Stabilization of heavy metals in MSWI fly ash using silica fume

The objective of this work was to investigate the feasibility and effectiveness of silica fume on stabilizing heavy metals in municipal solid waste incineration (MSWI) fly ash. In addition to compressive strength measurements, hydrated pastes were characterized by X-ray diffraction (XRD), thermal-analyses (DTA/TG), and MAS NMR (²⁷Al and ²⁹Si) techniques. It was found that silica fume additions could effectively reduce the leaching of toxic heavy metals. At the addition of 20% silica fume, leaching concentrations for Cu, Pb and Zn of the hydrated paste cured for 7 days decreased from 0.32 mg/L to 0.05 mg/L, 40.99 mg/L to 4.40 mg/L, and 6.96 mg/L to 0.21 mg/L compared with the MSWI fly ash. After curing for 135 days, Cd and Pb in the leachates were not detected, while Cu and Zn concentrations decreased to 0.02 mg/L and 0.03 mg/L. The speciation of Pb and Cd by the modified version of the European Community Bureau of Reference (BCR) extractions showed that these metals converted into more stable state in hydrated pastes of MSWI fly ash in the presence of silica fume. Although exchangeable and weak-acid soluble fractions of Cu and Zn increased with hydration time, silica fume addition of 10% can satisfy the requirement of detoxification for heavy metals investigated in terms of the identification standard of hazardous waste of China.     

塑烧管除尘器在冶金精轧线的应用

冶金精轧线烟气烟尘含油含水，采用传统的布袋除尘等方式难以治理。塑烧管具有刚性结构、高过滤效率、压降稳定、疏水疏油性、防静电等特性，适合于治理含油含水的烟气。塑烧管除尘器在冶金精轧线的应用取得了良好的效果。     

我国废钢铁资源的可持续利用政策

本文概述了我国废钢铁资源回收利用的现状以及钢铁工业对废钢铁资源的需求现状，用三种不同的模型预测了未来钢铁工业的发展对废钢铁资源的需求，提出了废钢铁资源可持续利用存在的问题和政策建议。     

Exposure Programme on Atmospheric Corrosion Effects of Acidifying Pollutants in Tropical and Subtropical Climates

Many national exposure programmes have been performed in tropical and subtropical climates during the last 50 years. However, ambitious programmes involving more than a few countries are scarce. In this paper a recently formed network of test sites is described involving 12 test sites in Asia (India, Vietnam, Thailand, Malaysia and China including Hong Kong) and four test sites in Africa (South Africa, Zambia and Zimbabwe). This effort is part of the 2001–2004 Swedish International Development Agency (SIDA) funded Programme on Regional Air Pollution in Developing Countries (RAPIDC). Corrosion attack after one (2002–2003) year of exposure (carbon steel, zinc, copper, limestone and paint coated steel) are presented together with environmental data (SO₂, NO₂, HNO₃, O₃, particles, amount and pH of precipitation, temperature and relative humidity) for all the test sites. The obtained corrosion values are substantially higher than expected for limestone, higher than expected for carbon steel and lower than expected for zinc compared to values calculated using the best available dose–response functions.     

节能减排 实现钢铁企业可持续发展

通过对钢铁行业消耗水资源及产生污染情况进行分析，阐述了目前钢铁行业为节能减排而采取的管理、技术、污染治理措施，以达到减少废水外排量、降低污染物浓度、降低新水消耗的目的，对钢铁行业废水回用中尚存和潜在的工艺、设计问题进行了讨论，同时提出了通过清洁生产、优化工艺结构来解决问题的措施和建议，确立了企业近期和长期的节能减排任务目标。     

连续退火机组氮气窒息事故分析及预防对策

介绍了某冷轧厂连续退火机组发生的一起氮气窒息事故,分析了水淬槽氮气产生的机理、事故发生的原因,提出了预防氮气窒息事故的对策措施.     

钠盐量影响下DD6单晶高温合金的高温热腐蚀规律研究

目的 开展镍基单晶高温合金DD6在950 ℃下的热盐腐蚀试验(95%Na2SO4+5%NaCl)，探明涂盐量和涂盐方式(周期涂盐和单次涂盐)对DD6高温热腐蚀的影响规律和机理。方法 结合扫描电子显微镜、X射线能量色散谱、X射线衍射等设备，对不同涂盐量及涂盐方式下DD6的表面及横截面形貌进行观察分析，分析不同涂盐量和涂盐方式下DD6的高温热腐蚀机理。结果 DD6在950 ℃下主要发生碱性熔融热腐蚀，同时伴随氧化、硫化和氯化等过程。高温热腐蚀使得DD6合金表面生成的保护性氧化膜被熔融态的腐蚀介质破坏，导致O、S、Cl等外部元素通过氧化膜的缺陷进入DD6基体中，在合金的亚表面发生内氧化、内硫化以及内氯化反应，横截面上出现明显的腐蚀层，其主要由氧化物以及硫化物组成。随着热腐蚀的进行，DD6表面物质发生了剥蚀，沉积盐量的增加导致剥蚀现象越加严重，合金内部致密的组织结构也被破坏，横截面上出现了大量孔洞、裂纹等缺陷。在相同涂盐量下，周期涂盐法使得DD6的腐蚀程度高于单次涂盐法。结论 DD6高温热腐蚀行为与涂盐量及涂盐方式密切相关，相同涂盐方式下，涂盐量越大，DD6热腐蚀更加严重。涂盐量一定时，周期涂盐法使得DD6的热腐蚀剧烈程度大于单次涂盐法，且DD6在上述热腐蚀条件下均发生剥蚀破坏。     

SRHSC梁主要设计参数损伤敏感度分析

以型钢高强混凝土(SRHSC)梁为研究对象,结合SRHSC梁受力机理及承载能力的试验研究成果,提出了极限状态下的承载能力是评价梁力学性能的关键指标,将损伤前后梁正截面抗弯承载力之比和斜截面抗剪承载力之比的均值作为自变量,给出了SRHSC梁损伤表征函数,并借助"预定损伤法",揭示了主要设计参数对SRHSC梁损伤演化的影响规律。研究成果将为建立地震激励下SRHSC框架结构楼层损伤模型提供理论和数据支持。     

L型钢管混凝土芯柱耐火极限研究

火灾高温对结构安全有显著影响,为研究等肢L形钢管混凝土芯柱的耐火极限及其影响因素,利用ABAQUS软件建立合理的高温反应分析模型,在验证模型可靠性基础上,分析了荷载比、截面边长、长细比、荷载偏心率、含钢率等对L形钢管混凝土芯柱耐火极限的影响。研究结果表明:在一定参数范围内,荷载比和截面边长是构件耐火极限的主要影响参数,荷载比越小,截面边长越大,构件的耐火极限越高;长细比和荷载偏心率对其影响较大,长细比和荷载偏心率越小,构件的耐火极限越高;含钢率对其影响不显著。结果可为异形钢管混凝土芯柱的抗火安全设计提供参考。     

云南昌宁玉地里温泉水文地球化学特征及形成模式

以水化学及同位素技术为基础,对昌宁县玉地里温泉的地质及地热特征进行了研究,并取得了一些重要的认识.通过对比研究该温泉地下热水1980年和2012年的水文地球化学数据,发现经过30多年的循环演化,其水化学类型仍为HCO3-Na型.δD和δ18O同位素为该温泉首次获得,数据显示地下热水具有现代大气降水的氢氧同位素组成特征,属断裂带对流型深循环低温地下热水系统,其补给源区位于东部和南部山区,热储层和盖层的构造及岩性特征与地下热水的深循环和化学组成有着密切联系.