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21.
Thin-film technique is becoming an industry standard for the preparation of TiO2-based photocatalyst for organic destruction. The catalyst provides several advantages over the conventional powder TiO2 in the treatment of wastewater and groundwater. In this study, a continuous stir flow reactor model is developed capable of describing the photocatalytic process. The model incorporates the following fundamental mechanisms: adsorption, diffusion, liquid-film transfer, UV attenuation, and photocatalytic reaction. All of the simulation results indicate that there exists a highly nonlinear relation between each of these parameters and the destruction rate. Various incident light intensities also are incorporated to simulate the energy efficiency. The simulations illustrate that the photocatalytic model can be used to elucidate the effect of process variables. It is also possible to “custom-design” a catalyst for the treatment of a particular waste stream. 相似文献
22.
Modeling rhizofiltration: heavy-metal uptake by plant roots 总被引:1,自引:0,他引:1
P. Verma K. V. George H. V. Singh S. K. Singh A. Juwarkar R. N. Singh 《Environmental Modeling and Assessment》2006,11(4):387-394
The discovery of phytoaccumulation potential of plant species has led to its application for remediation of heavy-metal-contaminated soil and wastewater, which is termed as phytoextraction/rhizofiltration. For prediction, analysis, planning and cost-effective design of such systems, mathematical models not only are used as a screening tool but also provide optimal parameters like harvesting time, irrigation schedule, etc. Several laboratory and field scale studies have been carried out in the past, and mathematical expressions have been developed by various researchers for different phenomena like metal adsorption in soil, plant root growth with time, moisture and metal uptake by plant root, moisture movement in unsaturated zone, soil moisture relationship, etc. The complete design of any such phytoremediation program would require the knowledge of behavior of heavy-metal movement in soil, water and plant root system. In this paper, a model for simulating heavy-metal dynamics in soil, water and plant root system is developed and discussed. The governing non-linear partial differential equation is solved numerically by implicit finite difference method using Picard's iterative technique, and the formulation has been illustrated using a characteristic example. The source code is written in MATLAB. 相似文献
23.
Nitrogen leaching is a world-wide concern for the quality of ground- and surfacewater. Measures to abate this is still limited by a lack of understanding mechanisms behind all factors describing the leaching process, time lags between countermeasures and improvement in waterquality and spatial distribution of nitrogen leaching. The purpose of this study was to do an initial test of the SOILNDB model system which is built on the existing mechanistic SOIL and SOILN models and an automatic parameterization procedure for use of simplified input data. The test was done by simulating nitrogen leaching from each of the 150 fields in a small catchment during a three-year study period. The simulated mean root-zone nitrogen leaching rate from all the fields in the catchment was compared to measurements of nitrogen flow in the stream draining the catchment and showed good agreement in between-year dynamics. 相似文献
24.
Assessing land use impacts on flood processes in complex terrain by using GIS and modeling approach 总被引:1,自引:0,他引:1
Y. B. Liu F. De Smedt L. Hoffmann L. Pfister 《Environmental Modeling and Assessment》2005,9(4):227-235
A distributed hydrologic modeling and GIS approach is applied for the assessment of land use impact in the Steinsel sub-basin, Alzette, Grand-Duchy of Luxembourg. The assessment focuses on the runoff contributions from different land use classes and the potential impact of land use changes on runoff generation. The results show that the direct runoff from urban areas is dominant for a flood event compared with runoff from other land use areas in this catchment, and tends to increase for small floods and for the dry season floods, whereas the interflow from forested, pasture and agricultural field areas contributes to the recession flow. Significant variations in flood volume, peak discharge, time to the peak, etc., are found from the model simulation based on the three hypothetical land use change scenarios. 相似文献
25.
IntroductionContaminationofediblevegetationbypersistent,ubiquitouschemicalssuchasPCBs,dioxins,pesticides,andherbicidesprovidesamajorexposureroutetohumans ,domesticanimalsandwildlife .Uptakeoftheseorganicchemicalsbyplant,andsubsequentdistributionintheplan… 相似文献
26.
27.
Sean LIU 《环境科学学报(英文版)》2003,(6)
IntroductionTheconventionalmethodforsubsurfaceremediationofgroundwatercontaminationwithVOCsistheso called“pump and treat”technology .Thelimitationofthisapproachistheprohibitivelylongtreatmenttimeforremediatingthegroundwatercontaminatedwithcommonchlorinatedsolventsthathavedensitiesgreaterthanthatofwater(classifiedasDNAPLs densenon aqueousphaseliquids) .Thisislargelyduetotheverylowwatersolubilityandlowbiodegradabilityofthisclassofsolventsandthetendencyofthesolventssettlinginthebottomofanaqu… 相似文献
28.
综述了土壤及地下水系统中反硝化作用的研究进展,详细地介绍了反硝化作用的原理和机制,用以防治地表水和地下水的污染。 相似文献
29.
A Simulation of Temporal and Spatial Variations in Carbon at Landscape Level: A Case Study for Lake Abitibi Model Forest in Ontario,Canada 总被引:2,自引:0,他引:2
Xiaolu Zhou Changhui Peng Qing-Lai Dang Jiaxin Chen Sue Parton 《Mitigation and Adaptation Strategies for Global Change》2007,12(4):525-543
Using a case study of the Lake Abitibi Model Forest (LAMF), this study aims to assess the temporal and spatial variability
in carbon storage during 1990–2000, and to present a comprehensive estimation of the carbon budget for LAMF's ecosystems.
As well, it provided the information needed by local forest managers to develop ecological and carbon-based indicators and
monitor the sustainability of forest ecosystems. Temporal and spatial carbon dynamics were simulated at the landscape level
using ecosystem model TRIPLEX1.0 and Geographical Information System (GIS). The simulated net primary productivity (NPP) and
carbon storage in forest biomass and soil were compared with field data and results from other studies for Canada's boreal
forests. The results show that simulated NPP ranged from 3.26 to 3.34 tC ha−1 yr−1 in the 1990s and was consistent with the range measured during the Boreal Ecosystem-Atmosphere Studies (BOREAS) in central
Canada. Modeled NPP was also compared with the estimation from remote sensing data. The density of total above-and belowground
biomass was 125.3, 111.8, and 106.5 tC ha−1 for black spruce, trembling aspen, and jack pine in the LAMF ecosystem, respectively. The total carbon density of forested
land was estimated at 154.4 tC ha−1 with the proportion of 4:6 for total biomass and soil. The analysis of net carbon balance of ecosystem suggested that the
LAMF forest ecosystem was acting as a carbon sink with an allowable harvest in the 1990s. 相似文献
30.
This paper uses a prediction model of groundwater pollution based on the experiments in the laboratory and in field .The model, which was tested and calibrated by the field observated data ,satisfactorily simulated the field conditions in land treatment system of wastewater . Particularly , the model can provide the reliable pollution prediction of heavy metals , organisms and nitrogen . The model was used to predict the groundwater pollution caused by the land treatment system in the region of North China . The calibration of the model showed that correlation coefficients between the tested and predictive data of Cr6+. As3+, organism and NH4+ could reach 0.990, which proved that the model possessed the realistic instructive significance for design and use of wastewater land treatment systems . 相似文献