化工安全评价探讨

安全评价在化工行业中占有重要地位。安全评价的方法随着科技的进步也有了长足地发展。本文通过对国内外化工安全评价现状的分析，详细地比较了几种常用。在此基础上，提出一套可行的评价方案，并结合具体项目，运用该方案分析了项目的危险等级，制定了预防措施。     

硝化甘油生产系统的安全分析

对硝化甘油生产事故进行了综合统计分析,然后采用ＦＴＡ对硝化甘油生产过程的危险性作了详细的定性分析,并且根据分析结果提出了针对性的改进措施和安全注意事项     

树木健康与病虫草害的关系分析

本文论述了树木健康与病害、虫害、草害的关系。     

(艹屈)和5-甲基(艹屈)的ab initio计算

湾区非角环上的甲基取代能大大增加多环芳烃的致癌性,量子化学的从头计算(ab initio)指出,5-甲基(艹屈)C1-C2键的电子性质有利于在此健发生亲电反应,电子密度分布图说明5-甲基(艹屈)在C1—C2键周围的电子密度明显大于(艹屈)相应部分的电子密度,这也有利于亲电试剂的进攻,因而在代谢过程中,5-甲基(艹屈)容易在此位置发生亲电氧化形成环氧化物,进而形成终致癌剂,这就使5-甲基(艹屈)的致癌性比(艹屈)大大增强。     

A fetus with a chromosome 13 ring and placenta with chromosome 13 rod/ring mosaicism

A fetus was identified by prenatal cytogenetic diagnosis as having a karyotype 46,XY,r(13) (p11q13). Termination of the pregnancy yielded a severely malformed fetus. Fetal abnormalities included anencephaly, imperforate anus and urethral meatus, severe talipes, syndactyly, cardiac defects and other anomalies. Confirmatory studies on cultured placental villi cells indicated a second cell line, 46,XY, −13,+ 13qter→cen::13ql3→qter. This cell line was not detectable in cells derived from the fetus despite extensive studies. It seems likely that the two cell lines arose simultaneously with selection favouring the 46,XY,r(13) line. How the chromosome rearrangements may have arisen is discussed. We are unaware of other cases where a cell line identifiable by a chromosome abnormality appeared to be confined to placental tissue. However, studies on placental tissue may be helpful in understanding the origin of other unbalanced de novo rearrangements.     

Genetic and Environmental Effects Assessment in Scots Pine Provenances Planted in Central Siberia

Scots pine provenance trials were established in 1964 in forest-steppe and in 1974 in southern taiga zones of Central Siberia from seeds collected over whole Russia. Tree-ring characteristics (radial growth and density chronologies) from 12 and 16 provenances planted in those plantations were measured densitometrically. Tree-ring analysis revealed a retention of a genetically fixed response to climatic factors proper to pines' origin. Trees from higher latitudes keep the orientation towards accelerated growth at the beginning of a growing season, which is followed by a rapid transition to formation of latewood cells and deceleration of growth earlier, than in medium-latitude trees. Main climatic factors controlling tree-rings formation differed slightly between different provenances within plantations. Genetically fixed ability of the provenances are not great (less than 15%), that proves high adaptability of pines to abrupt climatic change. Tree-ring formation of Scots pine provenances is mainly determined by the environmental factors.     

Dendroremediation of trinitrotoluene (TNT) part 1: Literature overview and research concept

BACKGROUND, AIM AND SCOPE: For decades, very large areas of former military sites have been contaminated diffusely with the persistent nitroaromatic explosive 2,4,6-trinitrotoluene (TNT). The recalcitrance of the environmental hazard TNT is to a great extent due to its particulate soil existence, which leads to slow but continuous leaching processes. Although improper handling during the manufacture of TNT seems to be a problem of the past in developed countries, environmental deposition of TNT and other explosives is still going on unfortunately, resulting from thousands of unexploded ordnance or low order explosions at munitions test areas and at current battlefields. OBJECTIVE: Sustainable phytoremediation strategies for explosives in Germany, which intend to use trees to decontaminate soil and groundwater ('dendroremediation'), have to consider that most of the former German military sites are already covered with woodlands, mainly with conifer stands. Therefore, parallel investigation of the remediation potential is necessary for both of the selected hybrids of fast growing broadleaf trees, which are waiting for planting and forest conifers, which have already proven for decades that they are able to grow on explosive contaminated sites. MAIN FEATURES: A short literature review is given regarding phytoremediation of TNT with herbaceous plants and some general aspects of dendroremediation are discussed. Furthermore, an overview of our TNT-dendroremediation research network is introduced, which has the strategic goal to make dendroremediation more calculable for a series of potent trees for site-adapted in situ application and for the assessment of tree remediation potentials in natural attenuation processes. RESULTS AND DISCUSSION: Some of our methods, results and conclusions yet unpublished are presented. For a preliminary calculation of area-related annual TNT dendroremediation potential of five-year-old trees, the following values were assessed: Salix EW-13 6.0, Salix EW-20 8.5, Populus ZP-007 4.2, Betula pendula 5.2, Picea abies 1.9 and Pinus sylvestris 0.8 g m(-2) a(-1). For a 45-year-old spruce forest, an annual natural attenuation potential of 4.2 g TNT m(-2) a(-1) was found. CONCLUSION, RECOMMENDATIONS AND PERSPECTIVE: Our main results deliver quantitative proposals for dendroremediation strategies in situ and provide decision aids. Also aspects of growth of raw materials for energy production are considered. Our dendroremediation research concept for TNT and its congeners can be easily completed for other trees of interest and it can also be applied to herbaceous plants. Knowing the current bottlenecks of phytoremediation and considering the known environmental behaviour of other contaminants, elements of our methodological approach may be easily adapted to those pollutant groups, e.g. for pesticides, pharmaceuticals, PAHs, chlorinated recalcitrants and, with some restrictions, to inorganics and to multiple contaminations. Our dynamical dendrotolerance test systems will help to predict tree growth on polluted areas. To provide some light into the black box of TNT dendroremediation, experimental data regarding the uptake, distribution and degradation of [14C]-TNT in mature tree tissues will be reported in the second part of this publication.     

绿化树种对大气金属污染物吸滞能力

研究测定了部分城市绿化树种对重金属大气铅、镉污染物的吸滞能力。结果表明：绿化树种对大气铅、镉污染物具有一定的吸收净化能力，并依污染气体和树种的不同具有明显差异；对铅吸收量高的树种有：桑树、黄金树、榆树、早树、梓树；吸镉量高的树种有：美青杨、桑树、早树、榆树、梓树、刺槐。     

我国珍贵树木保护中若干法律问题的思考

保护珍贵树木具有十分重要的意义,本文从立法、司法的角度,归纳了当前我国保护珍贵树木的法律制度及相关的法律责任,对于进一步完善与珍贵树木保护相关的法律规定提出了自己的设想.     

Safety evaluation of leak in a storage tank using fault tree analysis and risk matrix analysis

The work presented in this paper used a quantitative analysis of relevant risks through the development of fault tree analysis and risk analysis methods to aid real time risk prediction and safety evaluation of leak in a storage tank. Criticality of risk elements and their attributes can be used with real time data to predict potential failures likely to occur. As an example, a risk matrix was used to rank risk of events that could lead to a leak in a storage tank and to make decisions on risks to be allowed based on past statistical data. An intelligent system that recognizes increasing level(s) and draws awareness to the possibility of additional increase before unsafe levels are attained was used to analyse and make critical decisions. After a visual depiction of relationships between hazards and controls had been actualized, dynamic risk modelling was used to quantify the effect controls can potentially have on hazards by applying historical and real-time data into a probabilistic model. The output of a dynamic risk model is near real-time quantitative predictions of risk likelihood. Results from the risk matrix analysis method mixed with RTD and FTA were analyzed, evaluated, and compared.