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991.
Samaratunga SS Nishimoto J Tabata M 《Environmental science and pollution research international》2008,15(1):27-30
BACKGROUND, AIMS AND SCOPE: Chromium enters into the aquatic environment as a result of effluent discharge from steel works, electroplating, leather tanning industries and chemical industries. As the Cr(VI) is very harmful to living organisms, it should be quickly removed from the environment when it happens to be contaminated. Therefore, the aim of this laboratory research was to develop a rapid, simple and adaptable solvent extraction system to quantitatively remove Cr(VI) from polluted waters. METHODS: Aqueous salt-solutions containing Cr(VI) as CrO4(2-) at ppm level (4-6 ppm) were prepared. Equal volumes (5 ml) of aqueous and organic (2-PrOH) phases were mixed in a 10 ml centrifuge tube for 15 min, centrifuged and separated. Concentrations of Cr(VI), in both the aqueous and organic phases, were determined by atomic absorption spectrometry. The effects of salt and acid concentrations, and phase-contact time on the extraction of Cr(VI) were investigated. In addition, the extraction of Cr(VI) was assessed in the presence of tetramethylammonium chloride (TMAC) in 2-PrOH phase. Effects of some other metals, (Cd(II), Co(II), Cu(II), Ni(II) and Zn(II)), on the extraction of Cr(VI) were also investigated. RESULTS AND DISCUSSION: The Cr(VI) at ppm level was extracted quantitatively by salting-out the homogeneous system of water and 2-propanol(2-PrOH) using chloride salts, namely CaCl2 or NaCl, under acidic chloride media. The extracted chemical species of Cr(VI) was confirmed to be the CrO3Cl-. The ion-pair complex extracted into the organic phase was rationalized as the solvated ion-pair complex of [2-PrOH2+, CrO3Cl-]. The complex was no longer stable. It implied the reaction between extracted species. Studies revealed that salts and acid directly participated in the formation of the above complex. Use of extracting agents (TMAC) didn't show any significant effect on the extraction of Cr(VI) under high salting-out conditions. There is no significant interference effect on the extraction of Cr(VI) by the presence of other metals. The Cr(VI) in the organic phase was back-extracted using an aqueous ammonia solution (1.6 mol dm(-3)) containing 3 mol dm(-3) NaCl. The extraction mechanism of Cr(VI) is also discussed. CONCLUSIONS: Salting-out of homogeneous mixed solvent of 2-propanol can be employed to extract Cr(VI) quantitatively, as an ion-pair of [2-PrOH2+ * CrO3Cl-] solvated by 2-PrOH molecules. Then, the complex becomes 'solvent-like' and is readily separated into the organic phase. The increase of Cl- ion concentration in the aqueous phase favors the extraction. The 2-PrOH, salts and acid play important roles in the extraction process. There is no need to use an extracting agent at a high salting-out condition. RECOMMENDATIONS AND PERSPECTIVES: Chromium(VI) must be quickly removed before it enters into the natural cycle. As the 2-PrOH is water-miscible in any proportion, ion-pairing between 2-PrOH2+ and CrO3Cl- becomes very fast. As a result, Cr(VI) can easily be extracted. Therefore, the method is recommended as a simple, rapid and adaptable method to quickly separate Cr(VI) from aqueous samples. 相似文献
992.
Pb/Zn冶炼废渣中重金属的生物浸出-盐浸处理 总被引:3,自引:0,他引:3
利用中温嗜热菌对某铅锌冶炼废渣进行生物浸出盐浸处理研究,并根据国家固体废物浸出毒性方法(HJ/T299-2007)对盐浸后余渣进行毒性分析。研究结果表明,在pH 1.5、温度65℃、矿浆浓度5%的优化条件下生物浸出3 d后,废渣中Cu、In、Ga和Zn的浸出率分别达到了91.5%、91.8%、84.9%和93.4%;盐浸生物浸出渣,其浸出液中Ag、Pb浓度分别为7.6和247.5 mg/L,可从废渣中有效回收Cu、In、Ga、Zn、Ag和Pb。生物浸出盐浸处理后余渣约为原渣量的70%;毒性分析浸出液中重金属元素Ag、As、Cd、Cu、Pb和Zn浓度分别为2~3.5、2~3、0.3~0.5、30~50、2~4、20~60 mg/L,低于国家危险废物鉴别标准(GB5085.3-2007)。根据试验结果,提出了针对冶炼废渣资源化、减量化、无害化的生物浸出盐浸联用工艺。 相似文献
993.
994.
水质总氮测定中的有关问题探讨 总被引:1,自引:0,他引:1
对总氮测定中的一系列影响因素,诸如实验用水,器皿的洗涤,实验室环境试剂的提纯、配制和保存,消解温度、压力和时间的控制,以及高氨氮水样中的总氮测定、总氮、总磷的同时测定和其他有关的问题,作了较为详细的探讨,并提出了相应的解决办法。 相似文献
995.
非饱和土土-水特征曲线(SWCC)表示了土中含水量与吸力之间的关系。针对非饱和土干-湿循环过程中的吸力变化特征,开展试验研究。采用体积压力板仪实现非饱和土的脱湿和吸湿过程。试验成果显示:(1)土-水特征曲线是不稳定的,它与土体含水率的变化路径有关;(2)在干湿循环过程中,相同的基质吸力具有不同的含水量。 相似文献
996.
997.
998.
999.
Zhang B Hong M Zhang B Zhang XL Zhao YS 《Environmental monitoring and assessment》2007,133(1-3):379-386
Endemic fluorosis was investigated and studied in the west region of the Songnen plain, Northeast China in 2001–2002. The
results showed that the fluorine distribution in aquatic environment was that the fluorine concentrations in the lake water
and unconfined ground water were higher than that in the river water and confined ground water. The lake water (Alkali lake)
is connected with unconfined ground water. In unconfined ground water, from the east and southeast areas to the west and the
northwest areas of the plain, fluorine concentration fluctuated with high and low alternatively. The fluorine in the water
comes from the weathering of rocks and minerals in the mountains and hills around the Songnen Plain. The main influence factors
of the fluorine distribution in aquatic environment are discussed. Unconfined ground water containing high fluorine is used
as drinking water. In this region, the fluorine concentration in drinking water is evidently correlated to the morbidity of
dental and skeletal fluorosis. High fluorine concentration in drinking water has endangered human health. 相似文献
1000.
The present paper describes an effort for developing the total maximum daily load (TMDL) for phosphorus and a load reduction
strategy for the Feitsui Reservoir in Northern Taiwan. BASINS model was employed to estimate watershed pollutant loads from
nonpoint sources (NPS) in the Feitsui Reservoir watershed. The BASINS model was calibrated using field data collected during
a 2-year sampling period and then used to compute watershed pollutant loadings into the Feitsui Reservoir. The simulated results
indicate that the average annual total phosphorus (TP) loading into the reservoir is 18,910 kg/year, which consists of non-point
source loading of 16,003 kg/year, and point source loading of 2,907 kg/year. The Vollenweider mass balance model was used
next to determine the degree of eutrophication under current pollutant loading and the load reduction needed to keep the reservoir
from being eutrophic. It was estimated that Feitsui Reservoir can becoming of the oligotrophic state if the average annual
TP loading is reduced by 37% or more. The results provide the basis on which an integrated control action plan for both point
and nonpoint sources of pollution in the watershed can be developed. 相似文献