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51.
52.
以堇青石蜂窝陶瓷为载体的新型钒氧化物脱氮催化剂研究 总被引:18,自引:2,他引:16
以TiO2/Al2O3/堇青石蜂窝陶瓷为载体,以V2O5-MoO3-WO3为活性组分,用于氨法选择性催化还原烟气中NO的新型催化剂,并对该催化剂的活性性能和微观结构进行了评价和表征.同时,将该催化剂的活性性能与其它几种活性组分相同但载体、制备方法、结构不同的催化剂进行了对比.对比结果表明,该新型催化剂能取得最好的选择性催化还原氮氧化物催化性能BET、FT IR、XPS表征实验结果表明,其高催化活性得益于大比表面积及大孔体积,而TiO2/Al2O3/堇青石蜂窝陶瓷载体及其制备方法对获得好的催化剂构型起了至关重要的作用. 相似文献
53.
54.
铁基催化剂的微波水热处理对其SCR脱硝性能的影响 总被引:1,自引:0,他引:1
利用微波对共沉淀制备的铁铈钛复合氧化物催化剂前驱体进行水热处理,探讨了微波水热处理对铁基催化剂低温SCR脱硝性能的优化;并对微波水热处理条件的影响进行了正交分析.结果表明:对铁基催化剂前驱体进行微波水热处理,可提高其低温SCR脱硝性能,使其脱硝温度窗口向低温偏移;且微波水热处理的低温优化效果与催化剂中Fe/Ti摩尔比密切相关,Fe/Ti摩尔比越小,微波水热处理的低温优化越强;微波加热方式和微波辐射时间会影响微波水热处理对铁基催化剂SCR脱硝性能的低温优化;在相同微波辐射时间条件下,当P30逐渐变为P80,微波水热处理对铁基催化剂低温SCR脱硝的促进作用降低;在P30条件下,微波辐射15min使铁基催化剂具有最佳低温SCR脱硝活性. 相似文献
55.
目前针对加装FBC-DPF(燃油添加剂-柴油机颗粒捕集器)后的柴油机放特性研究较少,并且缺乏FBC-DPF对颗粒物中PAHs排放量的影响效果研究. 为全面评估加装FBC-DPF后柴油机颗粒物排放特性和FBC-DPF对柴油机尾气中的颗粒物排放污染控制效果,在发动机台架上对装有FBC-DPF的重型柴油机进行了颗粒物排放特性试验. 利用电子低压撞击仪(ELPI)测量加装FBC-DPF前、后柴油机颗粒物的数浓度与粒径分布,用玻璃纤维滤膜采集加装FBC-DPF前、后尾气中的固相PAHs,利用色谱质谱联用仪对加装FBC-DPF前、后尾气中的固相PAHs进行定量分析. 结果表明:①加装FBC-DPF后柴油机排放的颗粒物数浓度大幅降低,FBC-DPF对尾气中颗粒物的捕集效率平均值在95%左右;②加装FBC-DPF后柴油机固相PAHs总比排放量有所降低,在大负荷区域降幅在25.0%~88.0%之间;③加装FBC-DPF前的颗粒物中位直径为30~89nm,而加装FBC-DPF后的颗粒物中位直径为41~98nm,平均增幅为38.2%. 对于国Ⅳ及未来国Ⅴ柴油机排放法规,FBC-DPF是解决柴油机颗粒物排放的有效手段;此外,FBC-DPF可以大幅降低柴油机尾气中的有毒成分,并且能够适应高含硫量的燃油环境. 相似文献
56.
Junhua LI Hong HE Chun HU Jincai ZHAO 《Frontiers of Environmental Science & Engineering》2013,7(3):302-325
This review reports the research progress in the abatement of major pollutants in air and water by environmental catalysis. For air pollution control, the selective catalytic reduction of NO x (SCR) by ammonia and hydrocarbons on metal oxide and zeolite catalysts are reviewed and discussed, as is the removal of Hg from flue gas by catalysis. The oxidation of Volatile organic compounds (VOCs) by photo- and thermal-catalysis for indoor air quality improvement is reviewed. For wastewater treatment, the catalytic elimination of inorganic and organic pollutants in wastewater is presented. In addition, the mechanism for the procedure of abatement of air and water pollutants by catalysis is discussed in this review. Finally, a research orientation on environment catalysis for the treatment of air pollutants and wastewater is proposed. 相似文献
57.
Combination of biodiesel-ethanol-diesel fuel blend and SCR catalyst assembly
to reduce emissions from a heavy-duty diesel engine 总被引:3,自引:0,他引:3
In this study, the efforts to reduce NOx and particulate matter (PM) emissions from a diesel engine using both ethanol-selective catalytic reduction (SCR) of NOx over an Ag/Al2O3 catalyst and a biodiesel-ethanol-diesel fuel blend (BE-diesel) on an engine bench test are discussed. Compared with diesel fuel, use of BE-diesel increased PM emissions by 14% due to the increase in the soluble organic fraction (SOF) of PM, but it greatly reduced the Bosch smoke number by 60%-80% according to the results from 13-mode test of European Stationary Cycle (ESC) test. The SCR catalyst was effective in NOx reduction by ethanol, and the NOx conversion was approximately 73%. Total hydrocarbons (THC) and CO emissions increased significantly during the SCR of NOx process. Two diesel oxidation catalyst (DOC) assemblies were used after Ag/Al2O3 converter to remove CO and HC. Different oxidation catalyst showed opposite effect on PM emission. The PM composition analysis revealed that the net effect of oxidation catalyst on total PM was an integrative effect on SOF reduction and sulfate formation of PM. The engine bench test results indicated that the combination of BE-diesel and a SCR catalyst assembly could provide benefits for NOx and PM emissions control even without using diesel particle filters (DPFs). 相似文献
58.
《环境科学学报(英文版)》2023,35(2):491-504
Ce1-xZrxO2 composite oxides (molar, x = 0-1.0, interval of 0.2) were prepared by a cetyltrimethylammonium bromide-assisted precipitation method. The enhancement of silver-species modification and catalytic mechanism of adsorption-transformation-desorption process were investigated over the Ag-impregnated catalysts for low-temperature selective catalytic oxidation of ammonia (NH3-SCO). The optimal 5 wt.% Ag/Ce0.6Zr0.4O2 catalyst presented good NH3-SCO performance with >90% NH3 conversion at temperature (T) ≥ 250°C and 89% N2 selectivity. Despite the irregular block shape and underdeveloped specific surface area (∼60 m2/g), the naked and Ag-modified Ce0.6Zr0.4O2 solid solution still obtained highly dispersed distribution of surface elements analyzed by scanning electron microscope-energy dispersive spectrometer (SEM-EDS) (mapping), N2 adsorption-desorption test and X-ray diffraction (XRD). H2 temperature programmed reduction (H2-TPR) and X-ray photoelectron spectroscopy (XPS) results indicated that Ag-modification enhanced the mobility and activation of oxygen-species leading to a promotion on CeO2 reducibility and synergistic Ag0/Ag+ and Ce4+/Ce3+ redox cycles. Besides, Ag+/Ag2O clusters could facilitate the formation of surface oxygen vacancies that was beneficial to the adsorption and activation of ammonia. NH3-temperature programmed desorption (NH3-TPD) showed more adsorption-desorption capacity to ammonia were provided by physical, weak- and medium-strong acid sites. Diffused reflectance infrared Fourier transform spectroscopy (DRIFTS) experiments revealed the activation of ammonia might be the control step of NH3-SCO procedure, during which NH3 dehydrogenation derived from NHx-species and also internal selective catalytic reduction (i-SCR) reactions were proposed. 相似文献
59.
60.
选择性催化还原废气脱硝技术 总被引:1,自引:0,他引:1
选择性催化还原(SCR)法是目前普遍采用的废气催化脱硝方法。详细介绍了SCR废气脱硝的原理、工艺流程、运行控制的主要影响因素如催化剂的活性、反应温度、氨气加入量等及工业应用实例。 相似文献