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AbstractA novel method of synthesis of tin dioxide quantum dots employing Camellia sinensis shoots as reducing agent and stabilizer is presented. The quantum dots were characterized by UV spectroscopy, X-Ray diffraction analysis, Fourier transform infrared spectroscopy, scanning electron microscopy, energy-dispersive X-ray spectroscopy and transmission electron microscopy. The crystalline tin dioxide quantum dots with an average size of 4.3?nm were of flake like morphology capped by phenolic compounds of Camellia sinensis. The quantum dots were employed for the photocatalytic degradation of thiamethoxam resulting in 57% degradation within 45 mins. 相似文献
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Jinglian ZHAO Liang ZHAO Xinping WANG 《Frontiers of Environmental Science & Engineering in China》2008,2(4):415-420
The photocatalytic performance of ZnO/ZnS hybrid nanocomposite was largely higher than that of the mere ZnO or ZnS nanoparticles,
but the complicated procedure and misdistribution of final products limited its large-scale productions. The exploration of
a novel synthesis route of ZnO/ZnS hybrid photocatalysts with high catalytic performance is becoming a crucial step for the
large-scale application of ZnO/ZnS hybrid photocatalytic technique. Preparation and characterization of nanosized ZnO/ZnS
hybrid photocatalysts were studied in this paper. The photocatalysts were obtained via microwave-hydrothermal crystallization
with the help of sodium citrate. The products were characterized by X-ray diffraction (XRD), transmission electron microscopy
(TEM), particle size distribution (PSD), and Fourier transformed infrared spectroscopy (FT-IR). The results indicated that
so-synthesized ZnO/ZnS samples consisted of the high pure cubic (sphalerite) ZnS and hexagonal ZnO nanocrystallines with a
narrow particle size distribution. The possible formation mechanisms of ZnO/ZnS nanocrystallines were mainly attributed to
the superficially protective effect of citrate. The photocatalytic experiments demonstrated that the ZnO/ZnS photocatalysts
exhibited a higher catalytic activity for the degradation of acid fuchsine than other monocomponents. 相似文献
86.
ZnFe_2O_4/TiO_2光催化剂制备及乙酰甲胺磷降解性能研究 总被引:3,自引:1,他引:2
分别采用共沉淀法和溶胶-凝胶法制备了ZnFe2O4和掺杂ZnFe2O4的纳米级TiO2光催化剂,进行了XRD、TEM和UV visDRS表征,以卤素灯为光源对纳米TiO2降解水溶液中乙酰甲胺磷农药进行了研究。考察了反应液初始pH值、催化剂用量、H2O2用量对降解率的影响。实验结果表明,焙烧温度为400℃、掺杂量为0.5%的ZnFe2O4/TiO2纳米粉体降解效果最佳,在相同条件下,反应2h后农药降解率可比纯TiO2提高20%左右。正交实验优化了降解反应条件,在常温常压下,起始pH值为12、H2O2浓度为12mmol/L、催化剂浓度为0.5g/L、反应3h后,初始浓度为1.0×10-4mol/L的乙酰甲胺磷农药降解率可达61.2%。 相似文献
87.
采用超声辅助水热法合成了磁性分子筛Fe3O4/SSZ-13,然后通过溶胶-凝胶法对其继续负载TiO2制得复合光催化剂TiO2-Fe3O4/SSZ-13。借助XRD,FTIR,SEM,TEM,VSM,UV-Vis,PL对其形貌、结构及性能进行了表征,并考察了其光催化性能。表征结果表明,Fe3O4的加入不会改变分子筛的原有结构,复合材料的光响应范围扩大,电荷分离效率提高。降解实验结果表明,光照40 min时活性艳红的去除率可达89.7%,光照60 min时活性艳红去除率可达最大(93.6%),较TiO2提高了5.7%。此外,这种材料还具有较强的磁性,饱和磁化强度为17.80 (A·m2)/kg,可通过外加磁场回收。 相似文献
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Yan Zhang Yuyan Zhang Xue Li Xiaohan Zhao Cosmos Anning John Crittenden Xianjun Lyu 《Frontiers of Environmental Science & Engineering》2020,14(4):69
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采用微波溶剂热法—浸渍法制备了WO3/γ-Bi2MoO6纳米异质结复合可见光催化剂(简称光催化剂),用XRD、SEM、XPS和UV-Vis分光光度法对其进行了表征。以甲基橙为目标降解物,考察了光催化剂的催化性能。表征结果显示:WO3分散在γ-Bi2MoO6晶体表面,未进入晶格内部;与WO3和γ-Bi2MoO6相比,WO3/γ-Bi2MoO6在紫外和可见光区的吸收强度均有所提高,且对光的吸收发生了明显的红移,禁带宽度变窄;二者形成的p-n型异质结能及时有效地促进光生电子-空穴对的分离,提高催化活性。实验结果表明:WO3/γ-Bi2MoO6的催化活性优于WO3和γ-Bi2MoO6;在甲基橙溶液初始质量浓度为10 mg/L、光催化剂WO3(1.0%)/γ-Bi2MoO6加入量为1 g/L时,反应3 h时甲基橙的降解率最高(达97.48%),甲基橙溶液中TOC的去除率也最高(为92.0%)。 相似文献
90.