示波极谱滴定法测定工业废水中的硫化物

在pH为5.5的醋酸-醋酸钠-氯化钾底液中,用Cu~(2+)离子沉淀硫化物,过量的Cu~(2+)离子用标准8-羟基喹啉溶液回滴,以8-羟基喹啉在单微铂电极示波极谱图上的敏锐切口指示滴定终点。废水的色度、浊度等对测定不产生干扰,无须进行预蒸馏处理,操作简便、快速。方法的相对偏差小于1.0％,变异系数小于0.6％,水样的加标回收 率为97—103％。     

加快建立中国社会主义市场经济下的工业环境管理新模式

本文论证社会主义市场经济下环境管理模式与推行清洁生产工艺(无废、少废及高效转换工艺)的关系,剖析市场经济国家环境管理模式的精髓,密切结合推行工业生产全过程控制(包括环境标志这种反向控制手段),提出加快建立中国社会主义市场经济下的工业环境管理新模式。      

基于资源环境承载力的武汉市三大万亿集群产业发展策略研究

资源环境是城市的基础性资源,对经济社会发展具有支撑与约束作用,为加快实施武汉市光电子信息、汽车及零部件和大健康3个万亿级产业集群建设,推动制造业高质量发展,结合武汉市工业发展和资源环境利用现状,计算和评估三大万亿产业经济发展指标、资源消耗指标和污染排放指标,提出三大万亿产业集群发展策略建议.     

TS-35型氨法脱硫工业化试验及其经济性分析

对TS 35型氨法脱硫工艺进行了系统的工业化试验研究 ,该脱硫工艺对原有锅炉参数影响小 ,氨水消耗量少 ,阻力小 ,能耗低 ,脱硫效率可达 80 % ,几乎无废水排放 ,适用于中小型锅炉的脱硫 ,但有可能会加剧锅炉尾部设备的腐蚀。对于大型锅炉 ,必须考虑副产品硫酸铵的销路和价格问题。通过经济性分析 ,得出目前实施的排污收费制度存在一定的弊病 ,有必要完善以总量控制为目标的排放许可权交易制度     

Carcinogenic effect of potential toxic metals in school children through contaminated drinking water around the industrial area of Pakistan

Due to papulation increase in Pakistan the demand of drinking water increased day by day. After the industrial grooming the wastewater producing harmful effect on the surrounding area of industries and drinking water contamination increased. Pakistan is on 82 amongst the 125 countries of the word having drinking water problem. Different parameter set by World Health Organization (WHO) and Pakistan Environmental Protection Agency (Pak-EPA) of hazard dimension index (HD) and Lifetime Cancerogenic risk Calculation (LFCR) of Potentially toxic metals that are As, Cd, Cr, Ni, Pb (PTMs) are higher, and the school age children are under high risk of cancer. All the drinking constraints set by regulating authority is fully neglected by inopportune human process by solid waste dumping and houses and industrial disposal with any proper treatment. This study discusses all the HD and LFCR parameter in three age group children, male and female through drinking water around the Hattar Industrial Estate (HIE) in Pakistan. In children and women more HD and LFCR thread than the adult man. The overall result shows that the HD risk is higher than the LFCR due to the PTMs in drinking water only HD is exceed from the limit of WHO and Pak-EPA. If there is no proper arrangement take place for the removal of As and PTMs from the industrial wastewater and drinking water than within few years all the population around the study area effected with different type of cancer.     

我国典型钢铁工业城市夏季臭氧污染来源解析研究

邯郸与其周边城市相比,臭氧(O3)污染最为严重.基于观测数据分析夏季邯郸O3浓度的时空特征,结果显示:观测期间邯郸O3超标天数比率为86.7％,各区县O3浓度分布存在差异,高温、低湿和偏南贴地气团传输是此次O3连续污染的主要成因.继而,以CAMx-OSAT模型模拟方法进行O3来源解析,溯源分析显示:邯郸O3污染具有明显...     

工业园区产业规划循环经济模式分析与改进研究——以银川望远工业园区开展循环经济模式为例

循环经济是实现工业园区可持续发展的最佳模式,概述了循环经济理论和工业园区开展循环经济的最佳模式—生态工业园的概念,结合银川望远工业园区循环经济实施方案,对方案进行了分析和论证,并提出该工业园区建设生态工业园的进一步循环经济模式。     

水泥旋窑并行处理城市污水厂污泥的污染物排放研究

通过重庆某水泥厂的工业试验,测定了水泥旋窑并行处理城市污水厂污泥的烟气参数及污染物排放指标,分析了并行处理污泥对旋窑烟气的影响程度及各项指标之间的相关性。结果表明：①在污泥添加速率增大时,烟气流速、排气量、含氧量、空气过剩系数、HF和SO₂等排放浓度均随之增加,粉尘、NO_x排放浓度基本保持不变,HCl排放浓度下降,CO排放浓度先剧增后缓慢下降,而总烃排放浓度无明显规律;②污泥添加速率与SO₂排放浓度、烟气流速与排气量、含氧量与空气过剩系数、总烃浓度与SO₂排放浓度、烟气流速与总烃浓度呈显著正相关,污泥添加速率与HCl浓度、SO₂浓度与HCl浓度、NO_x与总烃浓度呈显著负相关;③烟气排放的污染物主要来自煤的燃烧,各指标之间的相关性主要表现为煤耗量增加而引起的连锁效应,但污泥本身在高温条件下燃烧产生的污染物较少,由污泥燃烧产生的污染物之间的相关性较小;④污泥添加速率达到2.4 t/h时,水泥旋窑并行处理城市污水处理厂污泥过程中所有指标均满足国家及相应的控制标准,但其参数优化及污染物控制极为复杂,该方法处理污泥需要进行深入研究才能在工业上应用。     

旅游发展价值取向与制度变革：美国国家公园体系的启示

通过对旅游发展的价值取向与管理体制分析发现,美国国家公园体系让国民享受到保护较好的遗产资源和舒适生态的游憩环境,国家公园提供的国民精神教育与实在的公益性服务提高了国民的凝聚力。相比而言,我国国家级保护区体系缺乏统一协调的发展理念、管理部门职能交叉、法律基础薄弱、管理及维护经费无稳定保障、公共服务意识缺失。因而,我国必须改变保护区内以经济利益为核心的旅游发展价值取向,建议对现有制度作如下调整：严格规范准入机制,重新梳理国家级保护区名录;完善现有立法,切实保护各类具有国家意义的遗产资源;逐步推进大部门体制改革,形成统一化管理的国家级保护区体系;启动淘汰机制限制保护区的数量扩张,将中央财政集中到确需保护的保护地;推出原住民资助计划,推进文化保护与社会公平;提高保护区体系从业人员素质,为各保护区建立具有科学性和教育性的解说系统,发挥国家级保护区体系对国民精神教育的重大作用.     

Changes in the structure of chortobiont invertebrate community exposed to emissions from a copper smelter

The aboveground phytomass of meadow plants and the density of chortobiont invertebrates in secondary upland meadows were estimated using a biocenometer in three areas differing in the level of pollution with emissions from the Middle Ural Copper Smelter (Revda, Sverdlovsk oblast) in 2006 and 2007. As the smelter is approached, the total amount of phytomass (dry weight) decreases by a factor of 1.3–1.9, with the proportion of grasses reaching 100%; the total abundance of invertebrates increases two-to threefold due to sucking phytophages, which account for up to 80% of the invertebrate community. The abundance of gnawing phytophages near the smelter is reduced, with some taxa entirely missing (e.g., mollusks and phalangiid harvestmen). Rearrangements in chortobiont community structure are attributable to changes in the physiological state of plants and in the species diversity and architecture of the herbaceous layer, with consequent modification of hydrothermal conditions in it, as well as by the direct toxic effect of heavy metals.