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11.
Continuous flow transesterification of waste frying oil (WFO) with methanol for the biodiesel production was tested in a laboratory scale jacketed reactive distillation (RD) unit packed with clam shell based CaO as solid catalyst. The physiochemical properties of the clam shell catalysts were characterized by X-ray Diffraction (XRD), Brunauer–Emmett–Teller (BET), Scanning Electron Microscopy (SEM), and Energy Dispersive Atomic X-ray Spectrometry (EDAX). The effects of the reactant flow rate, methanol-to-oil ratio, and catalyst bed height were studied to obtain the maximum methyl ester conversion. Reboiler temperature of 65°C was maintained throughout the process for product purification and the system reached the steady state at 7 hr. The experimental results revealed that the jacketed RD system packed with clam shell based CaO showed high catalytic activity for continuous production of biodiesel and a maximum methyl ester conversion of 94.41% was obtained at a reactant flow rate of 0.2 mL/min, methanol/oil ratio of 6:1, and catalyst bed height of 180 mm. 相似文献
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Density functional theory (DFT) has been used to investigate the reaction pathways with steam reforming of glycerol under cold plasma conditions. Total energies, energy barriers, and reaction enthalpies at 298.15 K have been calculated at the GGA/PW91/DNP level. The calculation shows that, with the presence of steam, the energy barrier of glycerol conversion is reduced and the conversion from glycerol to H2 and CO is promoted under cold plasma conditions. The formation of syngas was through a multi-step pathway via the conversion of OHCH2CHOH, CH2OH, CH2O, HCO,·and CH3, while the recombination of H generated extra H2. The synthesis of hydrocarbons are from the recombination of·CH3,·CH2, and·CH, which could be primarily generated through glycerol dissociation. The structure of glycerol anion was also studied in this work, and it was less stable than the neutral molecule. The route for the formation of OHCH2CHOH·and CH2OH·from glycerol anion is thermodynamically favorable. 相似文献
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采用蒸发法处理城市生活垃圾焚烧厂垃圾沥滤液,着重考察了不同沥滤液初始pH值对蒸发去除COD和氨氮效果的影响,并采用GC-MS对蒸发冷凝液中有机物成分进行了分析鉴定.结果表明,生活垃圾沥滤液的初始pH对冷凝液中COD、氨氮含量及有机污染物分布产生了决定性的影响.沥滤液在酸性条件下(pH≤6)蒸发,随着pH的增加,冷凝液中COD的含量线性降低,而氨氮的含量线性增加.当沥滤液的初始pH值从6增加到11,冷凝液中COD的含量呈对数函数降低,而氨氮的含量表现出显著增加趋势.从冷凝液中鉴定出38种有机污染物,多为沸点较低的醇、酸、酚和酯类.在酸性条件下(pH=3),冷凝液中挥发性有机酸和低碳醇的相对丰度接近90%.在近中性条件下(pH=6.2),冷凝液中的有机污染物以酚、酸和杂环类化合物为主.在碱性条件下(pH =11),冷凝液中酚和杂环类化合物占比较高,而酸的含量极少. 相似文献
14.
污水污泥间壁热干燥实验研究 总被引:5,自引:1,他引:4
研究了污泥间壁热干燥的工艺过程,分析了其工艺参数、冷凝水水质和产生的污染气体,探讨了有机物水解机理.结果表明,污泥含水率与停留时间呈负指数函数相关.收集到的干燥冷凝水属高浓度有机废水,其总有机碳(TOC)、挥发性有机酸(VFA)和氨氮(NH3-N)浓度均很高,pH值保持在9~9.5.干燥冷凝水中挥发性有机酸和氨氮来源于2部分:低温110 ~130℃时,主要发生蛋白质的水解,生成有机酸和氨氮;高温140~150℃时,主要发生脂肪类的水解,生成有机酸.干燥温度低于150 ℃时,污泥间壁热干燥过程无污染气体产生. 相似文献
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The moisture from skin sweat and atmospheric water affects the thermal protective performance provided by multilayer protective clothing. Four levels of moisture content were selected to evaluate the impact of moisture on thermal protection under dry (thermal radiation) and wet (thermal radiation and low-pressure steam) heat exposure. Also, the role of moisture and its relationship with exposure time were analyzed based on skin heat flux and Henriques integral value. The addition of moisture to a fabric system was found to result in differences in second-degree and third-degree skin burn times. When moisture is added to a fabric system, it both acts as a thermal conductor to present a negative effect and provides a positive effect owing to thermal storage of water and evaporative heat loss. The positive or negative effects of moisture are mainly dependent on the thermal exposure time, the moisture content and the presence of hot steam. 相似文献
20.
电除尘设备在减少工业粉尘排放量、降低大气环境污染、保护生态环境等方面有着重要的作用,随着我国对节能减排工作的重视及环保要求的提高,保证其安全、稳定、经济、节能运行成为火电厂环保工作重点。对北仓电厂三期2×1000 MW机组电除尘电场供电方式优化、电除尘振打方式优化、电除尘闭环控制技术、电除尘高频电源技术、电除尘灰斗、瓷套蒸汽加热技术组合集成应用进行了研究,在确保除尘效率达到要求的情况下,降低运行电耗。相关的电除尘深度节能技术成果在国内同类型设备中具有一定的借鉴意义。 相似文献