Removal of Cd2+ from water by Friedel’s salt (FS: 3CaO.Al2O3·CaCl2·10H2O): Sorption characteristics and mechanisms

The development of low-cost and efficient new mineral adsorbents has been a hot topic in recent years. In this study, Friedel’s salt (FS:3CaO·A12O3 ·CaCl2 ·10H2O), a hexagonal layered inorganic absorbent, was synthesized to remove Cd2+ from water. The adsorption process was simulated by Langmuir and Freundlich models. The adsorption mechanism was further analyzed with TEM, XRD, FT-IR analysis and monitoring of metal cations released and solution pH variation. The results indicated the adsorbent FS had an outstanding ability for Cd(Ⅱ) adsorption. The maximum adsorption capacity of the FS for Cd(Ⅱ) removal can reach up to 671.14 mg/g. The nearly equal numbers of Cd2+ adsorbed and Ca2+ released demonstrated that ion-exchange (both surface and inner) of the FS for Cd(Ⅱ) played an important role during the adsorption process. Furthermore, the surface of the FS after adsorption was microscopically disintegrated while the inner lamellar structure was almost unchanged. The behavior of Cd(Ⅱ) adsorption by FS was significantly affected by surface reactions. The mechanisms of Cd2+ adsorption by the FS mainly included surface complexation and surface precipitation. In the present study, the adsorption process was fitted better by the Langmuir isotherm model (R2 = 0.9999) than the Freundlich isotherm model (R2 = 0.8122). Finally, due to the high capacity for ion-exchange on the FS surface, FS is a promising layered inorganic adsorbent for the removal of Cd(Ⅱ) from water.     

Photocatalytic degradation of carbofuran in TiO2 aqueous solution：Kinetics using design of experiments and mechanism by HPLC/MS/MS

The photocatalytic degradation kinetics of carbofuran was optimized by central composite design based on response surface methodology for the first time. Three variables, TiO2 concentration, initial pH value and the concentration of carbofuran, were selected to determine the dependence of degradation efficiencies on independent variables. Response surface methodology modeling results indicated that the degradation efficiency of carbofuran was highly affected by the initial pH value and the concentration of carbofuran. Then nine degradation intermediates were detected by HPLC/MS/MS. The Frontier Electron Densities of carbofuran were calculated to predict the active sites on carbofuran attacked by hydroxyl radicals and photoholes. Point charges were used to elucidate the chemisorption pattern on TiO2 catalysts during the photocatalytic process. By combining the experimental results and calculation data, the photocatalytic degradation pathways of carbofuran were proposed, including the addition of hydroxyl radicals and the cleavage of the carbamate side chain.     

滨岸缓冲带控制农田氮磷流失的作用和机理研究

农田面源氮磷的流失是导致河流湖泊等水体产生富营养化的主要原因之一,其带来的环境、经济及社会问题已引起国内外广泛关注。近年来,关于滨岸缓冲带截留污染物的效率和机理已成为研究热点。文章介绍了滨岸缓冲带在农业面源污染防治上的功能和作用,论述了滨岸缓冲带对氮磷养分的截留转化机理以及稳定同位素技术在机理研究中的应用,讨论了影响滨岸缓冲带截留转化氮磷养分的调控因子,在此基础上就目前滨岸缓冲带控制农田氮磷流失研究中存在的问题提出了未来的研究展望。     

人工湿地堵塞机理及防堵措施浅析及研究

人工湿地作为一种高效率、低投资、低运行费用、低能耗的污水处理技术,越来越受到世界各国的关注。随着人工湿地的不断推广与应用,堵塞是影响其应用和推广的主要因素之一。湿地发生堵塞后,基质的渗透系数会急剧下降,过水能力也随之降低,大量引入湿地系统的污水直接雍积在湿地表面,长期积水引发恶臭、导致蚊蝇滋生,恶化运行环境。本文通过对人工湿地运行过程中出现的填料堵塞机理与特点进行分析,归纳和总结了人工湿地堵塞的影响因素,提出了人工湿地堵塞相应的解决措施,提高人工湿地对污水的处理效果,以期能够为人工湿地的应用及推广提供参考。     

医院低碳经济管理路径探索研究

在建设两型社会的大背景下,我院积极探索低碳经济管理途径,通过实施‘‘四权分离物品管理机制”、全成本核算、打造数字化医院和低碳医疗等手段初步实现了低碳经济管理,并取得了极大的经济效益和社会效益。     

论民初我国救灾之主要特征

民国初年我国救灾的主要特征有三:一是救灾主体多元化,这可从阶层、国籍、职业、身份等方面看出,总体上又可划分为政府和社会力量两个方面。至于救灾效能,无论是政府还是社会救济力量均存在着或多或少的局限性。二是短效机制占主导,这可从救灾因素之临设性、救灾甚于防灾两点看出。三是社会过渡性彰显,无论是思想,还是机构、制度,都呈现出明显的新旧交错性,即社会过渡性。     

封闭湖泊蓝藻水华预警机制及应急控制方法

随着我国城市化进程的不断推进以及经济的快速发展,城市封闭湖泊水体污染日益严重,蓝藻水华现象频频发生。文章分析了该类水体水华的主要影响因素,并提出了预警机制。根据已开展的湖泊污染治理工程效果,针对性地提出了几种有效的封闭湖泊蓝藻水华应急控制方法。     

工业循环冷却水系统阻垢剂研究进展

本文简介了循环冷却水系统的应用现状和面临的问题．同时论述了冷却水系统结垢的成因和阻垢的机理,并介绍了阻垢剂的发展历程、研究进展及其特点。最后总结概括了未来阻垢剂的发展趋势。     

己内酰胺生产废水的铁碳微电解深度处理与机理研究

采用铁碳微电解方法对己内酰胺生产废水进行深度处理,探讨了pH值、停留时间、铁碳质量比对处理效果的影响。在pH为4、停留时间为120 min、铁碳质量比为4的最佳处理条件下,COD去除率可达57.8%,色度去除率可达68.4%。微电解对己内酰胺废水的作用主要通过铁的絮凝作用,处理过程中的酸性条件、微电解的氧化还原和电场作用,从而提高其去除效率。     

酵母融合菌对Cr的吸附性能及机理分析

研究了酵母融合菌R32对Cr的吸附性能及机理.结果表明,该菌对Cr(Ⅵ)有着很好的吸附效果,最佳吸附条件为pH≤3,投菌量为l0g/L(含水率(78±2)%),吸附温度30～35℃,Cr(Ⅵ)的初始浓度≤20mg/L.当Cr(Ⅵ)的初始浓度为10mg/L时,总铬及Cr(Ⅵ)的去除率达93.7%和96.5%,总铬的残留浓...