Simultaneous determination of eight metabolites of organophosphate and pyrethroid pesticides in urine

A simultaneous method for quantifying eight metabolites of organophosphate pesticides and pyrethroid pesticides in urine samples has been established. The analytes were extracted using liquid–liquid extraction coupled with WCX solid phase extraction (SPE) cartridges. Eight metabolites were chemically derivatized before analysis using gas chromatography–tandem mass spectrometry (GC–MS–MS). The separation was performed on a HP-5MS capillary column (30 m × 0.25 mm × 0.25 µm) with temperature programming. The detection was performed under electro-spray ionization (ESI) in multiple reaction monitoring (MRM) mode. An internal standard method was used. The extraction solvent, types of SPE cartridges and eluents were optimized by comparing the sample recoveries under different conditions. The results showed that the calibration curves of the five organophosphorus pesticides metabolites were linear in the range of 0.2–200 μg/L (r² ≥ 0.992) and that of the three pyrethroid pesticides metabolites were linear in the range of 0.025–250 μg/L (r² ≥ 0.991). The limits of detection (LODs, S/N ≥ 3) and the limits of quantification (LOQs, S/N ≥ 10) of the eight metabolites were 0.008–0.833 μg/L and 0.25–2.5 μg/L, respectively. The recoveries of the eight metabolites ranged from 54.08% to 82.49%. This efficient, stable, and cost-effective method is adequate to handle the large number of samples required for surveying the exposure level of organophosphorus and pyrethroid pesticides in the general population.     

Moisture transfer modeling during solar drying of potato cylinders considering shrinkage

In the present work, the thin layer drying kinetics of potato during natural convection solar drying was investigated experimentally. Cylindrical potato samples with length 50 mm and varying diameter of 8, 10 and 13 mm were dried in an in-house designed and fabricated laboratory scale mixed-mode solar dryer. Thirteen different thin-layer mathematical models were fitted to the experimental moisture ratio (MR) data. The obtained results indicated that the Modified Page model could satisfactorily describe the drying curve of potato cylinders with higher value of R² and lower values of RMSE and χ². The shrinkage parameter is incorporated in the analytical diffusion model to study the moisture transfer mechanism of potato cylinders. It was observed that the values of effective diffusion coefficient (D_eff) and convective mass transfer coefficient (h_m) are overestimated in the range of 85.02–90.27% and 39.11–45.11% for the range of sample diameter examined, without considering the shrinkage effect in the mass transfer analysis. A Multiphysics approach was adopted in this study to get insight into the drying behavior of potato cylinders in terms of food-moisture interactions during the solar drying process. The predicted results of MR are in close agreement with the experimental data. Moreover, the anisotropic behavior of shrinkage as well as the moisture distribution inside the potato cylinder was very well described by Multiphysics model.     

京津冀地区环境资产负债表编制研究

环境容量资产的核算是自然资源资产负债表编制中的主要组成部分。本文基于环境容量提出京津冀地区环境资产负债表编制方法,阐明该地区环境资产负债表的编制内容、核算范围以及编制路径,对2013年该地区及13个城市的环境容量资产进行核算,并编制了实物量资产负债表。在此基础上,提出了京津冀地区降低环境资产负债的政策建议,指出我国环境资产负债核算工作逐步规范化、制度化的方向。结果表明,京津冀地区大气及水环境容量均处于严重负债状态,其中,主要大气污染物SO2、NOx和PM2.5环境容量资产负债率分别为-235%、-263%和-316%,主要水污染物COD和NH3-N环境容量资产负债率分别为-414%和-850%。本文研究成果可为京津冀地区资源环境与经济发展决策提供科学基础,同时也可为其他地区开展环境资产核算研究提供参考。     

东平湖高浓度污染水团的发生规律及监测研究

通过对东平湖污染水团的监测和分析 ,研究了污染水团生成的原因及规律 ,并对污染水团对水产养殖的危害做了调查。对防治污染水团的生成及提高东平湖的水质进行了探讨。     

持久性有机污染物环境多介质空间分异模型研究进展

环境多介质空间分异模型能够对持久性有机污染物(POPs)在环境多个介质中空间尺度上的迁移转化和分配过程进行准确、细致和接近真实的描述,是进行POPs的环境多介质归趋模拟和环境风险评价的重要工具.将环境多介质空间分异模型分为环境多介质质量平衡空间区划模型和大气化学传输模型,对目前几种常用的环境多介质空间分异模型GLOBO...     

Quantifying The Rainfall-Water Level Fluctuation Process in a Geologically Complex Lake Catchment

Abstact Simulating hydrologic processes in geologically complex environments is a difficult scientific task since it incorporates high level of uncertainty. Many studies have attempted to accurately quantify the rainfall-water level elevation relationship in freshwater bodies so as to predict flooding and drought events. For this purpose several types of models have been implemented including distributed, black box and conceptual models that often provide efficient results, depending on the availability of reliable data as well as on the level of understanding of the system. Nevertheless, in the particular effort, three different models have been used to describe the relationship between rainfall and water level elevation in Trichonis Lake during the period 1951–1997. A Transfer Function model, a Dynamic Linear Regression and a physically based model, consisting of the lake's water budget equation, its Digital Bathymetric Model and GIS algorithms. These models have been tested to assess their efficiency and applicability in a karstic environment and the aim of the study was to find the best modeling option for developing sustainable water management plans and establishing a flooding/drought warning system in the particular lake catchment. The results indicated that in areas with geologically complex conditions, simple, physically-based models operate better than mechanistic models which usually cannot describe adequately the complexity of the system     

荠菜叶挥发性成分分析

采用水蒸气蒸馏法对荠菜叶挥发油进行了提取。通过毛细管气相色谱—质谱联用法分离并鉴定了其化学成分,用气相色谱面积归一化法测定了各成分的相对百分含量,共分离确定了其中12种化合物,所鉴定化合物的含量占全油的65.62%,主要化学成分为：L-胍基琥珀酰亚胺（21.28%）、植醇（18%）、植酮（9.6%）、油酸（4.71%）、棕榈酸（3.97%）等。     

锅炉量化管理是企业挖潜节能的重要途径

通过对辽河油田公司有关企业开展清洁生产审核,总结出了燃料锅炉量化管理的方法。在自然对流烘干室改造、碱液浓缩炉改造、燃煤锅炉设计效率核准等实例中,该方法可昭示能耗大的"瓶颈"部位,进而为企业制定节能方案、提出具体的节能改造措施提供了科学依据。实践证明:实施锅炉量化管理是企业挖掘节能潜力的重要途径。     

Integration of traditional and innovative characterization techniques for flux-based assessment of Dense Non-aqueous Phase Liquid (DNAPL) sites

Key attributes of the source zone and the expanding dissolved plume at a trichloroethene (TCE) site in Australia were evaluated using trends in groundwater monitoring data along with data from on-line volatile organic compound (VOC) samplers and passive flux meters (PFMs) deployed in selected wells. These data indicate that: (1) residual TCE source mass in the saturated zone, estimated using two innovative techniques, is small ( 10 kg), which is also reflected in small source mass discharge ( 3 g/day); (2) the plume is disconnecting, based on TCE concentration contours and TCE fluxes in wells along a longitudinal transect; (3) there is minimal biodegradation, based on TCE mass discharge of  6 g/day at a plume control plane  175 m from source, which is also consistent with aerobic geochemical conditions observed in the plume; and (4) residual TCE in the vadose zone provides episodic inputs of TCE mass to the plume during infiltration/recharge events. TCE flux data also suggest that the small residual TCE source mass is present in the low-permeability zones, thus making source treatment difficult. Our analysis, based on a synthesis of the archived data and new data, suggests that source treatment is unwarranted, and that containment of the large TCE plume ( 1.2 km long,  0.3 km wide; 17 m deep;  2000–2500 kg TCE mass) or institutional controls, along with a long-term flux monitoring program, might be necessary. The flux-based site management approach outlined in this paper provides a novel way of looking beyond the complexities of groundwater contamination in heterogeneous domains, to make intelligent and informed site decisions based on strategic measurement of the appropriate metrics.     

Mercury cycling and species mass balances in four North American lakes

A mass balance model for mercury based on the fugacity concept is applied to Lake Superior, Lake Michigan, Onondaga Lake and Little Rock Lake to evaluate model performance, analyze cycling of three mercury species groups (elemental, divalent and methyl mercury), and identify important processes that determine the source-to-concentration relationship of the three mercury species groups in these lakes. This model application to four disparate ecosystems is an extension of previous applications of fugacity-based models describing mercury cycling. The model performs satisfactorily following site-specific parameterization, and provides an estimate of minimum rates of species interconversion that compare well with literature. Volatilization and sediment burial are the main processes removing mercury from the lakes, and uncertainty analyses indicate that air-water exchange of elemental mercury and water-sediment exchange of divalent mercury attached to particles are influential in governing mercury concentrations in water. Any new model application or field campaign to quantify mercury cycling in a lake should consider these processes as important.