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61.
In this study, a low-temperature gliding arc discharge system was used to investigate the effects of steam content and operational parameters, i.e. total feed flow rate, applied voltage, and input frequency, on the reforming performance of CO2-containing natural gas. The addition of steam less than 10% was found to enhance both selectivities for hydrogen and carbon monoxide with a significant reduction of power consumptions. The highest hydrogen selectivity and yield with the lowest power consumptions were achieved at a steam content of 10 mol%, a total feed flow rate of 100 cm3/min (corresponding to a very short residence time of 1.37 s), an applied voltage of 13.5 kV and an input frequency of 300 Hz. Under these optimum conditions, the oxidative dehydrogenation reactions to produce hydrogen were dominant with the minimum activities of all undesired reactions of cracking and coupling. Both of the short residence time (1.37 s) with a low bulk temperature (lower than 200°C) in the plasma zone under atmospheric pressure, indicate that the studied plasma reactor (gliding arc system) is superior to conventional catalytic reactors for reforming of natural gas. 相似文献
62.
Fahime Abedini Seyed Ali Hosseini Aligholi Niaei Dariush Salari Milad Abbasi Shiva Marmarshahi 《International Journal of Green Energy》2018,15(1):20-27
The paper reports the production of syngas from dry reforming of methane (DRM) over La1?xCexNi1?yFeyO3 (x, y = 0–0.4) perovskites. A series of La1?xCexNi1?yFeyO3 were designed by central composite design (CCD) and synthesized by a sol–gel auto combustion method. Artificial neural network (ANN) approach was used to determine the relationship between preparation and operational parameters on the performance of the catalysts in the DRM process. Nickel mole fraction, lanthanum mole fraction, calcination temperature, and reaction temperature were considered as input variables, and conversion of methane was considered as the output variable. An ANN model with nine neurons in the hidden layer was the suitable in predicting conversion of methane. The genetic algorithm (GA) was subsequently used to determine the optimal preparation condition for enhancing the conversion of methane. La0.6Ce0.4Ni0.99Fe0.01O3 catalyst, calcined at 756°C was obtained to be the most active catalyst owing to the optimal composition of nickel and lanthanum in the catalyst formulation. 相似文献
63.
根据燃料特性及工艺特点,阐述了蒸汽灭火系统、水喷雾灭火系统、干粉灭火系统和泡沫灭火系统在燃油锅炉房中的应用条件、主要设计参数及与通风排烟系统的关系。 相似文献
64.
核电厂蒸汽发生器(SG)水位控制系统的安全可靠运行是保证核电厂安全性和经济性的关键因素,其控制对象具有高度复杂、非线性的特点。由于复杂系统的安全性是特定环境下由系统相关要素交互作用所产生的一种涌现特性,运用系统理论,以STAMP模型为基础对SG水位控制系统进行安全性分析,以利于在设计早期阶段发现影响该系统安全运行的潜在风险因素,预防危险事故。该方法将系统理论用于核电厂关键系统和设备安全性分析,为核电厂安全运行提供了新的技术手段支持。 相似文献
65.
针对IGCC电站烟气排放ρ(NOx)不达标的问题,分别采用燃气轮机注氮脱硝和余热锅炉(余热蒸汽发生器,HRSG )SCR脱硝技术降低烟气的NOx排放量。介绍了两种技术的原理,比较了两种技术的脱硝效果、运行成本及技术特点。实际运行结果表明:安装了注氮设备的燃气轮机可以控制排气的ρ(NOx)小于90 mg/m3,但每年的运行成本较高(达2 250万元);在余热锅炉中安装SCR脱硝设备,性能测试数据符合设计要求,SCR出口ρ(NOx)小于50 mg/m3,且每年的运行成本较低,仅为422万元。 相似文献
66.
针对北方某城市的一个规划采暖供热区域的350MW超临界机组供热和将原有2×220MW纯凝机组改为供热机组供热的两种供热方案,就两种不同供热方案的初投资能耗和运行能耗进行了综合能耗比较,从节能的角度就供热方案的选择给出了参考意见。 相似文献
67.
纤维素酶气相双动态固态发酵 总被引:6,自引:0,他引:6
为了充分利用纤维素酶固态发酵的优势,提出了纤维素酶气相双动态固态发酵的方式.研究结果表明:在优化条件下(最佳压力脉冲范围、脉冲频率及气体内循环速率),发酵温度得到较好地控制,9.0cm高的填料层中最大温度梯度为0.12℃/cm;以汽爆秸秆为底物,发酵水活度得到较好的保持;动态培养发酵周期(60h)比静态发酵周期(84h)缩短了 1/3,酶活(20.36IU/g)比静态酶活(10.82IU/g)提高了1倍,压力脉动固态培养的料层上中下微生物生长状况均匀一致,且疏松,而静态固态发酵的料层中部几乎没有菌体生长利用气相双动态固态发酵可为纤维素酶大规模生产奠定基础. 相似文献
68.
69.
This study focused on steam gasification and reforming of waste biomass using a reforming catalyst. The purpose of the study was to evaluate the durability of a commercial Ni reforming catalyst and the effect of CaO on the reforming behavior, and to clarify detailed factors of catalytic performance, as well as the effect of operating parameters on the characteristics of produced gas composition. Moreover, catalyst regeneration was carried out and the behavior of catalytic activity based on gas composition was investigated. Using a fluidized bed gasifier and a fixed bed reformer, gasification and reforming of waste biomass were carried out. Commercial Ni-based catalyst and calcined limestone (CaO) were applied to the reforming reaction. Temperature of the gasifier and reformer was almost 1023 K. Ratio of steam to carbon in the feedstock [mol mol−1] and equivalence ratio (i.e., ratio of actual to theoretical amount of oxygen) [-] were set at about 2 and 0.3, respectively. The feed rate of the feedstock into the bench-scale gasifier was almost 15 kg h−1. The results of waste biomass gasification confirmed the improvement in H2 composition by the CO2 absorption reaction using the reforming catalyst and CaO. In addition, CaO proved to be especially effective in decreasing the tar concentration in the case of woody biomass gasification. Catalytic activity was maintained by means of catalyst regeneration processing by hydrogen reduction after air oxidation when woody biomass was used as feedstock. 相似文献
70.