Remediation of Cu and As contaminated water and soil utilizing biochar supported layered double hydroxide: Mechanisms and soil environment altering

Preparing materials for simultaneous remediation of anionic and cationic heavy metals contamination has always been the focus of research. Herein a biochar supported FeMnMg layered double hydroxide (LDH) composites (LB) for simultaneous remediation of copper and arsenic contamination in water and soil has been assembled by a facile co-precipitation approach. Both adsorption isotherm and kinetics studies of heavy metals removal by LB were applied to look into the adsorption performance of adsorbents in water. Moreover, the adsorption mechanisms of Cu and As by LB were investigated, showing that Cu in aqueous solution was removed by the isomorphic substitution, precipitation and electrostatic adsorption while As was removed by complexation. In addition, the availability of Cu and As in the soil incubation experiments was reduced by 35.54%–63.00% and 8.39%–29.04%, respectively by using LB. Meanwhile, the addition of LB increased the activities of urease and sucrase by 93.78%–374.35% and 84.35%–520.04%, respectively, of which 1% of the dosage was the best. A phenomenon was found that the richness and structure of microbial community became vigorous within 1% dosage of LB, which indirectly enhanced the passivation and stabilization of heavy metals. These results indicated that the soil environment was significantly improved by LB. This research demonstrates that LB would be an imaginably forceful material for the remediation of anionic and cationic heavy metals in contaminated water and soil.     

锅炉烟气湿法除尘风机带水问题及治理对策

文章从湿法除尘机理入手，分析了冲激式除尘系统和水膜除尘系统风机易带水的原因，并有针对性地提出了解决风机带水的几种方法，这些方法经实践证明效果良好，有的已获国家专利技术。     

Restructuring water industry in China: towards sustainable urbanization

１　ＩｎｔｒｏｄｕｃｔｉｏｎＩｎｄｕｓｔｒｉａｌｉｚａｔｉｏｎａｎｄｕｒｂａｎｉｚａｔｉｏｎａｒｅｔｗｏｍａｉｎａｓｐｅｃｔｓｏｆｅｃｏｎｏｍｉｃｄｅｖｅｌｏｐｍｅｎｔ．Ｃｈｉｎａｈａｓｂｅｅｎｕｎｄｅｒｇｏｉｎｇｔｈｅｓｅｃｏｕｒｓｅｓ．ＩｎｔｈｅｐｒｏｃｅｓｓｏｆＣｈｉｎｅｓｅｕｒｂａｎｉｚａｔｉｏｎ，ｔｈｅｐｒｏｐｏｒｔｉｏｎｏｆｕｒｂａｎｐｏｐｕｌａｔｉｏｎｉｎｔｏｔａｌｐｏｐｕｌａｔｉｏｎｉｎｃｒｅａｓｅｓｆｒｏｍ２５－８１％ｉｎ１９８８ｔｏ２９－９２％ｉｎ１９９７（ＳＳＢ，１９９０；…     

铜基催化剂上甲苯深度氧化的机理分析

运用浸渍法制备了一系列CuO/γ-Al2O3催化剂,利用FTIR、MS、XRD等技术研究了甲苯在该催化剂上的深度氧化的性能及反应机理。初步讨论了活性氧化铝上铜的最佳负载量,铜在催化剂中的作用,以及甲苯在该催化剂上不同条件下反应的中间产物和最终产物及其产生机理。     

高浓度甲基橙湿式过氧化氢氧化及机理初探

采用湿式过氧化氢氧化法 (WPO)处理高浓度偶氮染料甲基橙溶液 ,考察了多种因素对去除效果的影响 ,结果表明 ,对于 4 0 0mg L的甲基橙溶液 ,其最佳处理条件为 :温度 16 0℃ ,H2 O2 浓度 33mg L ,Fe2 + 浓度为 91 2mg L ,处理后脱色率在 95 %以上。对比废水处理前后紫外光谱与红外光谱图的变化 ,说明染料分子结构中的偶氮键发生断裂 ,破坏了分子结构的偶氮 -苯环共轭发色体系 ,从而达到了脱色的目的     

化工项目的环境风险评价探析——以甲基丙烯酸甲酯工程为例

风险评价是化工项目环境影响评价的重点工作之一,结合对MMA生产过程中工艺过程及产污环节进行解析,了解原辅料及主副产品的理化特性,通过对工程潜在的环境风险环节进行识别和风险类型确定,从而科学准确地进行风险源项分析,以故障树方式确定事故发生的最大概率,进而完成各种事故状态下的后果影响分析,并根据事故产生的后果,提出防范和减缓事故发生后的风险,从组织措施、技术措施等诸多方面提出风险管理方案和应急防范预案,来保障事故一旦发生对环境的影响降低到最小程度.     

环太平洋陆缘成矿带区段对比及中国东南找矿思路

环太平洋陆缘弧系按其演化历史不同可分为挤压型、盆岭型和裂解型三种。不同类型弧系的不同区段金属成矿分带互有差别,甚至相反,其主要原因在于:1.构造演化历史不同,板块俯冲的势态不同;2.火山岩系列和火山岩组合,花岗岩成因类型及其发育程度和分布特征不同;3.地壳厚度和结构、基底杂岩的性质、基底构造特点和基底所赋存时代较老的金属矿化不同。在对比环太平洋成矿带各区段金属成矿特征的基础上,提出中国东南Au、Cu找矿的战略目标应在浙中闽西,江南古陆南缘和长江中下游;矽卡岩型Pb-Zn-Ag矿在浙闽沿海火山岩区有一定远景;裂谷式火山构造洼地可成为浅成热液贵金属和有色金属矿化的远景地段。     

水溶液中邻二氯苯的超声去除

研究了超声辐照技术去除模拟废水中的邻二氯苯的效果和影响因素,包括超声电功率、初始浓度、溶液初始pH值、空气曝气以及自由基抑制剂等;研究结果表明,超声辐照去除邻二氯苯主要以空化泡内的高温热解为主,并分析了邻二氯苯超声去除的途径和机理。     

PXW型摆辗机摆动机构运动学问题初探

给出了PXW型摆辗机摆头运动机构的机构运动简图,并据此认为具有多种摆头运动轨迹之摆辗机摆杆轴线上除顶点以外的各点只能是作球面运动,因而以往在摆头运动轨迹分析中将其简化为平面杆系势必引入误差.注意到这一点将有助于摆辗机的结构设计和对摆辗加工中应力-应变的分析.     

低浓度硝基苯标准样品的考核

提出了在四级站的考核项目中，在考核低浓度硝基苯标准样品时通过改进：曲线绘制方法、取过滤液方法、调pH值方法、标样稀释方法等手段提高考核结果的准确性。