．77％）,平均胸径20～30cm、〉30Cm者分别为5种（均为8．06％）;4）梅州城区植物群落结构的特征,可用乔木高度因子、胸径因子、密度因子及冠幅因子来表述,这4个主因子的方差累积贡献率达到81．55％,可以很好地反映出群落结构的大部分信息;5）梅州市城区乔木层的优势树种是垂榕、大叶榕、大王椰子,次优势种是阿珍榄仁、阴香、海南蒲桃、细叶榕、木棉、麻楝、香樟、洋紫荆,这11个树种分属桑科、棕榈科、使君子科·、樟科、桃金娘科、木棉科、楝科、豆科（云实科）,它们是梅州城市森林的骨干树种和基调树种,决定了梅州城市森林的南亚热带性质的外貌。     

基于TM遥感影像的广州市城区公园增湿效应研究

选取广州市城区17个公园作为研究对象,分析了公园对周边环境的增湿效应。结果表明,公园周边与公园边界点的空气湿度差随着其远离公园边界距离的增大而增加,且增长趋势逐渐减缓,拟合曲线近似于一条过原点的三次多项式（R2〉0.80）。绿化率大于50%、长宽比接近1的公园,其平均增湿范围和增湿湿度差均与绿地面积存在显著的正线性关系（R2分别为0.94和0.77）。水体面积比例较大或长宽比较大（约≥2）的公园,比同等条件下水体面积较小或长宽比较小的公园（≈1）增湿效果好。     

基于环境影响的绿化物流成本初探

作为物流服务价值的重要组成部分,物流成本受到相关企业的普遍重视,物流成本核算对于制定科学合理的微观物流策略、提高企业经济运行质量和效率具有重要意义。然而作为物流成本核算的基础,当前的微观物流成本构成中并未考虑企业物流活动的环境影响,不能真正反映物流活动的全部成本,从而影响了企业的可持续健康发展。基于资源环境的价值理论,提出应以绿化物流成本来衡量企业物流活动的全部消耗,即在微观物流成本构成中考虑环境成本,并给出了微观绿化物流成本的基本公式。