红枫湖地表水中多环芳烃的分布及来源

将固相微萃取与气相色谱联用,对贵阳红枫湖水样中16种美国环境保护署优控的多环芳烃进行分析。结果表明：红枫湖水中16种多环芳烃总量为0167 1~0336 4 μg/L,与国内其它水系相比,湖中存在多环芳烃轻度污染。7种（萘、荧蒽、苯并(b)荧蒽、苯并(k)荧蒽、苯并(a)芘、茚并(1,2,3-cd)芘和苯并(ghi)苝）多环芳烃的总量未超出中国城市供水行业对多环芳烃规定的限值,但作为饮用水源,红枫湖水中的苯并(a)芘含量已超出我国标准GB3838-2002中生活饮用水地表水源地的苯并(a)芘限值,并且苯并(a)蒽、〖JX-*9〗〖SX（B-25x〗〖HT7,5”〗艹〖〗〖HT6”,5”〗屈〖HT5”〗〖SX）〗〖JX*9〗、苯并(b)荧蒽、苯并(k)荧蒽、苯并(a)芘、茚并(1,2,3-cd)芘的含量也超过了美国环境保护署地表水水质标准限值。通过多环芳烃特征参数的比值,分析了红枫湖水中多环芳烃的污染来源。污染源分析表明,湖中多环芳烃的主要来源为燃烧源,包括木材、煤以及化石燃料的燃烧,同时也有一部分多环芳烃是来源石油类物质的输入.     

污水湿地处理工艺优化组合设计

污水湿地处理系统是利用土壤、作物、微生物自然净化功能的生态工程技术。主要有水面湿地和渗滤湿地两种类型,在天津城市污水土地处理与利用系统研究的基础上,将两种工艺的优点进行优化组合,并应用于大港油田等污水湿地处理工程,运行结果表明：将水面湿地和渗滤湿地工艺优化组合设计的示范工程,具有提高水力负荷、减少运行费用、节省工程投资、处理效果稳定等特点,有利于处理工程的长期稳定运行。     

Modeling Runoff Response to Land Cover and Rainfall Spatial Variability in Semi-Arid Watersheds

Hydrologic response is an integrated indicator of watershed condition, and significant changes in land cover may affect the overall health and function of a watershed. This paper describes a procedure for evaluating the effects of land cover change and rainfall spatial variability on watershed response. Two hydrologic models were applied on a small semi-arid watershed; one model is event-based with a one-minute time step (KINEROS), and the second is a continuous model with a daily time step (SWAT). The inputs to the models were derived from Geographic Information System (GIS) theme layers of USGS digital elevation models, the State Soil Geographic Database (STATSGO) and the Landsat-based North American Landscape Characterization classification (NALC) in conjunction with available literature and look up tables. Rainfall data from a network of 10 raingauges and historical stream flow data were used to calibrate runoff depth using the continuous hydrologic model from 1966 to 1974. No calibration was carried out for the event-based model, in which six storms from the same period were used in the calculation of runoff depth and peak runoff. The assumption on which much of this study is based is that land cover change and rainfall spatial variability affect the rainfall-runoff relationships on the watershed. To validate this assumption, simulations were carried out wherein the entire watershed was transformed from the 1972 NALC land cover, which consisted of a mixture of desertscrub and grassland, to a single uniform land cover type such as riparian, forest, oak woodland, mesquite woodland, desertscrub, grassland, urban, agriculture, and barren. This study demonstrates the feasibility of using widely available data sets for parameterizing hydrologic simulation models. The simulation results show that both models were able to characterize the runoff response of the watershed due to changes of land cover.     

Standardisation of Temperature Observed by Automatic Weather Stations

Daily mean, maximum and minimum surface airtemperature data were gathered from a network ofautomatic weather stations (AWS) within the Moor HouseNational Nature Reserve in northern England. Five AWSwere installed next to the official EnvironmentalChange Network weather station at Moor House. Datawere compared graphically and correction constantswere calculated to adjust data from each AWS to thestandard of the official station by optimising theconcordance correlation coefficient. Each correctedstation was re-located next to one of five in-situstations in and around the reserve, allowingcorrection of all temperature sensors to a commonstandard. The mean error associated with measureddaily mean, maximum and minimum temperature for eachsensor does not exceed ±0.2 K. The procedurequantifies a source of systematic measurement error,improving the identification of spatial temperaturedifferences between stations.     

Study on Management and Control of Nonpoint Source Pollution from Urban Surface Runoff

Urbanization is the dominant form of land-use change in terms of impacts on water quality, hydrology, physical properties of watersheds and their nonpoint source （NPS） pollution po-tential at present. Urbanization has changed the source, process and sink of urban NPS pollution, especially raised the pollution load of urban runoff NPS in receiving water. Urban runoff pollution is a hot spot of research on NPS. This paper analyzed type, source and harm of the NPS pollutants of urban runoff and its influence on the receiving water. Through estimating NPS pollution load of urban runoff and summarizing the law and characteristics of urban runoff NPS systemically, study on management and control of urban runoff NPS pollution was focused on the application of BMPs （best management practices）. It is a fresh methodology that management and control on NPS pollution from urban surface runoff was analyzed by methods of landscape ecology, environmental economics and environmental management. The paper provided a scientific reference for mitigating urban water environment pressure and an effective method for management and control of NPS pollution from urban surface runoff.     

城市热场剖面的分形维数计算及其意义研究——以上海中心城区为例

城市热环境是城市中建筑物的不断增加及人类活动、大气状况、地表热量传输等多种因素综合作用的结果,因此城市往往具有极为复杂的热表面。由于热量分配、传输具有一定的复杂性,传统的模型预测与定点观测方法在分析城市热表面空间结构及其形成机制方面存在一定的不足。随着空间信息科学的发展,卫星遥感技术为获取城市热场信息提供了可靠的手段。选用上海市2000年6月14日的Landsat ETM+热波段影像,首先反演城市地表温度,再引入剖面线分形的方法,在GIS的支持下,计算从人民广场出发的8个方向的分维数,并进一步探讨剖面线分形的意义,得到如下结论：城市热表面的剖面线具有明显的分形特征,8个方向的分维数为1.530 0～1.780 6,表征不同剖面线的复杂程度。热场表面剖面线的分维数揭示了3个方面的意义：首先不同的分维数反映热场不同方向上温度变化的复杂程度;其次,相对于城市中心,反映不同方向上城市边界形态的差异性;第三,进一步揭示不同方向上,下垫面土地利用类型空间组合变化的复杂程度。     

Enhanced photocatalytic activity of TiO2 by surface fluorination in degradation of organic cationic compound

Experiments were carried out to investigate the influence of TiO2 surface fluorination on the photodegradation of a representative organic cationic compound, Methylene Blue （MB）. The eleetropositive MB shows poor adsorption on TiO2 surface; its degradation performs a HO. radical-mediated mechanism. In the F-modified system, the kinetic reaction rate enlarged more than 2.5 fold that was attributed mainly to the accumulating adsorption of MB and the increased photogenerated hole available on the F-modified TiO2 surface.     

Nitrogen interception in floodwater of rice field in Taihu region of China

A field experiment located in Taihu Lake Basin of China was conducted,by application of urea or a mixture of urea with manure, to elucidate the interception of nitrogen(N)export in a typical rice field through"zero-drainage water management"combined with sound irrigation,rainfall forecasting and field drying,N concentrations in floodwater rapidly declined before the first event of field drying after three split fertilizations,and subsequently tended to retum to the background level.Before the first field drying,total particulate nitrogen(TPN)was the predominant N form in floodwater of plots with no N input,dissolved inorganic nitrogen(DIN)on plots that received urea only,and dissolved organic nitrogen(DON)on plots treated with the mixture of urea and manure.Thereafter TPN became the major form.No N export was found from the rice field,but total nitrogen(TN)of 15.8 kg/hm~2 was remained,mainly due to soil N sorption.The results recommended the zero-drainage water management for full-scale areas for minimizing N export.     

Adsorption of Pb and Cd on the natural surface coatings (NSCs) in the presence of organochlorine pesticides: a preliminary investigation

Adsorption of Pb and Cd in the presence and absence of organochlorine pesticides (OCPs) on natural surface coatings (NSCs), which were collected in the Nanhu Lake in Changchun, China, was measured in order to investigate the effect of the OCPs on the adsorption of heavy metals on the NSCs. Adsorption of Pb/Cd was carried out under controlled laboratory conditions (mineral salt solution with defined species, ionic strength 0.05 mol/l, 25 degrees C and pH 6.0) with initial Pb and Cd concentrations ranging from 0.2 to 2.5 mol/l. The classical Langmuir adsorption isotherm was applied to estimate the equilibrium coefficients of the adsorption of Pb and Cd on the NSCs. Adsorption interference between Pb/Cd and the OCPs on the NSCs indicated that the adsorption of Pb/Cd on the NSCs was influenced by the OCPs, and competitive adsorption between Pb and the OCPs was observed while adsorption of Cd was enhanced by addition of the OCPs. Adsorption data fit the Langmuir isotherm well for the NSCs treated with the OCPs at different equilibrium concentrations. The results showed that the amount of adsorbed Pb decreased by more than 40% while the amount of adsorbed Cd increased by over 60% with an increase in the initial concentrations of the OCPs ranging from 0 to 5.0 microg/l and that adsorption of Pb/Cd on the NSCs was strongly affected by the OCPs. This preliminary study highlights the importance of the OCPs on the NSCs in controlling the transport, fate, biogeochemistry, bioavailability and toxicity of trace metals in aquatic environments.     

Evidence of hydrocarbon contamination from the Burgan oil field, Kuwait: interpretations from thermal remote sensing data

The paper presents the application of thermal remote sensing for mapping hydrocarbon polluted sites. This has been achieved by mono-window algorithm for land surface temperature (LST) measurements, using multi-date band 6 data of Landsat Thematic Mapper (TM). The emissivity, transmittance and mean atmospheric temperature were used as critical factors to estimate LST. The changes in the surface emissivity due to oil pollution alter the apparent temperature, which was used as a recognition element to map out oil polluted surfaces. The LST contrast was successfully used to map spatial distribution of hydrocarbon pollution in the Burgan Oil field area of Kuwait. The methodology can be positively used to detect waste dumping, oil spills in oceans and ports, besides environmental management of oil pollution at or near the land surface.