吹扫捕集/气相色谱/质谱法测定水体中54种常见挥发性有机物的研究

运用吹扫捕集/气相色谱/质谱(P＆T/GC/MS)法对水体中54种常见的挥发性有机物(VOCs)进行了测定.结果表明,VOCs的色谱分离情况较好,平均加标回收率为88.5%～117.0%,相对标准偏差为0.71%～8.50%,准确度和精密度均符合有关分析测试的要求;方法检出限为0.10～0.61μg/L,远低于<地表水环境质量标准>(GB 3838-2002)、<生活饮用水卫生标准>(GB3838-2002)及国外相关标准的限值;54种VOCs的线性范围不同,低沸点的VOCs线性范围较宽,高沸点的VOCs的线性范围较窄,因此在分析VOCs样品配制标准工作曲线时,应注意不同沸点VOCs的线性范围.     

Relation Between Flow and Temporal Variations of Nitrate and Pesticides in Two Karst Springs in Northern Alabama1

Abstract: Two karst springs in the Mississippian Carbonate Aquifer of northern Alabama were sampled between March 1999 and March 2001 to characterize the variability in concentration of nitrate, pesticides, selected pesticide degradates, water temperature, and inorganic constituents. Water temperature and inorganic ion data for McGeehee Spring indicate that this spring represents a shallow flow system with a relatively short average ground‐water residence time. Water issuing from the larger of the two springs, Meridianville Spring, maintained a constant temperature, and inorganic ion data indicate that this water represents a deeper flow system having a longer average ground‐water residence time than McGeehee Spring. Although water‐quality data indicate differing short‐term responses to rainfall at the two springs, the seasonal variation of nitrate and pesticide concentrations generally is similar for the two springs. With the exception of pesticides detected at low concentrations, the coefficient of variation for most constituent concentrations was less than that of flow at both springs, with greater variability in concentration at McGeehee Spring. Degradates of the herbicides atrazine and fluometuron were detected at concentrations comparable to or greater than the parent pesticides. Decreases in concentration of the principal degradate of fluometuron from about July to November indicate that the degradation rate may decrease as fluometuron (demethylfluometuron) moves deeper into the soil after application. Data collected during the study show that from about November to March when recharge rates increase, nitrate and residual pesticides in the soil, unsaturated zone, and storage within the aquifer are transported to the spring discharges. Because of the increase in recharge, fluometuron loads discharged from the springs during the winter were comparable to loads discharged at the springs during the growing season.     

Variations in Base‐Flow Nitrate Flux in a First‐Order Stream and Riparian Zone1

Abstract: Nonpoint source pollution, which contributes to contamination of surface waters, is difficult to control. Some pollutants, particularly nitrate (), are predominantly transmitted through ground water. Riparian buffer zones have the potential to remove contaminants from ground water and reduce the amount of that enters surface water. This is a justification for setting aside vegetated buffer strips along waterways. Many riparian zone hydrologic models assume uniform ground‐water flow through organic‐rich soil under reducing conditions, leading to effective removal of ground‐water prior to discharge into a stream. However, in a small first‐order stream in the mid‐Atlantic coastal plain, base‐flow generation was highly variable (spatially and temporally). Average base‐flow loads were greater in winter than summer, and higher during a wetter year than in dryer years. Specific sections of the stream consistently received greater amounts of high ground water than others. Areas within the riparian zone responsible for most of the exported from the watershed are termed “critical areas.” Over this 5‐year study, most of the exported during base flow originated from a critical area comprising less than 10% of the total riparian zone land area. Allocation of resources to address and improve mitigation function in critical areas should be a priority for continued riparian zone research.     

The Forest‐Streamflow Relationship in China: A 40‐Year Retrospect1

Abstract: The relationship between forests and streamflows has long been an important research interest in China. The purpose of this paper is to summarize progress and lessons learned from the forest‐streamflow studies over the past four decades in China. To better measure the research gaps between China and other parts of the world, a brief global review on the findings from paired watershed studies over the past 100 years was also provided. In China, forest management shifted in the later 1990s from timber harvesting to forest restoration. Forest‐streamflow research was accordingly changed from assessing harvesting impacts to evaluating both harvesting and forestation effects. Over the past four decades, Chinese forest hydrology research has grown substantially. Significant progress has been made on measuring individual processes, but little solid, long‐term data were available to assess the relationship between forest changes and streamflows because of an absence of standard paired watersheds. In addition, misuse of statistical analyses was often found in the literature. A unique opportunity exists in China to study the forestation effects on streamflow as several large‐scale forestation programs are being implemented. Such an opportunity should include a robust paired watershed design under an integrated watershed ecosystem framework to avoid repeating the lessons already learned. Recommendations on future forest‐streamflow research directions in China are provided.     

Relative Effects of Climate and Water Use on Base‐Flow Trends in the Lower Klamath Basin1

Abstract: Since the 1940s, snow water equivalent (SWE) has decreased throughout the Pacific Northwest, while water use has increased. Climate has been proposed as the primary cause of base‐flow decline in the Scott River, an important coho salmon rearing tributary in the Klamath Basin. We took a comparative‐basin approach to estimating the relative contributions of climatic and non‐climatic factors to this decline. We used permutation tests to compare discharge in 5 streams and 16 snow courses between “historic” (1942‐1976) and “modern” (1977‐2005) time periods, defined by cool and warm phases, respectively, of the Pacific Decadal Oscillation. April 1 SWE decreased significantly at most snow courses lower than 1,800 m in elevation and increased slightly at higher elevations. Correspondingly, base flow decreased significantly in the two streams with the lowest latitude‐adjusted elevation and increased slightly in two higher‐elevation streams. Base‐flow decline in the Scott River, the only study stream heavily utilized for irrigation, was larger than that in all other streams and larger than predicted by elevation. Based on comparison with a neighboring stream draining wilderness, we estimate that 39% of the observed 10 Mm³ decline in July 1‐October 22 discharge in the Scott River is explained by regional‐scale climatic factors. The remainder of the decline is attributable to local factors, which include an increase in irrigation withdrawal from 48 to 103 Mm³/year since the 1950s.     

SWATMOD‐Prep: Graphical User Interface for Preparing Coupled SWAT‐MODFLOW Simulations

This article presents SWATMOD‐Prep, a graphical user interface that couples a SWAT watershed model with a MODFLOW groundwater flow model. The interface is based on a recently published SWAT‐MODFLOW code that couples the models via mapping schemes. The spatial layout of SWATMOD‐Prep guides the user through the process of importing shape files (sub‐basins, hydrologic response units [HRUs], river network) from an existing SWAT model, creating a grid, performing necessary geo‐processing operations to link the models, writing out SWAT‐MODFLOW files, and running the simulation. The option of creating a new single‐layer MODFLOW model for near‐surface alluvial aquifers is available, with the user prompted to provide groundwater surface elevation (through a digital elevation model), aquifer thickness, and necessary aquifer parameter values. The option of simulating nitrate transport in the aquifer also is available, using the reactive transport model RT3D. The interface is in the public domain. It is programmed in Python, with various software packages used for geo‐processing operations (e.g., selection, intersection of rasters) and inputting/outputting data, and is written for Windows. The use of SWATMOD‐Prep is demonstrated for the Little River Experimental Watershed, Georgia. SWATMOD‐Prep and SWAT‐MODFLOW executables are available with an accompanying user's manual at: http://swat.tamu.edu/software/swat-modflow/ . The user's manual also accompanies this article as Supporting Information.     

Inventory of Interbasin Transfers in the United States

Interbasin transfers (IBTs) are man‐made transfers of water that cross basin boundaries. These transfers are used to distribute water resources according to supply and demand. The objectives of this work were to quantify the number of IBTs that exist in the United States (U.S.) and to examine the distribution of IBTs and potential causes associated with any observed clustering of IBTs. Defining “basin” was important to enable determination of which transfers qualify as “interbasin.” A variety of definitions are employed by states, with no federal definition. The most recent national studies of IBTs were conducted by the U.S. Geological Survey (USGS) in 1985 and 1986 using USGS Hydrologic Unit Code (HUC) definitions of basins. To build a 2016 inventory of IBTs in the U.S., and to identify where they most commonly occur, the USGS National Hydrography Database (NHD) was utilized in conjunction with the Watershed Boundary Dataset (WBD). Transfers across HUC6 basin boundaries were considered interbasin. Geographical information analysis with the NHD and WBD databases revealed that there are a total of 2,161 man‐made waterways crossing HUC6 basin boundaries in the U.S. IBTs are somewhat concentrated: Florida, Texas, and North Carolina account for over 50% of the total identified IBTs. For some states, identified IBTs are locally clustered. Analysis of these clusters suggests a variety of reasons that IBTs have been built, including population, drainage, and agricultural factors.     

Water Quality Signals from Rural Land Use and Exurbanization in a Mountain Landscape: What's Clear and What's Confounded?

In mountainous landscapes with high climatic and geomorphic variability, how do rural land uses and exurbanization alter hydrology and water quality? We evaluated effects of rural land use and exurbanization on streamflows, suspended sediment concentrations and loads, specific conductance, and summer water temperatures in 12 streams and rivers within the Upper Little Tennessee River basin in the southern Appalachian Mountains. Eleven streams featured low levels of development (>61% forest cover) but differed in land use patterning, basin size, annual precipitation, and watershed morphology. One urban stream, located within the largest town in the basin, provided the high development comparative endpoint. Even low levels of rural development and exurbanization were associated with substantial increases in suspended sediment concentrations, sediment loads, and summer stream temperature daily maxima and diurnal variation. Observed summer temperature increases were much larger than would be expected due to global climate change over the next century. Specific conductance was idiosyncratic among the smaller streams. These water quality changes were not accompanied by streamflow changes that were discernible amid the high natural variation in precipitation and geomorphology. The water quality findings suggest the need for applying the best management practices, including riparian buffers, to even low levels of rural development.     

Simulation of Daily Flow Pathways,Tile‐Drain Nitrate Concentrations,and Soil‐Nitrogen Dynamics Using SWAT

Tile drainage significantly alters flow and nutrient pathways and reliable simulation at this scale is needed for effective planning of nutrient reduction strategies. The Soil and Water Assessment Tool (SWAT) has been widely utilized for prediction of flow and nutrient loads, but few applications have evaluated the model's ability to simulate pathway‐specific flow components or nitrate‐nitrogen (NO₃‐N) concentrations in tile‐drained watersheds at the daily time step. The objectives of this study were to develop and calibrate SWAT models for small, tile‐drained watersheds, evaluate model performance for simulation of flow components and NO₃‐N concentration at daily intervals, and evaluate simulated soil‐nitrogen dynamics. Model evaluation revealed that it is possible to meet accepted performance criteria for simulation of monthly total flow, subsurface flow (SSF), and NO₃‐N loads while obtaining daily surface runoff (SURQ), SSF, and NO₃‐N concentrations that are not satisfactory. This limits model utility for simulating best management practices (BMPs) and compliance with water quality standards. Although SWAT simulates the soil N‐cycle and most predicted fluxes were within ranges reported in agronomic studies, improvements to algorithms for soil‐N processes are needed. Variability in N fluxes is extreme and better parameterization and constraint, through use of more detailed agronomic data, would also improve NO₃‐N simulation in SWAT. Editor's note : This paper is part of the featured series on SWAT Applications for Emerging Hydrologic and Water Quality Challenges. See the February 2017 issue for the introduction and background to the series.     

丹江口水库蓄水后汉江中下游水文时空变化的#br# 定量评估及其生态影响

采用变化范围法（RVA）定量研究了丹江口水库蓄水后汉江中下游水文情势的时空变化,评估出汉江干流变化度最大的江段和水文特征指标类别,分析了其对应的生态影响,并针对汉江流域的四大家鱼和水华问题进行了敏感水文指标的变化度分析。结果显示:丹江口大坝蓄水后,汉江下游河道流量是中变化度占主导,比例范围为47～63%;水位是高变化度占主导,襄阳站和皇庄站高变化度的水文指标所占比例远大于其它站点,依次为53% 和75%,各站水位较蓄水前下降了1～2 m。黄家港站高/低流量脉冲出现的频率减少（变化度为-0.49和 -0.62）,且持续的时间变短（变化度为-0.87和 -0.74）。皇庄站和襄阳站流量和水位的月均值和极值较蓄水前减少,逆转次数在高RVA范围内较蓄水前增加（变化度为1.82）。四大家鱼产卵的敏感水文指标出现频率较蓄水前减少,且为中高变化度。下游河道枯水期流量和水位减小,增加了水华发生几率。