HgCl2对太湖不同季节优势藻生长的影响

为探讨HgCl₂对不同季节湖泊生态系统的影响,以太湖不同季节优势藻——舟形藻(冬季)和惠氏微囊藻(夏季)为对象,研究不同浓度的HgCl₂对2种优势藻生长的影响以及2种藻对HgCl₂的吸附能力. 结果表明:舟形藻对HgCl₂暴露刺激比惠氏微囊藻更为敏感,在c(HgCl₂)为1×10-9~1×10-7 mol/L的范围内,HgCl₂对惠氏微囊藻的生长表现出低浓度促进、高浓度抑制的效应;而对舟形藻则表现出明显的抑制作用,并且抑制作用随着c(HgCl₂)的升高而更加明显. 吸附试验结果表明,惠氏微囊藻对HgCl₂的吸附率为88.4%~98.8%,舟形藻为87.1%~97.5%,并且吸附率和吸附量均随着c(HgCl₂)的升高而逐渐增大,说明这2种藻对HgCl₂都有极高的吸附效应. 吸附了HgCl₂的藻成为一个潜在的汞蓄积库,可对水环境产生危害.      

Mercury distribution in the sediments of Ambarlı Port Area,Sea of Marmara (Turkey)

The purpose of this study is to investigate historical and current mercury (Hg) contamination in the surface and core sediments of the Ambarl? Port area. Textural parameters, total organic carbon (TOC), ²¹⁰Pb and total Hg (THg) contents were measured. Mercury contamination of the sediments was assessed on the basis of the enrichment factor (EF), anthropogenic factor (AF), index of geoaccumulation (Igeo) and corresponding sediment quality guidelines. Most surface sediment samples were also non-toxic with mercury concentrations below the effects range-low (ERL) value, but mercury levels at five stations were between ERL and effects range-median (ERM) values, where occasional adverse effects concerning risk analysis are expected. The EF and Igeo analysis showed that there was no significant mercury enrichment and contamination in the core sediment before the 1650s, but values increased from then onwards to 2009 (being especially accelerated in line with port activities from 1989), disclosing a serious ecotoxicological risk to sediment-inhabited marine organisms.     

Temporal variability in atmospheric Hg released from natural and anthropogenic sources in central Taiwan

From September 2011 to February 2012, ambient air particulate and particulate-bound mercury [Hg(p)] concentrations were measured, together with dry deposition using a cold vapor atomic fluorescence spectrometry (CVAFS) analyser, at two characteristic sampling sites in central Taiwan. Results from the sampling site at Westin Park indicated that the lowest particulate dry deposition and lowest average particulate concentrations in total suspended particles (TSP) occurred in September (29.70±7.47 μ g m^?2×min) and February (34.38±13.60 ng m^?3), respectively. Moreover, results from the Gung-Ming junior high school (airport) site, showed that the highest average particulate dry deposition and average highest particulate concentrations in TSP occurred in February (156.76±30.36 μ g m^?2×min) and January (125.49±9.51 ng m^?3), respectively, during the winter. The Dragon Steel Plant and Han-Shian Aerospace Industrial Development Corporation were both nearby. These factors led to the high Hg(p) concentrations at Taichung Airport (TA) compared with Westin Park. Local large suspended particulates from heavy traffic were the main reason for the high average Hg(p) deposition at Westin Park compared with TA in this study.     

Possible cause of inhibition of seed germination in two rice cultivars by heavy metals Pb2+ and Hg2+

Seeds of two rice cultivars (Oryza sativa) cv. PR-116 and Pant Dhan-12 subjected to heavy metal lead (Pb²⁺) and mercury (Hg²⁺) exposure showed an inhibition in germination percentage, shoot and root length, and lower fresh and dry weight after 7 days. Both Pb²⁺ and Hg²⁺ inhibited the solubilization process of starch due to reduction in α-amylase activity, which is also evident from greater starch content and reduced soluble carbohydrate content of endosperms of treated seeds of the two cultivars. Mercury was more tolerated by Pant Dhan-12 when grown under in vitro culture medium containing 2% sucrose. The inhibitory effect of Pb²⁺ on embryo growth was not only abolished but also accelerated by 2% sucrose. The inhibitory effect, however, was not significantly blocked in Hg²⁺-treated embryos grown in vitro in sucrose containing medium. Embryos did not grow normally in a medium devoid of sucrose in either case. Data indicated that Pb²⁺ inhibited germination and seedling growth by impairing the solubilization of endosperm starch without markedly affecting the embryo, while Hg²⁺ inhibited germination and seedling growth by damaging the embryo itself.     

Exposure assessment for mercury from consumption of marine fish in Iran

Seven species of marine fish in the Persian Gulf and three species of marine fish in the Caspian Sea were collected from the local wholesale market in Mashhad, Iran. The mercury (Hg) concentration in muscle samples was determined by atomic absorption spectrophotometry. High total Hg concentration was found in Anchovy sprat (2.04 ± 1.23 µg g^?1) and Whitecheek shark (1.26 ± 1.85 µg g^?1) and the lowest content was detected in common carp (0.24 ± 0.24 µg g^?1) and Caspian salmon (0.25 ± 0.08 µg g^?1). The mean Hg content in all samples was 0.91 ± 1.07 µg g^?1. All samples of Persian Gulf and one sample of Caspian Sea had mean Hg concentration above 0.5 µg g^?1, the level established by joint FAO/WHO on Food Additives. Results showed that the estimated weekly intake of total Hg by a 60 kg adult is below the provisional tolerable weekly intakes recommended by joint FAO/WHO on Food Additives. For prevention of health risks, populations in Iran need to consume fish in moderate amounts.     

Abstracts to forthcoming papers

Food is the major source of metal exposure for the nonsmoking general population. Food samples of plant and animal origin from Ismailia, Egypt, were analyzed for the content of cadmium (Cd), lead (Pb), chromium (Cr), zinc (Zn), and copper (Cu) using AAS. The Cr, Zn, and Cu concentrations were in the range of 1.7–249?µg?kg^?1 wet weight (ww), 2–66?mg?kg^?1?ww, and 0.5–3.46?mg?kg^?1?ww, respectively. The mean daily intake of Cr, Zn, and Cu was 28.9?µg day^?1, 8.55?mg day^?1, and 1.7?mg day^?1, respectively. The intake estimates are within the range of the recommended intake established internationally. Concentrations of Cd and Pb were in the range of 10–321?µg?kg^?1?ww and 31–1200?µg?kg^?1?ww, respectively. The weekly dietary intake for Cd and Pb (4.02 and 20.4?µg?kg^?1 b.w, respectively) is lower than the FAO/WHO PTWI. Bread is the foodstuff that provided the highest rate of Pb and Cd (62 and 46% of the daily intake) to adults in Ismailia city.     

Toxicity biomarkers among US children compared to a similar cohort in France: a blinded study measuring urinary porphyrins

The purpose of this blinded study was to evaluate potential environmental toxicity in a cohort of neurotypical children (n = 28) living in a suburban area of north-central Texas in the United States (US) with a comparable age- and gender-matched cohort of neurotypical children (n = 28) living in a suburban area of southeastern France using urinary porphyrin testing: uroporphyrin (uP), heptacarboxyporphyrin (7cxP), hexacarboxyporphyrin (6cxP), pentacarboxyporphyrin (5cxP), precoproporphyrin (prcP), and coproporphyrin (cP). Results showed significantly elevated 6cxP, prcP (an atypical, mercury-specific porphyrin), and cP levels, and increasing trends in 5cxP levels, among neurotypical children in the USA compared to children in France. Data suggest that in US neurotypical children, there is a significantly increased body-burden of mercury (Hg) compared to the body-burden of Hg in the matched neurotypical children in France. The presence of lead contributing to the higher levels of cP also needs to be considered. Further, other factors including genetics can not be completely ruled out.     

Contamination status of arsenic,lead, and cadmium of different wetland waters

The present investigation was conducted to determine the contamination status of arsenic (As), cadmium (Cd), and lead (Pb) in the wetland waters of Bhaluka in Bangladesh. Water samples were collected from 15 selected wetlands of Bhaluka region and analyzed using an atomic absorption spectrophotometer. Estimated results of three metals detected were As (7–80?µg?L^?1), Pb (0–86?µg?L^?1) and Cd (0–70?µg?L^?1) in water samples in all wetlands. The level of As in all investigated wetlands (93%) was higher than that of WHO recommended permissible limit of drinking water except Alanga wetland. However, As levels were higher than that recommended for livestock water quality levels. Eighty-seven percent of the investigated wetlands showed lower content of Pb than WHO recommended permissible limit of drinking water, but two wetland waters (Dohuria-1 and Chowdhuri) were polluted with higher Pb levels. Sixty-seven percent of the investigated wetlands displayed higher levels of Cd than WHO recommended permissible limit in drinking water. Dissolved organic material showed no significant difference among the 15 investigated wetlands water, but total dissolved solids was significantly greater. The condition of the water of all wetlands was basic pH. All water samples were applied to linear regression equation and correlation coefficients where values showed no significant differences. Data demonstrate that the estimated high metal concentrations of these ponds may contribute to bioaccumulation within plants, food grains and shrimp.     

Maternal transfer of mercury to the developing embryo/fetus: is there a safe level?

Mercury (Hg) exposure is ubiquitous in modern society via vaccines, fish/crustacea, dental amalgam, food, water, and the atmosphere. This article examines Hg exposure in the context of primary exposure to pregnant women and secondary exposure experienced by their unborn babies. Babies in utero are particularly at risk of higher Hg exposure than adults (on a dose/weight basis through maternal Hg transfer via the placenta), and are more susceptible to adverse effects from mercury and its biologically active compounds. It is, therefore, critical that regulatory advisories around maximum safe Hg exposures account for pregnant women and secondary exposure that children in utero experience. This study focused on standardized embryonic and fetal Hg exposures via primary exposure to the pregnant mother of two common Hg sources (dietary fish and parenteral vaccines). Data demonstrated that Hg exposures, particularly during the first trimester of pregnancy, at well-established dose/weight ratios produced severe damage to humans including death. In light of research suggestive of a mercuric risk factor for childhood conditions such as tic disorders, cerebral palsy, and autism, it is essential that Hg advisories account for secondary prenatal human exposures.     

Preliminary survey of pharmaceutical residues in some important Romanian rivers

A number of important rivers of Romania were investigated for pharmaceutical and antifungal residues. In a post target approach analysis, a single-stage, high-resolution mass spectrometry was successfully applied for the screening of 43 pharmaceuticals and fungicides in water, using U-HPLC-Exactive Orbitrap MS at 50,000 full width at half maximum resolution. Detection was based on accurate masses and retention times. The study confirmed the presence of pharmaceuticals and antifungals such as diclofenac, sulfamethoxazole, carbamazepine, trimethoprim, thiabendazole, and clotrimazole, in water. Diclofenac and carbamazepine were the most frequently detected (eight samples); concentrations ranged from 5 to 50 ng L^?1. Low concentrations of griseofulvin were detected in the Prut River. Further monitoring studies should be carried out in order to fill the gaps of knowledge concerning the presence of pharmaceutical residues in Romanian water environment and to improve public understanding regarding the environmental risk of pharmaceutical contamination.