用于湿法净化黑烟表面活性剂筛选的数学模型研究

湿法净化燃煤窑炉中的黑烟,关键在于表面活性剂对炭黑的润湿、增溶和降低表面张力作用.根据研究筛选的数学模型,计算AEO-9和SDBS混合表面活性剂溶液的亲水亲油平衡值HLB、临界胶束浓度CMC与胶束形成吉布斯自由能ΔG0mf.通过实验测得不同配比AEO-9和SDBS溶液的CMC和处于该CMC时黑烟的去除效率η,分析混合溶液中HLB、CMC、ΔG0mf与η的关系,建立新的数学模型.结果表明,理论CMC与实测CMC吻合度较好;HLB与ln[CMC]线性相关;ΔG0mf与η存在二次函数关系.降低CMC可以有效增大HLB,增加溶解度,减小形成胶束的吉布斯自由能,降低表面张力,使形成胶束的反应更容易自发进行,有效提高黑烟去除效率.     

Mercury removals by existing pollutants control devices of four coal-fired power plants in China

The mercury removals by existing pollution control devices in four coal-fired power plants of China were carried out based on a measurement method with the aluminum matrix sorbent.     

垃圾渗沥液调节池的出水工艺探讨

为了保证调节所需的容积,垃圾渗沥液调节池一般占地面积和池深均较大,如何将调节池内的渗沥液输送至渗沥液处理设施是工程实践中经常面对的问题.本文在对各种垃圾渗沥液调节池出水工艺进行介绍、分析和对比的基础上,对渗沥液调节池的出水工艺的选择提出了建议.     

气体稳定同位素比质谱法分析本底大气CO2的δ13C和δ18O

将商用MAT253稳定同位素比质谱仪、Airtrap高效预浓缩气体捕集阱与自加工16口自动进样器集成,建立了高精度气体稳定同位素比质谱分析系统,用于程序化自动分析本底大气CO2的δ13C和δ18O.气样分析时用工作标气定量并穿插目标气测定,还定期用实验室上一级标气对工作标气和参比气进行标校,以保证分析结果的可靠和可比.结果表明,利用不同稳定同位素比范围的标气重复进样测试,发现该系统对δ13C和δ18O的分析精度分别优于0.03‰和0.06‰,能基本满足本底大气CO2的碳氧稳定同位素比分析需求和WMO/GAW质量目标.     

利用第二缺氧段硝酸盐氮浓度作为MUCT工艺运行控制参数

以模拟生活污水为对象考察了第二缺氧段硝酸盐氮质量浓度(SNO-3)作为MUCT工艺运行控制参数的可行性.将进水COD质量浓度恒定为(290±10)mg.L-1,TN质量浓度恒定为(55±0.5)mg.L-1,TP质量浓度恒定为(7.0±0.5)mg.L-1,改变第二缺氧段硝酸盐氮质量浓度以比较各段出水TN和TP质量浓度.结果表明,SNO-3值显著影响着出水TN和TP质量浓度,控制内循环回流量维持SNO-3为2.5 mg.L-1,可实现MUCT工艺的最优控制.利用各段硝酸盐氮和TP平均质量浓度进行的物料平衡计算结果表明SNO-3是影响厌氧段释磷量、第一缺氧段和第二缺氧段硝酸盐氮反应量、第二缺氧段吸磷量的重要参数.     

Analysis of Soil and Water Balance on the Land Arrangement Function

Abstract

The natural supply of land resources is limited, but the economic supply may change along with social and economic development, and its size is decided bye nature and social and economic body conditions. When the supplying ability of land resources threatens the development of society and the conflict between people and land becomes tense, it forced people to improve land utilization and to increase the effective supply of land resources. The paper made an overall consideration on the characteristics of the irrigated farming and the frail ecological environment in Fuhai County, Altay Area, Xinjiang Uigur Autonomous Region and explored land arrangement planning as well as water resource planning and environmental protection. The paper evaluated natural resources, land utilization and water resource of the case study areas and focused on the spatio-temporal balance between the utilization of water and land resources. In the end the paper a feasible plan was made out for the land arrangement project.     

Towards an integrated framework for sustainable innovation

Sustainable innovation represents a current challenge for companies, as firms need to change the way they design, develop, produce and distribute products and services. Therefore, this paper proposes a new framework to be used as a reference guideline for organisations to define a roadmap, specific actions and projects to achieve sustainable innovation, integrating four key enablers. The first enabler is mass customisation (MC), which targets the identification and compliance with customers' specific needs and requirements in order to achieve customer‐driven design. At the same time, the sustainable development (SD) paradigm is taken into consideration, where for any new product or service, companies analyse the benefits, risks and impacts of not only economic factors, but also social and environmental implications. The third enabler is linked to the value network (VN), where innovations happen owing to the active collaboration and distributed knowledge of partners inside and outside the company. Finally, the fourth and last considers the complete product and service life cycle (PSLC), where the three sustainable elements are identified and analysed in each single business process. Two case studies, (footwear sector and water treatment plants) are described to show the validity and successful deployment of the proposed framework in real industrial scenarios.     

Energy analysis of algae-to-biofuel production chains integrated with a combined heat and power plant

ABSTRACT

This study examines the energy and mass balances of algae cultivation and different post-processing pathways. Flue gases and excess heat from a combined heat and power (CHP) plant are used in algae cultivation, with nutrients from municipal wastewater. In the studied pathways, algae are cultivated in open ponds and photobioreactors with or without artificial lighting. Algal mass is used for methane, biodiesel or ethanol production, or it is combusted in a boiler. Results show that in most process pathways energy output exceeds the energy consumption in processing, and the energy returns are approximately twice as large as the electricity input. A large fraction of input energy is low-temperature heat, while the products have a higher value. Energy outputs from different pathways are similar, but heat and electricity consumption in processing vary significantly. Supercritical water gasification pathway is identified as a possible future option, whereas lipid extraction pathways are suggested to be the most likely candidates for industrial scale operations.     

7种指示性多氯联苯混合标准样品量值不确定度研究

分析并评估了异辛烷中7种指示性多氯联苯(PCBs)混合标准样品的量值不确定度。通过分析PCBs纯品中结构相似物、水分、无机物等杂质的含量,采用质量平衡法对PCBs纯品的纯度进行了定值。结果显示,7种指示性PCBs纯品的纯度为98.24%~99.92%,纯度不确定度为0.08%~1.28%。采用称量-容量法制备了各组分浓度均为50.0 μg/mL的异辛烷中7种指示性PCBs混合标准样品,全面分析了各组分的量值不确定度来源,主要包括样品配制、均匀性和长期稳定性等引入的不确定度。结果表明,该标准样品中,7种指示性PCBs组分的合成扩展不确定度为0.7~1.7 μg/mL。该标准样品量值准确且具有计量溯源性,可为我国PCBs相关国际履约监测和新污染物监测提供有效支撑。     

高分辨质谱在环境科学领域应用综述

探究复杂环境介质中有机污染物分析检测新方法,建立复杂环境介质中可疑和非目标化合物的快速筛选及确证方案,已成为环境科学领域的研究热点。高分辨质谱仪（HR-MS）具有质量范围宽、扫描速度快、灵敏度高等优点,使其在环境科学领域得到广泛应用。综述了混合高分辨率质谱（Q-TOF/Q Orbitrap）等HR MS技术的特点和工作原理,基于目标化合物分析、可疑化合物分析以及非目标化合物分析这3类研究策略,阐述了HR-MS在环境研究、药品监管及生物代谢物研究等领域的应用现状,进而分析了现阶段HR MS在环境科学领域中的应用局限性和发展前景。