生物炭输入对土壤污染物迁移行为的影响

重点综述了生物炭输入对土壤中污染物的吸附固持作用及生物有效性的影响,分析其作为土壤添加剂消减土壤污染风险的有效性,为生物炭在土壤中的应用研究提供依据。     

Microstructure of 2205 duplex stainless steel joint in submerged arc welding by post weld heat treatment

The 2205 duplex stainless steel (DSS) is of both good properties austenitic steel and ferritic steel, which applies to the shipbuilding industry usually. In this paper, the OM, XRD and microhardness test methods are used to analyze the variation of submerged arc welded (SAW) joints with and without post weld heat treatment (PWHT). The research results show that the σ phase disappear in the fusion edge zone near heat affect zone (HAZ) and an increase in the welded center zone during the follow-up PWHT, while the amount of γ phase is decreased in the welded center zone with PWHT. A segregation distribution of some second phases is also found in the welded center zone after PWHT. There have two pick values of microhardness arise in the fusion edge zone and the welded center zone separately without PWHT. However, a maximum value of microhardness at the fusion edge zone near HAZ is disappeared and the other is still held at the welded center zone during PWHT. It can be attributed to the changes of second phases, element diffusions and particle segregation during PWHT. A developing mechanism is issued to demonstrate the second phases transferring of the 2205 DSS SAW joints by PWHT.     

Improvement of welding heat source models for TIG-MIG hybrid welding process

Tungsten inert gas-metal inert gas (TIG-MIG) hybrid welding process is an effective way to improve welding productivity and quality due to advantages of the two processes. Mathematical analysis is crucial to fundamentally understand this synergetic welding process. In this study, based on experimental visualization of arc behaviors, some assumptions are proposed to deduce adaptive plane and volumetric heat source models separately for each involved welding method first. The influence of torch angles on distribution of temperature and geometry of weld bead are calculated and compared with experimental results. It shows that this developed algorithm of heat source can be employed to accurately predict welding process whether the electrode gun is slanted backward or forward to the direction of welding. Then TIG-MIG hybrid welding process is simulated and analyzed without considering the attractive or repulsive force of two arcs. The characteristic of TIG-MIG welding process is discussed compared to single MIG. It lays the foundation for the further research on the interaction of the two arcs during TIG-MIG hybrid welding.     

不同施磷量(KH2PO4)作用对Cu、Zn在红壤中的迁移转化

为了比较不同施磷量对土壤中重金属Cu、Zn迁移转化的影响,采用土壤柱进行室内淋溶实验,研究常见的磷肥磷酸二氢钾在少量5 mg·kg-1,适量15 mg·kg-1以及过量25 mg·kg-1条件下对Cu、Zn在红壤中的淋溶效应.结果表明土壤施用磷酸二氢钾降低了土壤渗滤液的pH,不同施磷量对土壤渗滤液pH影响不大,在整个淋滤过程,渗滤液pH呈现上升的趋势.磷酸盐作用下重金属Cu在土壤中的迁移主要集中表层土壤中,而Zn逐渐向深层土壤中迁移.土壤深层渗滤液中Cu、Zn浓度均比较低,对浅层地下水的危害性不大.淋滤结束后,重金属主要以残渣态存在土壤中,重金属Cu残渣态的比例为60%左右,重金属Zn残渣态比例为40%左右.高浓度磷酸二氢钾作用下有利于重金属Zn从残渣态及有机结合态向交换态转化.     

微生物燃料电池恒电流预培养阳极生物膜分析表征

阳极性能是影响微生物燃料电池(Microbial Fuel Cells,MFCs)性能的关键因素之一,同时阳极的接种挂膜过程是影响微生物燃料电池启动效率的关键因素.因此,本课题组提出了预培养阳极作为微生物燃料电池的一种新型阳极的概念,在三电极体系下,通过外加恒定电流预培养阳极,在不同条件下对阳极表面进行电化学选择和生物膜驯化以丰富生物膜结构和厚度.结果表明,阳极的性能与预培养电流大小密切相关,预培养阳极CF-4i(外加4 A·m-2电流密度)通过循环伏安法、塔菲尔曲线、电化学阻抗谱测试,性能好于其他测试组及对照组,装配阳极CF-4i的微生物燃料电池能实现最大功率密度968.20 m W·m-2,是对照组的2.53倍.同时,通过共聚焦显微镜观察发现,生物膜大体分两层,外层的活细胞及内层的死细胞,外层活细胞长在内层死细胞之上.这种结构分布表明,阳极生物膜中的活细胞部分绝大多数都分布于生物膜的外侧,而不是均布于整个阳极生物膜中;同时这也表明不是整个阳极生物膜都具有新陈代谢活性,但死亡的细胞可以继续积累在电极表面附近,活的外层膜负责电流的产生,而内层的死细胞作为一种导电基质.     

秸秆压块与燃煤供热系统生命周期环境排放对比研究

为证明采用秸秆压块燃料替代煤炭进行供热的可持续性,对秸秆压块和燃煤供热系统的生命周期环境排放进行了对比分析.基于我国2012年投入产出表,构建了投入产出生命周期评价(IO-LCA)和过程生命周期评价(PLCA)相结合的混合生命周期评价(Hybrid-LCA)模型,核算了玉米秸秆压块和燃煤供热系统供应1 GJ热的生命周期CO2、SO2、NOx和PM2.5排放.结果显示,秸秆压块供热系统的生命周期CO2排放量为7 kg·GJ-1热,比燃煤供热排放减少121 kg.此外,秸秆压块供热系统比燃煤供热系统可以分别减少SO2排放98%、NOx排放76%和PM2.5排放58%.控制原料水分,通过减少原料收集和能源转化过程中的耗损,减少能源转化过程的电力消耗以及控制原料收集半径等可以有效改进秸秆压块供热系统环境表现.     

城市热岛效应下浅层土中混凝土的酸腐蚀试验研究

针对城市热岛效应引起城区浅层土地温场升高这一观测结果,采用室内快速模拟试验方法,对城区酸性土壤腐蚀混凝土材料的温度效应开展了试验研究.试验研究了在温度为5℃、20℃和40℃条件下,混凝土试样在酸浓度分别为0%、5%和10%的沙土介质中放置30 d、90 d后的抗压强度变化规律,并对混凝土试样在腐蚀过程中的腐蚀系数变化规...     

西方发达国家转移环境灾害的途径、原因及对策

发达国家的环境问题尤其是灾害问题的改善,在很大程度上是以将国内的致灾因素向发展中国家转移为条件的。发达国家主要通过资源掠夺资源引进、国际投资与国际贸易等途径向发展中国家转嫁各种灾害;世界经济秩序的不平等性、国际贸易与投资理论的不合理性、现行国际法规及规则的不完善性是发达国家转嫁灾害的主要成因;控制灾害的转嫁必须坚持历史责任原则和可持续发展原则两个基本原则,并采取相应对策。     

Transport of Sr2+ and SrEDTA2- in partially-saturated and heterogeneous sediments

Strontium-90 has migrated deep into the unsaturated subsurface beneath leaking storage tanks in the Waste Management Areas (WMA) at the U.S. Department of Energy's (DOE) Hanford Reservation. Faster than expected transport of contaminants in the vadose zone is typically attributed to either physical hydrologic processes such as development of preferential flow pathways, or to geochemical processes such as the formation of stable, anionic complexes with organic chelates, e.g., ethylenediaminetetraacetic acid (EDTA). The goal of this paper is to determine whether hydrological processes in the Hanford sediments can influence the geochemistry of the system and hence control transport of Sr(2+) and SrEDTA(2-). The study used batch isotherms, saturated packed column experiments, and an unsaturated transport experiment in an undisturbed core. Isotherms and repacked column experiments suggested that the SrEDTA(2-) complex was unstable in the presence of Hanford sediments, resulting in dissociation and transport of Sr(2+) as a divalent cation. A decrease in sorption with increasing solid:solution ratio for Sr(2+) and SrEDTA(2-) suggested mineral dissolution resulted in competition for sorption sites and the formation of stable aqueous complexes. This was confirmed by detection of MgEDTA(2-), MnEDTA(2-), PbEDTA(2-), and unidentified Sr and Ca complexes. Displacement of Sr(2+) through a partially-saturated undisturbed core resulted in less retardation and more irreversible sorption than was observed in the saturated repacked columns, and model results suggested a significant reservoir (49%) of immobile water was present during transport through the heterogeneous layered sediments. The undisturbed core was subsequently disassembled along distinct bedding planes and subjected to sequential extractions. Strontium was unequally distributed between carbonates (49%), ion exchange sites (37%), and the oxide (14%) fraction. An inverse relationship between mass wetness and Sr suggested that sandy sediments of low water content constituted the immobile flow regime. Our results suggested that the sequestration of Sr(2+) in partially-saturated, heterogeneous sediments was most likely due to the formation of immobile water in drier regions having low hydraulic conductivities.     

Information technologies and the sharing of disaster knowledge: the critical role of professional culture

A comparative survey of a diverse sample of 96 US and Italian emergency management agencies shows that the diffusion of new information technologies (IT) has transformed disaster communications. Although these technologies permit access to and the dissemination of massive amounts of disaster information with unprecedented speed and efficiency, barriers rooted in the various professional cultures still hinder the sharing of disaster knowledge. To be effective the available IT must be attuned to the unique settings and professional cultures of the local emergency management communities. Findings show that available technology, context, professional culture and interaction are key factors that affect the knowledge transfer process. Cultural filters appear to influence emergency managers' perceptions of their own professional roles, their vision of the applicability of technology to social issues, and their perspective on the transferability of disaster knowledge. Four cultural approaches to the application of IT to disaster communications are defined: technocentric; geographic,; anthropocentric; and ecocentric.