复杂岩溶矿床延深水平涌水量的预测

随着岩溶矿床的延深开采,矿坑涌水量的计算成为防治水害首先要解决的难题。文章创造性地采用国外广泛采用的岩溶水衰减动态分析法,选择了我国南方复杂岩溶含水层中有代表性的重庆市红岩煤矿,将丛林采区茅口组岩溶水动力单元和该单元南大巷(标高+370 m)的茅口灰岩岩溶含水层的主要排水点-1号突水点作为研究对象,建立了该单元岩溶含水层的计算模型-衰减动态(流量和水位)方程,求出了岩溶水动力单元水均衡、地下水储量计算和矿坑涌水量预测的水文地质参数:a、T、K、S、μ、Ie,建立了该单元岩溶裂隙-管道水的水均衡方程, 根据连续观察一个水文年以上的丰富地下水动态资料,预测了红岩煤矿370 m标高以下的延伸开采水平(295- 370 m)矿坑涌水量。     

Anthropogenic Calcium Particles Observed in Beijing and Qingdao, China

Analysis of individual particles collected at Beijing in northern China revealed that particles abundant in calcium (Ca) always constituted a large fraction of mineral particles in the urban atmosphere. The particles were characterized by cubic morphologies. The major mineral element in the particles was Ca and few or no other mineral elements were detected. A large number of the particles were in the range of diameter <1 μm, where common natural mineral particles were rarely detected. The contribution of the Ca particles to the volume of total mineral particles greatly exceeded that of other mineral particles during non-dust-storm periods and was comparable to that during dust-storm periods. Reagent film tests showed that particulate sulfate and nitrate formation on the Ca particles was similar to that on common mineral particles. These results indicate that a large portion of Ca in the atmospheric particulate matter in Beijing was from anthropogenic sources rather than from natural sources, and the anthropogenic Ca particles acted as a significant medium for the formation of sulfate and nitrate. Similar particles were also detected at Qingdao, a coastal city in northern China. Data of a dust storm event showed that Ca-abundant particles from East China arrived there and moved out of the continent, similarly to Asian dust storm particles, suggesting possible contributions of anthropogenic Ca even in Asian dust storm samples in the downstream areas. Therefore, Ca may not be a good indicator of Asian dust from natural sources. However, the Ca particles, due to their unique shapes and elemental compositions, may provide an indicator for the atmospheric dispersion of anthropogenic particulate matters in East Asia.     

青岛即墨温泉沉积物特征及其对地热资源的标识意义

文章结合多种技术手段对青岛即墨温泉盆地第四纪沉积物进行研究。通过研究发现，在即墨温泉典型沉积物（矿泥）中，含有大量石膏、岩盐等与高矿化温泉地热水密切相关的自生矿物，以直隶小旋螺为代表的腹足类陆生软体动物化石和以土星介为代表的节肢动物介形虫化石在远离温泉喷口处大量分布，而在喷口附近缺失。根据胶东地区现有温泉与温泉沉积物的渊源关系，建立温泉沉积物对隐伏地热资源的标识性特征。     

基于正态云模型的区域矿产资源可持续力评价

矿产资源是人类生存和社会可持续发展的基础,研究区域矿产资源的可持续力发展水平、能力和发展趋势,不仅仅是个地区问题,更应是资源保障问题,因而对我国资源承载能力和可持续发展具有十分重要的意义。针对当前区域矿产资源可持续力定量测度研究较少,且现有评价方法不能同时兼顾指标的模糊性与随机性的难题,该研究将正态云模型引入区域矿产资源可持续力综合评价。从资源、经济、环境(含人口)三方面构建矿产资源可持续力评价指标体系,基于正态云模型结合改进的层次分析法,不仅使得指标特点得以保真,而且各指标权重的计算量也大大减少,提高了评价方法的适用性。以湖南省2010—2015年间的矿产资源为研究对象,进行矿产资源可持续力定量测度。结果显示,6年间,湖南省矿产资源可持续力状态虽然始终处于III级(一般)状态,但可持续力综合值从2.600 0上升到3.070 8,区域矿产资源可持续力水平有日趋增加态势;个别评价指标仍处于较弱状态,单位GDP能耗量、万元工业产值中矿业产值比率、人口密度单因子得分值均2.5,表明这些指标相对较弱,有待进一步采取相关措施进行改善。该评价结果与实地调研基本吻合,表明该方法是可行的。本方法在定量评价中能兼顾随机性和模糊性,且计算过程简便,结果可靠,能为矿产资源定量评价提供参考。     

京津冀地区矿产资源开发的生态环境影响研究

京津冀地区位于我国北方农牧交错带前缘,坝上、燕山、太行山等地区是区域水源的主要发源地,同样是京津及华北平原的主要生态屏障。对京津冀地区矿产资源开发的生态环境影响进行评价,具有重要现实意义。本文根据京津冀地区矿产资源开发现状、规划空间布局和生态环境特点,综合运用GIS空间分析技术和生态风险理论,从矿产资源的空间布局合理性角度入手,分析京津冀地区矿产资源开发利用的生态环境影响,并以此识别区域内矿产资源开发的生态风险高发区和较高发区。结果显示,京津冀地区矿产资源开发空间布局与燕山、太行山山地水源涵养与水土保持区、坝上高原风沙防护区等生态功能区存在空间重叠,规模性的矿产开发会对区域内的水源涵养、土壤保持、生物多样性维护等生态功能构成持续性影响;高海拔地区的高强度开矿同样会加剧水土流失和荒漠化。天津市滨海区,承德市宽城满族自治县,邯郸市武安市等市县因密集分布了已有的矿产开发企业,并囊括了近期矿产资源开发的众多矿区,矿产资源开发的遗留性问题也比较突出,成为矿产资源开发的生态风险高发区。在生态影响分析基础上,本文提出了有针对性的空间差异性生态保护对策,以期为京津冀地区矿产资源开发布局优化提供技术支撑。     

Effects of initial iron corrosion rate on long-term performance of iron permeable reactive barriers: Column experiments and numerical simulation

Column experiments and numerical simulation were conducted to test the hypothesis that iron material having a high corrosion rate is not beneficial for the long-term performance of iron permeable reactive barriers (PRBs) because of faster passivation of iron and greater porosity loss close to the influent face of the PRBs. Four iron materials (Connelly, Gotthart-Maier, Peerless, and ISPAT) were used for the column experiments, and the changes in reactivity toward cis-dichloroethene (cis-DCE) degradation in the presence of dissolved CaCO₃ were evaluated. The experimental results showed that the difference in distribution of the accumulated precipitates, resulting from differences in iron corrosion rate, caused a difference in the migration rate of the cis-DCE profiles and a significant difference in the pattern of passivation, indicating a faster passivation in the region close to the influent end for the material having a higher corrosion rate. For the numerical simulation, the accumulation of secondary minerals and reactivity loss of iron were coupled using an empirically-derived relationship that was incorporated into a multi-component reactive transport model. The simulation results provided a reasonable representation of the evolution of iron reactivity toward cis-DCE treatment and the changes in geochemical conditions for each material, consistent with the observed data. The simulations for long-term performance were also conducted to further test the hypothesis and predict the differences in performance over a period of 40 years under typical groundwater conditions. The predictions showed that the cases of higher iron corrosion rates had earlier cis-DCE breakthrough and more reduction in porosity starting from near the influent face, due to more accumulation of carbonate minerals in that region. Therefore, both the experimental and simulation results appear to support the hypothesis and suggest that reactivity changes of iron materials resulting from evolution of geochemical conditions should be considered in the design of iron PRBs.     

高硬度矿泉水的软化研究

采用加药沉淀－离子交换法,结合实例对高硬度矿泉水进行软化研究。试验结果和工艺计算表明,加药沉淀－离子交换法对高硬度矿泉水具有良好的软化效果,方法简单、投资少,成本低,水质好等优点,是一种既能降低矿泉水的硬度和碱度,火能保持水中微量元素含量的理想方法。     

Emission and Performance Characteristics of a 2 Litre Toyota Diesel Van Operating on Esterified Waste Cooking Oil and Mineral Diesel Fuel

Exhaust emission and performance characteristics were evaluated in a Toyota van, powered by a 21 indirect injection (IDI) naturally aspirated diesel engine, operating on vegetable based waste cooking oil methyl ester (WCOME).Tests were performed on a chassis dynamometer and the data were compared with previous results conducted on the same vehicle using mineral diesel fuel. The data obtained includes smoke opacity, carbon monoxide (CO), carbon dioxide (CO₂), oxygen (O₂), nitrogen dioxide (NO₂), nitric oxide (NO), sulfur dioxide (SO₂) and brake power. Engine lubricating oil samples were also taken. Results from this study indicated a difference of approximately 9% in brake power between the two fuels. WCOME developed a significant lower smoke opacity level and reduced CO, CO₂, SO₂ emissions. However, O₂, NO₂ and NO levels were higher with the vegetable oil based fuel. Power values were comparable for both fuels. Lubricating oil analysis gave little change of viscosity and wear metal concentrations after 2887km were: Silicon 35ppm, Chromium 3.3ppm, Iron 33.8ppm, Copper 14.1ppm and lead 78.6ppm.     

Identification and spatial patterns of coastal water pollution sources based on GIS and chemometric approach

Comprehensive and joint applications of GIS and chemometric approach were applied in identification and spatial patterns of coastal water pollution sources with a large data set （5 years （2000-2004）, 17 parameters） obtained through coastal water monitoring of Southern Water Control Zone in Hong Kong. According to cluster analysis the pollution degree was significantly different between September-next May （the 1st period） and June-August （the 2nd period）. Based on these results, four potential pollution sources, such as organic/eutrophication pollution, natural pollution, mineral/anthropic pollution and fecal pollution were identified by factor analysis/principal component analysis. Then the factor scores of each monitoring site were analyzed using inverse distance weighting method, and the results indicated degree of the influence by various potential pollution sources differed among the monitoring sites. This study indicated that hybrid approach was useful and effective for identification of coastal water pollution source and spatial patterns.     

Amplification of plasmid DNA bound on soil colloidal particles and clay minerals by the polymerase chain reaction

Polymerase chain reaction(PCR)was used to amplify a 600-base pair(bp)sequence of plasmid pGEX-2T DNA bound on soil colloidal particles from Brown soil(Alfisol)and Red soil(Ultisol),and three different minerals(goethite,kaolinite,montmorillonite). DNA bound on soil colloids,kaolinite,and montmorillonite was not amplified when the complexes were used directly but amplification occurred when the soil colloid or kaolinite-DNA complex was diluted,10- and 20-fold.The montmorillonite-DNA complex required at least 100-fold dilution before amplification could be detected.DNA bound on goethile was amplified irrespective of whether the complex was used directly,or diluted 10- and 20-fold.The amplification of mineral-bound plasmid DNA by PCR is,therefore,markedly influenced by the type and concentration of minerals used.This information is of fundamental importance to soil molecular microbial ecology with particular reference to monitoring the fate of genetically engineered microorganisms and their recombinant DNA in soil environments.