全文获取类型
收费全文 | 2008篇 |
免费 | 162篇 |
国内免费 | 290篇 |
专业分类
安全科学 | 324篇 |
废物处理 | 144篇 |
环保管理 | 409篇 |
综合类 | 1050篇 |
基础理论 | 177篇 |
环境理论 | 4篇 |
污染及防治 | 207篇 |
评价与监测 | 68篇 |
社会与环境 | 57篇 |
灾害及防治 | 20篇 |
出版年
2024年 | 2篇 |
2023年 | 16篇 |
2022年 | 24篇 |
2021年 | 48篇 |
2020年 | 67篇 |
2019年 | 60篇 |
2018年 | 38篇 |
2017年 | 57篇 |
2016年 | 84篇 |
2015年 | 74篇 |
2014年 | 88篇 |
2013年 | 159篇 |
2012年 | 181篇 |
2011年 | 169篇 |
2010年 | 111篇 |
2009年 | 150篇 |
2008年 | 84篇 |
2007年 | 125篇 |
2006年 | 121篇 |
2005年 | 101篇 |
2004年 | 94篇 |
2003年 | 102篇 |
2002年 | 106篇 |
2001年 | 70篇 |
2000年 | 71篇 |
1999年 | 55篇 |
1998年 | 46篇 |
1997年 | 57篇 |
1996年 | 33篇 |
1995年 | 32篇 |
1994年 | 8篇 |
1993年 | 7篇 |
1992年 | 5篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1985年 | 1篇 |
1984年 | 1篇 |
1981年 | 1篇 |
1979年 | 3篇 |
1970年 | 1篇 |
排序方式: 共有2460条查询结果,搜索用时 921 毫秒
671.
Towell MG Paton GI Semple KT 《Environmental pollution (Barking, Essex : 1987)》2011,159(12):3777-3783
The effect of cable oil concentration, nutrient amendment and bioaugmentation on cable oil component biodegradation in a pristine agricultural soil was investigated. Biodegradation potential was evaluated over 21 d by measuring cumulative CO2 respiration on a Micro-Oxymax respirometer and 14C-phenyldodecane mineralisation using a 14C-respirometric assay. Cable oil concentration had a significant effect upon oil biodegradation. Microbial respiratory activity increased with increasing cable oil concentration, whereas 14C-phenydodecane mineralisation decreased. Bioaugmentation achieved the best cable oil biodegradation performance, resulting in increases in cumulative CO2 respiration, and maximum rates and extents of 14C-phenyldodecane mineralisation. Generally, nutrient amendment also enhanced cable oil biodegradation, but not to the extent that degrader amendment did. Cable oil biodegradation was a function of (i) cable oil concentration and (ii) catabolic ability of microbial populations. Bioaugmentation may enhance cable oil biodegradation, and is dependent upon composition, cell number and application of catabolic inocula to soil. 相似文献
672.
673.
674.
Although polychlorinated biphenyls have never been manufactured in Ghana, it has been used extensively as dielectric fluid in electric transformers and capacitors. However, very little is known of its health and environmental impacts by both managers of these transformers and capacitors and also the general public. This work therefore seeks to explore INAA as a possible alternative to screening transformer oils for PCBs by determining the total chlorine content. The total chlorine content of transformer oil samples from Ghana that tested positive and some randomly selected samples that tested negative from screening using CLOR-N-OIL test kits, have had their total chlorine estimated. INAA using the Research Reactor located at the Ghana Atomic Energy Commission was used to estimate the total chlorine content of the oil samples. Neutron Activation and gamma ray spectroscopy using HPGe detector coupled to MAESTRO 32 software was used to determine the total chlorine content by integrating the peak area of the spectrum into a simplified program that was developed from the activation equation. Instrumental Neutron Activation Analysis was able to validate the result obtained from the test kits screening with accuracy 7.5%.The minimum total chlorine content of the positive samples determined by NAA was 71.34 μg g−1. 相似文献
675.
提出了水域泄漏油品回收技术的装备需求,介绍了水域泄漏油品问收处理措施.采用拦油栅来控制漂浮在水上的油品,将泄漏油品集中在相对较小的区域内,并使水面的浮油层加厚,然后使用人工或机械对泄漏油品进行回收.对于水域中的少量泄漏油品,采用吸油材料来进行吸附.在油膜较薄,难以用机械方法回收的情况下,使用消油剂或固化剂进行处理.水域... 相似文献
676.
677.
Effects of remediation technologies on polar compounds of crude oil in contaminated soils have not been well understood when compared to hydrocarbons. In this study, ultrahigh resolution Fourier transform ion cyclotron resonance mass spectrometry (FT-ICR MS) was used to characterize the changes in NSO polar compounds of crude oil and residual oil after long-term natural attenuation, biostimulation and subsequent ozonation following biostimulation of contaminated soils. N1 and O1 species, which were abundant in the crude oil, were selectively biodegraded, and species with higher double bond equivalent values and smaller carbon numbers appeared to be more resistant to microbial alteration. O2-O6 species were enriched by biodegradation and contained a large number of compounds with a high degree of unsaturation. Ozone could react with a variety of polar compounds in residual oil after biodegradation and showed high reactivity with polar species containing aromatic or multi-aliphatic rings, including the residual N1 and O1 species, naphthenic acids and unsaturated O3-O6 compounds. Fatty acids and O3-O8 species dominated by saturated alkyl compounds were resistant to ozonation or the primarily incomplete ozonation products. Principal component analysis of identified peaks in the FT-ICR MS spectra provided a comprehensive overview of the complex samples at the molecular level and the results were consistent with the detailed analysis. Taken together, these results showed the high complexity of polar compounds in residual oils after biodegradation or ozonation in contaminated soil and would contribute to a better understanding of bioremediation and ozonation processes. 相似文献
678.
Fish oils are one of the main sources of ω-3 fatty acids. However, they can present elevated levels of some lipophilic pollutants, such as hexabromocyclododecanes (HBCDs). Since data about HBCDs in fish oil samples are very limited, in this study, 25 samples of fish oil for feed and food have been analyzed. Total HBCDs, as well as, α-, β- and γ-diastereoisomers have been determined. Total HBCDs ranged from 0.09 to 26.8 ng g−1, with higher concentrations in fish oil for feed (average value of 9.69 ng g−1) than those for food (1.14 ng g−1). Concentrations of α-HBCD (average value of 4.12 ng g−1 in feed samples and 0.48 ng g−1 in food samples) and γ-HBCD (5.05 and 0.43 ng g−1 respectively) were higher than that of β-HBCD (0.52 and 0.19 ng g−1 respectively) in most of the samples. However, none of them was predominant in the samples. Concentrations of HBCDs were compared to concentrations of other pollutants and correlation between dioxin and dioxin-like PCBs levels and HBCDs levels were observed. Intake of HBCDs was calculated for fish oil with human consumption purposes and it ranged from 0.08 to 5.38 ng HBCDs d−1, which could contribute significantly to HBCDs total intake. Enantiomeric fractions were also determined. No clear enrichment was observed for γ-HBCD, while (−)-α-HBCD enrichment was detected in some samples. 相似文献
679.
Bao-Xiang Peng Qing Shu Jin-Fu Wang Guang-Run Wang De-Zheng Wang Ming-Han Han 《Process Safety and Environmental Protection》2008,86(6):441-447
Biodiesel is a non-toxic and biodegradable substitute for petroleum-based diesel. However, it is impractical to use refined edible oils to produce biodiesel due to its high cost and priority for food products, especially in China, while waste oils with high free fatty acids (FFAs) can be considered as the raw materials. In the present work, a solid acid catalyst comprising SO42−/TiO2–SiO2 was prepared, characterized and studied for its activity for the production of biodiesel from several low cost feedstocks with high FFAs. The solid acid catalyst can be recycled, easily removed and can simultaneously catalyze esterification and transesterification. The influence of reaction parameters was studied, and the optimized reaction parameters are reaction temperature 200 °C, molar ratio of methanol to oil 9:1 and catalyst concentration 3 wt.%. The catalyst showed good stability. A continuous process for biodiesel production from cheap raw feedstocks was proposed, and a 10,000-tonnes/year biodiesel production demonstration plant has been built. 相似文献
680.
The paper presents the application of thermal remote sensing for mapping hydrocarbon polluted sites. This has been achieved by mono-window algorithm for land surface temperature (LST) measurements, using multi-date band 6 data of Landsat Thematic Mapper (TM). The emissivity, transmittance and mean atmospheric temperature were used as critical factors to estimate LST. The changes in the surface emissivity due to oil pollution alter the apparent temperature, which was used as a recognition element to map out oil polluted surfaces. The LST contrast was successfully used to map spatial distribution of hydrocarbon pollution in the Burgan Oil field area of Kuwait. The methodology can be positively used to detect waste dumping, oil spills in oceans and ports, besides environmental management of oil pollution at or near the land surface. 相似文献