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31.
In multiphase systems capillary pressures play a significant role on fluid movement and retention. The facility to predict
the effect of different thermal remediation strategies requires the knowledge of the effect of temperature on capillary pressure-saturation
relationships in the soils.
The objective of recent study was (a) to develop a technique for routinely measuring the pressure-saturation curves of soil
samples saturated with a nonpolar liquid at different regulated temperatures (b) to build a database using the measured pressure-saturation
curves and the physical, chemical properties of the model soils (c) to establish the dependence of nonaqueous phase liquid
retention on the soil properties and the temperature.
The retention curves (extraction isotherms) with nonaqueous phase liquid were determined using a modified
pressure plate extractor. The wetting phase was a non-aromatic hydrocarbon distillation product. Pressure plates were designed and constructed in
the laboratory of our department. The temperature was held constant at 20, 40 and 60 ∘C.
Statistical analysis was performed involving selected soil parameters and the measured nonaqueous phase liquid retention data.
The results show that knowing some easily measurable soil parameters (bulk density, particle size distribution, humus and
lime content) we can estimate the nonaqueous phase liquid retention of the soils. The measured “extraction isotherms” provide
essential information about the temperature-dependency of pressure-saturation curves. 相似文献
32.
33.
通过电化学试验方法对X70钢在NaHCO3溶液中的腐蚀行为进行了研究.实验结果表明,当NaHCO3质量分数低于0.10%时,极化曲线呈现阳极活化溶解过程,高于0.10%时阳极极化出现钝化过程,并且在-0.6 V(vs.SCE)左右出现了一个新的小电流峰.通过对交流阻抗谱分析发现,高频区均是由略偏离半圆的容抗弧组成,并且实部有所收缩.HCO3-的还原反应在阴极过程中起主要作用,整个过程受极化控制.X70钢在NaHCO3溶液中的腐蚀速度随着NaHCO3质量分数的增大而增大,在试验结束后,对试样表面的腐蚀形貌进行了观察,并利用XRD分析出腐蚀产物主要为FeO(OH)和Fe3O4. 相似文献
34.
基于双指标多等级的土壤重金属生态风险评价 总被引:1,自引:0,他引:1
采用土壤中重金属的全量和有效态双重指标,建立基于多等级综合评估的土壤中重金属生态风险评价模型,将联合概率曲线法引入土壤评价模型,分析重金属暴露浓度与毒性数据的概率分布,考察重金属对土壤生物的毒害程度,从而确定土壤中重金属对于生态系统的风险。建立从简单到复杂的多等级综合评价方法,表征重金属的污染等级、浓度效应、多种重金属污染物的协同效应、不同重金属的毒性效应和土壤对不同重金属污染物的敏感性。选择典型地区采集有代表性的土壤样品,测定不同重金属的总量和有效态,验证评价模型的实用性和评价分级的合理性。旨在解决土壤重金属风险评价的方法学问题,为土壤环境质量管理提供支持。 相似文献
35.
Albert Rango Victor van Katwijk 《Journal of the American Water Resources Association》1990,26(1):135-144
ABSTRACT: The snowmelt-runoff model (SRM) was used to produce accurate simulations of streamfiow during the snowmelt period (April-September) for ten years on the Rio Grande Basin (3419 km2) near Del Norte, Colorado, U.S.A. In order to use SRM in the forecast situation, it was necessary to develop a family of snow cover depletion curves for each elevation zone based on accumulated snow water equivalent on April 1. Selection of an appropriate curve for a particular year from snow course measurements allows input of the daily snow cover extent to SRM for forecast purposes. Data from three years (1980, 1981, and 1985) were used as a quasi-forecast test of the procedure. In these years forecasted snow cover extent data were input to SRM, but observed temperature and precipitation data were used. The resulting six-month hydrographs were very similar to the hydrographs in the ten simulation years previously tested based on comparisons of performance evaluation criteria. Based on this result, the Soil Conservation Service (SCS) requested SRM forecasts for 1987 on the Rio Grande. Using the same procedure but with SCS estimated temperature and precipi-tation data, SRM produced a forecast hydrograph that had a r2= 0.82 and difference in seasonal volume of 4.4 percent. To approximate actual operational conditions, SRM computed daily flows were updated every seven days with measured flows. The resulting forecast hydrograph had a R2= 0.90 and a difference in volume of 3.5 percent. The method developed needs to be refined and tested on additional years and basins, but the approach appears to be applicable to operational runoff forecasting using remote sensing data. 相似文献
36.
Louis H. Motz 《Journal of the American Water Resources Association》1990,26(2):233-239
ABSTRACT: A drain function and set of type curves were defined for the mathematical solution that represents one-dimensional flow under nonsteady conditions in a leaky aquifer for the constant drawdown boundary condition. A match point procedure was developed for determining the aquifer parameters transmissivity, storage coefficient, and leakance based on the drain function and type curves. Use of the procedure is illustrated by an example that utilizes simulated aquifer drawdowns and flowrate data. The drain function and type curves developed in this investigation include the effects of leakage for the constant drawdown boundary condition, which is not included in the existing drain function and type curve found in the literature. Thus, a new set of type curves was developed that can be used to analyze drawdowns for one-dimensional flow in a leaky aquifer with constant drawdown at a line sink. Applications would include flow to a canal or river, drainage of agricultural lands, and dewatering associated with strip mining operations. 相似文献
37.
将UBET用于求解压缩圆环问题 ,可简便快速地取得上限解 ;进而采用该解绘制塑性加工中测量摩擦系数的理论校准曲线。对中性层的位置进行了精确求解 ;分析了绘制理论校准曲线时 ,总压缩量、压缩步长量等参数对其结果的影响 相似文献
38.
We analyzed the long-term behavior of breakthrough curves (BTCs) and temporal moments of a solute subjected to Freundlich equilibrium sorption (s = kc(n)). For one-dimensional transport in a homogeneous porous medium, we derived a power-law relation between travel time, tau, and solute displacement, chi, with the exponent being equal to the Freundlich n exponent. The mean solute velocity, derived from the first time moment, was found to change as tau(n-1). For n values larger than 0.66, the second time moment could be related to c chi(2/n), where c is a constant. An approach based on the use of a critical concentration was developed to estimate the presence of the asymptotic regime in the tail of the BTC. This approach was tested successfully using numerical case studies. One-dimensional numerical simulations with varying values of k, n and initial mass were run to verify the closed form analytical expressions for the large time behavior of temporal moments and the tailing part of breakthrough curves. Good agreement between the slope of the tailing part of log-log transformed BTCs and the predicted slope using asymptotic theory was found. Asymptotic theory in general underestimated the magnitude of the concentration in the tail. The quality of the estimated concentrations in the tail improved for small values of the dispersivity. Experimental BTCs of uranin and benazolin were analyzed in combination with sorption/desorption batch experiments using asymptotic theory. A good agreement between the value of n parameter derived from desorption experiment with benazolin and the value of the n parameter derived from the tail of the BTC was found. 相似文献
39.
Bone charcoal is being developed as a treatment for decontaminating polluted water. In particular, its potential to adsorb metal species from contaminated water supplies is being examined. In this study, bone charcoal was used in batch and column experiments designed to investigate the sorption of two cationic metals Cu and Zn. The data from batch experiments fitted the Langmuir isotherm and so theoretical maximum binding capacities could be obtained. These values were compared with experimental values derived from the column experiments. The mechanisms involved in the immobilisation were also investigated. 相似文献
40.
Robert D. Gibbons 《Environmental and Ecological Statistics》1995,2(2):125-145
With increasing concern over chemicals that are potential health hazards at low levels, determination of limits of detection have undergone considerable scrutiny. Most traditional detection limit estimators suffer from extensive statistical and/or conceptual limitations. In this paper, traditional detection limit estimators are described and critically evaluated. Using the terminology of Currie (1968), methods are categorized into decision limits versus detection limits. The methods are further categorized into single concentration design versus calibration design methodologies. While the single concentration design methods are useful for fixing ideas and clarifying definitions, they are shown to be extremely limited in practice since dependence of variability on concentration can neither be estimated or incorporated. Calibration-based detection limit estimators are described, compared and contrasted. Generalizations to non-constant variance, multiple future detection decisions and simultaneous control of Type I and II errors are provided. The various calibration-based methods are illustrated using real data and experimental design issues for detection limit studies discussed. 相似文献