Removal of polycyclic aromatic hydrocarbons from aqueous solution by raw and modified plant residue materials as biosorbents

Removal of polycyclic aromatic hydrocarbons （PAHs）, e.g., naphthalene, acenaphthene, phenanthrene and pyrene, from aqueous solution by raw and modified plant residues was investigated to develop low cost biosorbents for organic pollutant abatement. Bamboo wood, pine wood, pine needles and pine bark were selected as plant residues, and acid hydrolysis was used as an easily modification method. The raw and modified biosorbents were characterized by elemental analysis, Fourier transform infrared spectroscopy and scanning electron microscopy. The sorption isotherms of PAHs to raw biosorbents were apparently linear, and were dominated by a partitioning process. In comparison, the isotherms of the hydrolyzed biosorbents displayed nonlinearity, which was controlled by partitioning and the specific interaction mechanism. The sorpfion kinetic curves of PAHs to the raw and modified plant residues fit well with the pseudo second-order kinetics model. The sorption rates were faster for the raw biosorbents than the corresponding hydrolyzed biosorbents, which was attributed to the latter having more condensed domains （i.e., exposed aromatic core）. By the consumption of the amorphous cellulose component under acid hydrolysis, the sorption capability of the hydrolyzed biosorbents was notably enhanced, i.e., 6-18 fold for phenanthrene, 6-8 fold for naphthalene and pyrene and 5-8 fold for acenaphthene. The sorpfion coefficients （Kd） were negatively correlated with the polarity index [（O＋N）/C], and positively correlated with the aromaticity of the biosorbents. For a given biosorbent, a positive linear correlation between logKoc and logKow for different PAHs was observed. Interestingly, the linear plots of logKoc-logKow were parallel for different biosorbents. These observations suggest that the raw and modified plant residues have great potential as biosorbents to remove PAHs from wastewater.     

论水处理工程中的节能

人们在污水处理厂的建设中对污水处理工艺的先进性、可靠性以及工程投资大小考虑较多,而对污水处理厂建成后的运营管理考虑较少,因而造成许多污水处理厂建成后由于运营成本过高而不能正常运行。从能耗角度出发,分析造成运行成本高的主要原因以及相应采取的措施。     

Microstructure of 2205 duplex stainless steel joint in submerged arc welding by post weld heat treatment

The 2205 duplex stainless steel (DSS) is of both good properties austenitic steel and ferritic steel, which applies to the shipbuilding industry usually. In this paper, the OM, XRD and microhardness test methods are used to analyze the variation of submerged arc welded (SAW) joints with and without post weld heat treatment (PWHT). The research results show that the σ phase disappear in the fusion edge zone near heat affect zone (HAZ) and an increase in the welded center zone during the follow-up PWHT, while the amount of γ phase is decreased in the welded center zone with PWHT. A segregation distribution of some second phases is also found in the welded center zone after PWHT. There have two pick values of microhardness arise in the fusion edge zone and the welded center zone separately without PWHT. However, a maximum value of microhardness at the fusion edge zone near HAZ is disappeared and the other is still held at the welded center zone during PWHT. It can be attributed to the changes of second phases, element diffusions and particle segregation during PWHT. A developing mechanism is issued to demonstrate the second phases transferring of the 2205 DSS SAW joints by PWHT.     

碱改性净水污泥对水中氨氮的吸附效能研究

采用氢氧化钠浸渍法改性净水污泥,研究了碱改性净水污泥对水中NH+4的去除性能.同时,考察了模拟废水pH、吸附剂投加量、NH+4初始浓度、吸附温度及吸附时间对吸附性能的影响.结果表明,当pH为弱酸性或中性,投加碱改性净水污泥20 g·L-1时,在室温下对初始浓度为50 mg·L-1的NH+4模拟废水振荡吸附120 min,可达到氨氮排放二级标准.将实验数据分别用吸附等温模型和动力学模型进行拟合,发现净水污泥对NH+4的吸附符合Langmuir模型和二级动力学模型,且净水污泥对氨氮的吸附包括静电吸引和离子交换两种作用机理.     

某麦芽生产厂废水管理与处理实践研究

麦芽生产过程包括清选、浸麦、发芽、烘干以及除根等工序,废水主要来自于浸麦、发芽等工序。某麦芽生产厂根据麦芽过程用水和废水产生的特点,采用设备改进、加强工艺管理、用水管理、废水回用、提高员工技能等措施,通过源头削减和生产全过程控制,合理调节生产用水,降低生产用水量和废水产生量,麦芽生产水耗指标为2.4 m3水/吨麦芽。麦芽废水采用SBR工艺进行处理,出水水质满足排放标准要求。该麦芽企业废水管理和处理经验为同行业提供了较好的案例。     

电化学法处理工业废水的现状与发展研究

随着工业的快速发展,如何对工业废水进行高效处理是我们需要解决的问题。电化学方法反应装置简单,反应效率高,不会产生二次污染。对中国工业废水目前常用的电化学处理技术的进展和应用进行了综述,包括电化学氧化、电化学还原、电絮凝、电渗析等内容,对国内外的研究成果的总结可知,电化学法对工业废水的处理效率较高,有一定的应用前景。同时对电化学法将来的重点研究方向提出了展望。     

壳聚糖絮凝机理及絮凝性能的影响因素分析

壳聚糖是一种天然高分子聚合物,被广泛地作为絮凝剂用于水处理过程。探讨了壳聚糖的三种絮凝机理。在水处理中,其絮凝性能的发挥受到pH值、壳聚糖的投加量、壳聚糖的分子量以及壳聚糖的脱乙酰度等因素的影响。     

石油化工催化剂生产过程中的职业病防治及应急处理

石化企业使用了大量的催化剂,催化剂开发、生产过程复杂,有许多原料和生产工艺,存在许多潜在的安全隐患和职业病危害因素。为预防催化剂生产过程中的事故,通过分析催化剂生产过程中的职业病危害分析,提出了相应的职业病防范及应急处置措施,加强催化剂生产过程中的职业病防治和应急处置能力,创造良好的经济、生态和社会效益,有效防止催化剂生产过程中发生安全事故和职业病。     

分散式污水处理设施集约化管理创新探索

随着近年来大量农村污水处理设施的新建,项目污水处理设施面广、点多、单体规模小、污染物浓度变化大、经营困难等问题凸显,如何突破困境找到一条相对适合分散式污水处理设施的运营管理十分必要。本文提出了集约化管理创新探索,在生产标准化管理、人力资源管理、安全管理、设备设施管理及物资管理等方面全方位的总结了运营管理经验,为分散式污水处理设施管理提供了参考和借鉴。     

探究城市污水处理项目的环境影响评价

水作为人类赖以生存的主要能源物质,随着社会综合水平的提高,各行业对水资源的需求越是急切。而现阶段城市中大量污水给环境带来很多不利影响,环保公司针对城市污水处理不断在技术上进行突破、完善,将智能化节能技术运用到城市污水处理中,使设备、资源得到充分利用,为人们用水条件带来更加充沛、丰富的保障与支持。为有效处理城市污水,争取在城市污水处理发挥更大作用,带动城市环境可持续发展。