近50年来云贵高原太阳辐射变化特征及影响

到达地面的太阳辐射变化会对气候和生态环境产生较大影响。用云贵高原1961～2009年日射站辐射和气象观测资料,对多年来到达地面太阳总辐的年和季节变化趋势,及辐射变化对气候要素的影响进行了分析。结果表明：1961~1988年,总辐射呈明显下降趋势,之后发生逆转,1988~1994年总辐射呈显著上升趋势,1994年后其变化趋于缓和。总体呈现变暗－变亮－变缓的趋势。各季节总辐射变化的趋势为,秋季变化趋势极显著,春季变化的趋势显著,夏季变化的趋势较显著,冬季变化不明显。高原日照时数变化趋势与总辐射经历的变暗－变亮－变缓在时间上基本一致。总辐射变化对该地区的最高气温影响显著,但对蒸发量的影响不太明显。影响年辐射变化的各因子中,云量是影响高原总辐射变化的主要因素,相对湿度和能见度则影响较小     

几种涂层氙弧灯光老化试验加速性研究

太阳辐射是引起有机材料老化的最主要原因,实验室氙弧灯光老化试验具有较高的加速性。本文通过对有机涂层在广州试验站自然暴露试验结果以及实验室氙弧灯光老化试验结果进行对比研究,得到3种常用有机防护涂层的加速倍数,对于1#、2#样品的加速倍数为9,3#样品的加速倍数为6。     

Mycobiota and mycotoxins in bee pollen collected from different areas of Slovakia

Contamination by microscopic fungi and mycotoxins in different bee pollen samples, which were stored under three different ways of storing as freezing, drying and UV radiation, was investigated. During spring 2009, 45 samples of bee-collected pollen were gathered from beekeepers who placed their bee colonies on monocultures of sunflower, rape and poppy fields within their flying distance. Bee pollen was collected from bees’ legs by special devices placed at the entrance to hives. Samples were examined for the concentration and identification of microscopic fungi able to grow on Malt and Czapek-Dox agar and mycotoxins content [deoxynivalenol (DON), T-2 toxin (T-2), zearalenone (ZON) and total aflatoxins (AFL), fumonisins (FUM), ochratoxins (OTA)] by direct competitive enzyme-linked immunosorbent assays (ELISA). The total number of microscopic fungi in this study ranged from 2.98 ± 0.02 in frozen sunflower bee pollen to 4.06 ± 0.10 log cfu.g^?1 in sunflower bee pollen after UV radiation. In this study, 449 isolates belonging to 21 fungal species representing 9 genera were found in 45 samples of bee pollen. The total isolates were detected in frozen poppy pollen 29, rape pollen 40, sunflower pollen 80, in dried poppy pollen 12, rape pollen 36, sunflower 78, in poppy pollen after UV radiation treatment 54, rape 59 and sunflower 58. The most frequent isolates of microscopic fungi found in bee pollen samples of all prevalent species were Mucor mucedo (49 isolates), Alternaria alternata (40 isolates), Mucor hiemalis (40 isolates), Aspergillus fumigatus (33 isolates) and Cladosporium cladosporioides (31 isolates). The most frequently found isolates were detected in sunflower bee pollen frozen (80 isolates) and the lowest number of isolates was observed in poppy bee pollen dried (12 isolates). The most prevalent mycotoxin of poppy bee pollen was ZON (361.55 ± 0.26 μg.kg^?1), in rape bee pollen T-2 toxin (265.40 ± 0.18 μg.kg^?1) and in sunflower bee pollen T-2 toxin (364.72 ± 0.13 μg.kg^?1) in all cases in frozen samples.     

Laboratory studies of dissipation of 14C‐DDT from soil and plywood surfaces

Abstract

The effects of temperature and solar radiation on dissipation of ¹⁴C‐p,p'‐DDT from a latosol soil were studied under laboratory conditions. Volatilization was measured by trapping organic volatiles during 6 weeks and was found to increase with rise of temperature from 3.8% of initial amount at ambient temperature to 5.9% at 45°C.

Studies on the effect of solar radiation using quartz tubes under sterilized and non‐sterilized conditions have shown that volatilized organics were highest in quartz tubes, with soil microflora presumably playing a very minor role in volatilization. Mineralization was shown to be low in sterilized systems and highest in non‐sterilized quartz systems. Studies on binding suggest that soil bioactivity may be involved in the formation of a portion of the bound residue. These laboratory experiments seem to support data from the field, where it is maintained that volatilization is a major mechanism for dissipation. Degradation in soil and to a lesser extent solar irradiation contribute also substantially to the dissipation mechanisms. Radiocarbon dissipated from plywood surfaces under indoor conditions in a biphasic fashion. Loss of 50% occurred after 5.5 weeks while the remainder dissipated at a very slow rate.     

Atrazine removal by ozonation processes in surface waters

Abstract

Atrazine (6‐chloro‐N‐ethyl‐N'‐isopropyl‐1,3,5‐triazinedyl‐2,4‐diamine) was treated with ozone alone and in combination with hydrogen peroxide or UV radiation in three surface waters. Experiments were carried out in two bubble reactors operated continously. Variables investigated were the ozone partial pressure, temperature, pH, mass flow ratio of oxidants fed: hydrogen peroxide and ozone and the type of oxidation including UV radiation alone. Residence time for the aqueous phase was kept at 10 min. Concentrations of some intermediates, including deethylatrazine, deisopropylatrazine and deethyldeisopropylatrazine, were also followed. The nature of water, specifically the alkalinity and pH were found to be important variables that affected atrazine (ATZ) removal. Surface waters with low alkalinity and high pH allowed the highest removal of ATZ to be reached. There was an optimum hydrogen peroxide to ozone mass flow ratio that resulted in the highest ATZ removal in each surface water treated. This optimum was above the theoretical stoichiometry of the process. Therefore, to reach the maximum removal of ATZ in a O₃/H₂O₂ process, more hydrogen peroxide was needed in the surface waters treated than in ultrapure water under similar experimental conditions. In some cases, UV radiation alone resulted in the removal of ATZ higher than ozonation alone. This was likely due to the alkalinity of the surface water. Ozonation and UV radiation processes yield different amounts of hydrogen peroxide. Combined ozonations (O₃/H₂O₂ and O₃/UV) lead to ATZ removals higher than single ozonation or UV radiation but the formation of intermediates was higher.     

微波辐照碳酸钾化学活化法制备菌渣活性炭

以食用菌渣为原料,以K2CO3为活化剂,利用微波辐照加热法制备活性炭。采用正交实验设计,研究了活化功率、活化时间、K2CO3与菌渣质量比、浸渍时间对活性炭碘值及得率的影响。实验结果表明,活化时间、活化功率、K2CO3与菌渣质量比对活性炭碘值影响显著,浸渍时间对活性炭碘值影响不显著;对活性炭得率,各因素影响均不显著。综合考虑碘值和得率2个指标,实验得出的最佳活性炭制备工艺条件为:活化功率560 W,活化时间20 min,K2CO3与菌渣质量比0.8,浸渍时间20 h。     

Phenogenetic response of silver birch populations and half-sib families to elevated ozone and ultraviolet-B radiation at juvenile age

Phenogenetic response of silver birch populations and half-sib families to separate and combined elevated ozone (O₃) concentrations and ultraviolet-B (UV-B) radiation dozes was studied at juvenile age in the climatic chambers. Significant population and family effects were found for seedling height, lamina width, and leaf damage. The exposure to UV-B radiation decreased genetic variation at the stage of seed germination. Complex exposure to UV-B and O₃ caused an increase of genetic variation at the stage of intensive seedling growth: seedling height genetic variation in separate treatments increased from 23.7–38.6 to 33.7–65.7%, the increase for lamina width was from 10.2–13.9 to 13.6–31.8%. Different populations and families demonstrated differing response to elevated complex UV-B and O₃ exposure. Changes of genetic intra-population variation were population-specific. Such changes in genetic variation under the impact of stressors can alter adaptation, stability, and competitive ability of regenerating populations in a hardly predictive way.     

输变电建设项目环境管理中存在问题及对策探讨

阐述了输变电建设项目在环境标准、技术规范、公众参与及竣工环保验收等方面存在的问题,并针对这些方面提出了建议。     

UV-B辐射增强对褶皱臂尾轮虫种群增殖的影响

运用群体累计培养的方法研究了UV-B辐射增强对褶皱臂尾轮虫(Brachionus plicatilis)种群增殖的影响.结果表明:UV-B辐射对褶皱臂尾轮虫的种群数量、雌体抱卵率和种群增殖率都有显著影响.在本实验辐射强度(20 μW/cm2)和剂量范围内,低剂量的0.24和0.48 kJ/m2 处理组在实验的一定时期内对褶皱臂尾轮虫的种群数量和雌体抱卵率有一定的刺激作用;而高剂量的0.72、0.96和1.20 kJ/m2 处理组对轮虫的种群数量和雌体抱卵率则有显著的抑制作用,甚至可导致整个种群的灭绝.褶皱臂尾轮虫的种群增殖率随UV-B辐射的增强显示出了一致性减小的变化规律,因此可以作为指示大气UV-B辐射强弱的生物指标.     

1983～2012年长江流域地表净辐射变化特征

本文采用统计相关分析、Morlet小波分析、Rodionov时间序列分析与GIS空间分析等技术方法,分析了1983年7月至2012年9月长江流域SRB和CERES地表净辐射月产品的时空变化特征.结果表明:拟合后遥感产品比气象辐射站点观测值整体高15.8％,平均误差为15.31 W/m2,均方根误差为21.58W/m2.长江流域地表净辐射多年均值为78.0W/m2,整体呈下降趋势,于1996年突降,存在16年和10年周期;季相上,呈夏＞春＞秋＞冬.空间上,呈现西部地区＞东部地区＞中部地区;1996～2012年相较1983～1995年净辐射整体下降,其中上游流域降幅大于中下游;净辐射降低主要出现在5～7月,降幅较大地区主要是长江上游流域部分地区和长江中游流域纬度较低地区.研究结果对于认识长江流域的气候变化条件下的能量和水分循环过程等具有重要意义.