痕量壬基酚及相关化合物的样品预处理和测定

对近年来环境样品中痕量内分泌干扰物壬基酚及相关化合物的分离富集方法和测定技术的研究进展进行了综合评述。重点讨论了索氏提取、液液萃取、液膜分离、回流萃取、固相萃取、固相微萃取、超临界流体萃取、超声提取八种样品预处理方法和气相色谱质谱联用、高效液相色谱两种测定方法,而且针对以上方面提出了尚需进一步研究的问题。     

工业企业动态安全风险评估模型在某炼钢厂安全风险管控中的应用

通过研究工业企业动态安全风险评估模型在某炼钢厂安全风险管控中的应用,探索该安全风险评估模型作为企业安全风险评估方法的可行性,为企业进行安全风险辨识、评级和分级管控选取风险评估方法提供参考。     

基于覆岩裂隙带发育高度的走向高抽巷合理位置确定

为确定大采高综采面高抽巷的合理位置,以李村煤矿1303工作面为研究背景,采用理论分析、数值模拟及现场监测等研究方法,对1303工作面覆岩裂隙发育特征、高抽巷空间位置对其围岩稳定性与抽采效果的影响规律进行系统研究。研究结果表明:高抽巷宜布置在覆岩裂隙发育区,远离回风巷道采动应力影响的位置;1303工作面覆岩破坏范围随推进距离增加,呈现先急剧增大后趋于稳定的趋势,工作面推进距离为300 m时,裂隙带高度稳定在50 m左右,形成瓦斯抽采的优势通道;高抽巷距离煤层顶板、回风巷越近,越易失稳,不利于长期抽采,综合考虑高抽巷不同位置时的瓦斯抽采效率及围岩稳定性,确定其合理位置分别是距离回风巷平距为35 m,垂距为45 m;结合现场瓦斯浓度监测结果,得出上隅角、工作面、回风巷瓦斯浓度最大值分别为0.42%,0.24%,0.33%,远低于瓦斯超限标准1%,进一步证明高抽巷层位的合理布置,可以提高瓦斯抽采效果。     

焊接工程质量与焊接工程文件

焊接质量只能是过程控制作为国际焊接标准体系中的核心标准ISO 3834给出过程控制手段就是焊接工程文件对不同质量等级对应的文件要求不同,等级越高的焊接产品,其过程控制的文件也越多,控制点更细,保证产品达到高品质要求.与之对比某事故工程的反例,该工程的焊接文件漏项多,过程控制不能保障焊接工程的安全.通过对比国际标准,发现由于国内产品焊接标准不够成熟,没有规定产品GB/T 12467质量等级(类似ISO 3834-2,3,4),因此文件分级欠专业要求.焊接制造业升级必然是标准先行,焊接标准明确质量等级,焊接工程文件体系也将完善,从而为保障焊接工程的安全运行保驾护航.     

铁路振动对历史城墙影响的测试分析

铁路列车运行对周围建筑产生振动影响,古建筑对振动更为敏感。为比较不同控制点位置及方向的振动响应,以某历史城墙为保护目标,基于《古建筑防工业振动技术规范》分析铁路振动对城墙的影响,得出水平方向振动速度对古建筑更不利,古建筑顶部水平振动大于底部水平振动;铁路引起的古建筑的水平振动中,垂直于铁路线方向是主要贡献量,并显著大于平行于铁路线方向。     

考虑人因可靠性的安全仪表功能SIL验证方法研究

油气站场一般设置有紧急停车系统（ESD）等存在操作员介入的非常规安全仪表功能（SIF）,为解决已有的安全完整性等级（SIL）评估方法不能针对此类SIF进行功能安全评价的情况。对存在操作员介入的非常规SIF进行研究,将其中的人为因素细分为观察、决策和执行3个阶段;根据各类人因可靠性分析方法优缺点,筛选CREAM和HCR方法分别分析紧急情景环境和应急响应时间对非常规SIF人因失效概率的影响,建立考虑人因可靠性的SIL验证模型;基于此模型选取某输油站典型SIF开展SIL评估,分析人因失效对SIF整体可靠性的影响水平,并提出改善措施。结果表明:将操作员应急响应过程中的人因失效概率引入传统的SIL验证模型中,可实现对非常规SIF的功能安全评价;人因失效对非常规SIF具有显著影响,筛选的人因可靠性模型可准确计算人因失效概率。     

基于双层规划的应急物资调配研究

为在突发性自然灾害发生后的黄金救援时间内,使各应急物资调配中心的物资在最短时间内高效地运往各受灾点,最大程度地平衡受灾程度不同的受灾点群众对应急物资救援的心理满意度,构建以应急物资救援时间最短为目标的上层模型;通过借鉴前景理论量化受灾群众的心理满意度,在考虑各受灾点对有限应急物资存在竞争关系的基础上,建立下层非合作博弈模型;设计遗传算法求解上层模型、改进粒子群算法求解下层模型的层次混合算法。结果表明:构建的多应急物资调配中心多受灾点的非线性整数双层规划模型,使应急物资的调配具有时效性,且更加客观地衡量各灾点物资调配的公平合理性,该模型为应急物资调配研究提供借鉴与参考。     

北京地铁列车运行引起建筑室内振动污染特征与评价

以分频最大振级(VL max)和最大Z振级(VL Z max)作为评价量,结合相关标准,监测与评价北京市地铁列车运行引起的临近建筑室内振动。结果表明:北京市2条地铁线路的振动特征频率分别为25 Hz、31.5 Hz、40 Hz和63 Hz,以40 Hz为主;特征频率上振动加速度级(VAL)增量明显;VL max、VL Z max的大小既与频率计权因子不统一有关,也与地铁对建筑室内振动的影响程度及振动能量在不同中心频率上的分布差异直接相关;地铁隧道埋深较水平距离对地铁振动衰减作用显著;地铁振动监测与评价的频率范围可统一为对人体影响较大的1 Hz^80 Hz,并统一频率计权因子。     

Assessing contamination of smoked sprats (Sprattus sprattus) with polycyclic aromatic hydrocarbons (PAHs) and changes in its level during storage in various types of packaging

The analysis of material used in this study demonstrated that the amount of polycyclic aromatic hydrocarbons (PAHs) in smoked sprats varies from the level below the lowest detection limit in muscles up to 9.99 µg kg^?1 of benzo[a]pyrene (BaP) in fish skin. Such a high level of PAHs in skin was reported only in one of six batches of sprats, while mean BaP level was at 1.69 µg kg^?1. Regardless such a high BaP level in skin, its concentration in muscles did not exceed the maximum acceptable level. The study objective was to assess to what extent packaging materials adsorb PAH compounds from food. Changes in the PAH levels were monitored in fish during their storage in packages made of various materials. The storage time was from 0 to 168 hours. The obtained results varied considerably, therefore their scatter did not allow to confirm unequivocally the preliminary hypothesis about the reduction of PAHs due to their migration to packaging material. However, analysis of the packaging used in this study demonstrated a significant increase in the level of total 16 PAHs. When high-density polyethylene (HDPE) packaging was analysed, a six-fold increase in the total 16 PAHs was observed comparing to the blank sample.     

Impact of a proposed revision of the IESTI equation on the acute risk assessment conducted when setting maximum residue levels (MRLs) in the European Union (EU): A case study

ABSTRACT

Proposals to update the methodology for the international estimated short-term intake (IESTI) equations were made during an international workshop held in Geneva in 2015. Changes to several parameters of the current four IESTI equations (cases 1, 2a, 2b, and 3) were proposed. In this study, the overall impact of these proposed changes on estimates of short-term exposure was studied using the large portion data available in the European Food Safety Authority PRIMo model and the residue data submitted in the framework of the European Maximum Residue Levels (MRL) review under Article 12 of Regulation (EC) No 396/2005. Evaluation of consumer exposure using the current and proposed equations resulted in substantial differences in the exposure estimates; however, there were no significant changes regarding the number of accepted MRLs. For the different IESTI cases, the median ratio of the new versus the current equation is 1.1 for case 1, 1.4 for case 2a, 0.75 for case 2b, and 1 for case 3. The impact, expressed as a shift in the IESTI distribution profile, indicated that the 95th percentile IESTI shifted from 50% of the acute reference dose (ARfD) with the current equations to 65% of the ARfD with the proposed equations. This IESTI increase resulted in the loss of 1.2% of the MRLs (37 out of 3110) tested within this study. At the same time, the proposed equations would have allowed 0.4% of the MRLs (14 out of 3110) that were rejected with the current equations to be accepted. The commodity groups that were most impacted by these modifications are solanacea (e.g., potato, eggplant), lettuces, pulses (dry), leafy brassica (e.g., kale, Chinese cabbage), and pome fruits. The active substances that were most affected were fluazifop-p-butyl, deltamethrin, and lambda-cyhalothrin.