碱激发胶凝材料及其固化Pb^2＋的试验研究

对碱激胶凝材料（碱-偏高岭土、碱-矿渣和碱-粉煤灰）与水-水泥体系固化Ph^2＋进行了试验研究,其中水-水泥体系为对比样。结果表明：对于相同稠度的碱激发胶凝材料,即使Pb^2＋含量达到2．4％,除了碱-粉煤灰的抗压强度略低外,其他都达到30MPa以上,满足填埋或做建筑基材的使用要求;与水泥相比,碱激发胶凝材料能显著降低重金属离子（Ph^2＋）浸出浓度,其规律性与其NH4交换容量大小的规律性一致,与其固化体的抗压强度的大小没有相关性。     

Processes affecting the movement of organochlorine pesticides (OCPs) between soil and air in an industrial site in Turkey

Soil and atmospheric concentrations, dry deposition and soil-air gas exchange of organochlorine pesticides (OCPs) were investigated at an industrial site in Aliaga, Izmir, Turkey. Current-use pesticides, endosulfan and chlorpyrifos, had the highest atmospheric levels in summer and winter. Summertime total (gas + particle) OCP concentrations in air were higher, probably due to increased volatilization at higher temperatures and seasonal local/regional applications of current-use pesticides. Particle deposition fluxes were generally higher in summer than in winter. Overall average dry particle deposition velocity for all the OCPs was 4.9 ± 4.1 cm s⁻¹ (average ± SD). ΣDDXs (sum of p,p′-DDT, p,p′-DDD, and p,p′-DDE) were the most abundant OCPs in Aliaga soils (n = 48), probably due to their heavy historical use and persistence. Calculated fugacity ratios and average net gas fluxes across the soil-air interface indicated volatilization for α-CHL, γ-CHL, heptachlorepoxide, cis-nonachlor, trans-nonachlor, and p,p′-DDT in summer, and for α-CHL, γ-CHL, trans-nonachlor, endosulfan sulfate, and p,p′-DDT in winter. For the remaining OCPs, soil acted as a sink during both seasons. Comparison of the determined fluxes showed that dry particle, gas-phase, and wet deposition are significant OCP input mechanisms to the soil in the study area.     

Polycyclic aromatic hydrocarbon (PAH) deposition to and exchange at the air-water interface of Luhu, an urban lake in Guangzhou, China

Urban lakes are vulnerable to the accumulation of semivolatile organic compounds, such as PAHs from wet and dry atmospheric deposition. Little was reported on the seasonal patterns of atmospheric deposition of PAHs under Asian monsoon climate. Bulk (dry + wet) particle deposition, air-water diffusion exchange, and vapour wet deposition of PAHs in a small urban lake in Guangzhou were estimated based on a year-round monitoring. The total PAH particle deposition fluxes observed were 0.44-3.46 μg m⁻² day⁻¹. The mean air-water diffusive exchange flux was 20.7 μg m⁻² day⁻¹. The vapour deposition fluxes of PAHs ranged 0.15-8.26 μg m⁻² day⁻¹. Remarkable seasonal variations of particulate PAH deposition, air-water exchange fluxes and vapour wet deposition were influenced by seasonal changes in meteorological parameters. The deposition fluxes were predominantly controlled by the precipitation intensity in wet season whereas by atmospheric concentration in dry season.     

不同市场结构组合下稀土最优开采路径研究

本文从价格视角将我国稀土市场结构的变化历程划分为不同阶段,分别从理论和现实视角上探讨了在国际、国内都是完全竞争市场,国际市场垄断、国内市场完全竞争,国际市场完全竞争、国内市场垄断,国际、国内都是垄断市场条件下稀土最优开采路径及最优耗竭时间,并通过设定参数判断其相对大小关系。发现在一定的假设条件下,开采前期当国内和国际市场都是完全竞争时,稀土最优开采量是最大的;当国内和国际市场都是垄断时,稀土最优开采量是最小的;其他两种市场情况下稀土最优开采量居于中间,当国际市场是稀土的主要消费地时,国际竞争-国内垄断市场情况下稀土最优开采量大于国际垄断-国内竞争市场情况下稀土最优开采量,反之,国际垄断-国内竞争市场情况下稀土最优开采量大于国际竞争-国内垄断市场情况下稀土最优开采量。     

农户从事生态循环农业意愿与行为的决定:市场收益还是政策激励?

发展生态循环农业是我国新时期转变农业发展方式的战略选择,农户是生态循环农业的经营主体和利益相关者,厘清农户参与生态循环农业的根本动机,对于制定有效的生态循环农业推广措施具有重要意义。文章基于湖北省391份农户调查数据,首先,在文献回顾的基础上提出市场收益、政策激励对农户生态循环农业从事意愿与行为影响路径的基本假设,并利用OLS方法分析市场收益和政策激励对农户从事生态循环农业意愿与行为的影响;其次,运用优势分析法评估市场收益类变量和政策激励类变量影响农户意愿与行为过程中的相对重要性;最后,通过交互效应检验市场收益类变量和政策激励类变量间的交互作用。结果表明:收入预期对农户从事生态循环农业的意愿与行为均有直接的积极影响,是促进农户从事生态循环农业的最重要的因素;焚烧秸秆惩罚政策和废弃物资源化补贴政策对农户从事生态循环农业的意愿有积极影响,沼气池建设补贴政策和废弃物资源化补贴政策对农户生态循环农业行为有促进作用;收入预期与废弃物资源化补贴政策在影响农户生态循环农业行为的过程中存在互补效应。本研究认为,市场收益是刺激农户采纳生态循环农业生产模式的首要因素,因此,要着力完善生态农业市场体系,增强生态农产品的市场竞争力,提升农户对生态循环农业的盈利信心;另外,政策激励对于农户采纳生态循环农业具有促进作用,应该做到约束与激励并行,同时注意加强农业政策的科学设计与落实执行。     

氨/硫铵法烟气脱硫技术特点及市场前景分析

通过对我国二氧化硫污染现状及控制要求的分析,提出了氨/硫铵法作为一种资源回收型脱硫方法,具有反应速度快、工艺流程简单、吸收剂利用率高、适用范围广及可实现资源回收利用的特点;以工程案例的形式分析了氨/硫铵法的技术经济指标,并对氨/硫铵法的应用前景和市场需求进行了预测。     

基于SCP模型的节能环保市场分析研究

从需求角度出发,区分了节能环保产业中三种不同类型的市场,然后以SCP模型为分析框架,对三种不同类型的市场结构、企业行为和绩效进行了分析和比较,归纳了节能环保产业中不同类型的市场所存在的问题和解决思路。     

Modeling Nutrient Transports and Exchanges of Nutrients Between Shallow Regions and the Open Baltic Sea in Present and Future Climate

We quantified horizontal transport patterns and the net exchange of nutrients between shallow regions and the open sea in the Baltic proper. A coupled biogeochemical-physical circulation model was used for transient simulations 1961-2100. The model was driven by regional downscaling of the IPCC climate change scenario A1B from two global General Circulation Models in combination with two nutrient load scenarios. Modeled nutrient transports followed mainly the large-scale internal water circulation and showed only small circulation changes in the future projections. The internal nutrient cycling and exchanges between shallow and deeper waters became intensified, and the internal removal of phosphorus became weaker in the warmer future climate. These effects counteracted the impact from nutrient load reductions according to the Baltic Sea Action Plan. The net effect of climate change and nutrient reductions was an increased net import of dissolved inorganic phosphorus to shallow areas in the Baltic proper.     

Influence of dissolved humic substances on the mass transfer of organic compounds across the air-water interface

The effect of dissolved humic substances (DHS) on the rate of water-gas exchange of two volatile organic compounds was studied under various conditions of agitation intensity, solution pH and ionic strength. Mass-transfer coefficients were determined from the rate of depletion of model compounds from an apparatus containing a stirred aqueous solution with continuous purging of the headspace above the solution (dynamic system). Under these conditions, the overall transfer rate is controlled by the mass-transfer resistance on the water side of the water-gas interface. The experimental results show that the presence of DHS hinders the transport of the organic molecules from the water into the gas phase under all investigated conditions. Mass-transfer coefficients were significantly reduced even by low, environmentally relevant concentrations of DHS. The retardation effect increased with increasing DHS concentration. The magnitude of the retardation effect on water-gas exchange was compared for Suwannee River fulvic and humic acids, a commercially available leonardite humic acid and two synthetic surfactants. The observed results are in accordance with the concept of hydrodynamic effects. Surface pressure forces due to surface film formation change the hydrodynamic characteristics of water motion at the water-air interface and thus impede surface renewal.     

改造集散市场 建设新型再生资源回收利用体系

目前“三位一体”（回收网点→分拣中心→集散市场）回收体系模式,因集散市场功能单一、产业链短,不能带动行业走向产业化。回收网点建设适应我国国情,而集散市场成为先进的完整的回收体系的短板。按照示范基地建设标准,把集散市场改造升级为拥有深加工利用产业链,拥有平台支撑优势,能够进行资源的规模化高值化利用的产业园区。把回收和利用两大产业板块融合一体,是再生资源产业化的发展方向。