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491.
J.P. Giesy Jr. 《毒物与环境化学》2013,95(3):203-224
Organic carbon from one stream and two ponds in South Carolina was fractionated into five nominal molecular diameter fractions by ultrafiltration. The concentrations associated with and binding capacity for Ca, Cd, Cu and Pb were determined for each fraction. The distribution of organic carbon among ultrafilter fractions varied from water to water, with the largest percentage occurring in the smaller fractions. Calcium was associated with each of the fractions isolated from each of the three waters, indicating Ca is bound to organics in all fractions, however, more than 99% of the Ca which passed the smallest ultrafilter was removed by cationic exchange resin. Each fraction bound more Ca than Cd, Cu or Pb except in a few cases where Pb binding was greater. All of the organic fractions had their Ca++ binding sites saturated. Calcium was not an effective competitive ion against Cd, Cu or Pb for organic binding sites. The total Cu binding capacity was less than that of Ca or Pb but similar to that of Cd. Naturally occurring organics bound more Pb than Cd or Cu but less than Ca. Saturation of Cu binding sites was less than 20% in most ultrafilter fractions except that with a nominal molecular weight of between 10,000 and 300,000 where the percent of saturation was as much as 60%. Approximately 50% of the Cu was removed onto anionic exchange resin in two waters while more than 90% was removed from water with a high organic content. Percent saturation of Cd and Pb binding sites ranged from 0.091% to 5.4% and 0.059% to 1.5%, respectively. All ions tested effectively competed with Cd, Cu or Pb for some but not all binding sites, indicating that organic binding sites were heterogeneous. A generalized order of metal‐organic stabilities based on competition for binding sites is Al>Cd>Pb>Cu>Ni = Mg=Zn = Mn>Ca. Both Cd+2 and Al+3 effectively out competed Pb++ and Cd and Pb out competed Cu for most organic binding sites. 相似文献
492.
Dominique Calmet 《Chemistry and Ecology》2013,29(1-4):41-49
For hundreds of years, the seas have been used as a place to dispose of wastes from human activities. Although no high level radioactive waste has been disposed of into the sea, variable amounts of packaged low level radioactive wastes have been dumped at 47 sites in the northern part of the Atlantic and Pacific Oceans. in 1946 the first sea dumping operation took place at a site in the North-East Pacific Ocean. the last dumping operation was in 1982, at a site off the European continental shelf in the Atlantic Ocean. Between these two dates, an estimated 46 PBq (1.24 MCi) of radioactive waste coming from research, medical, military and industrial activities have been disposed of at sea. the present trend, through the Convention for the Prevention of Marine Pollution by Dumping of Wastes and other Matter and other Regional Conventions, points towards the prohibition of the dumping of any radioactive waste into the marine environment. 相似文献
493.
494.
以钛白粉厂产生的酸解泥渣为研究对象,开展危险废物豁免管理研究,酸解泥渣豁免管理不仅可以减少环境风险,还能减轻企业处理处置的负担。危险特性鉴别结果表明,酸解泥渣不具有浸出毒性,毒性物质含量低于危险废物鉴别标准;酸解泥渣具有一定的腐蚀性,但水洗可降低其腐蚀性,经2次水洗后酸解泥渣不再具有腐蚀性危险特性;酸解泥渣经水洗后重金属的浸出毒性有所降低;酸解泥渣水洗后堆存时因地表径流产生的环境风险不高,水洗处理后酸解泥渣的环境风险将显著降低,3次水洗后的酸解泥渣即使在发生地质灾害时也不会造成水体水质的污染风险;钛白粉厂酸解泥渣水洗处理后可以进行豁免管理。 相似文献
495.
农业生物质废弃物的数量正在迅速增加,导致许多环境和治理问题. 因此,将农业生物质废弃物回收利用并增值应用越来越受到关注. 近些年农业生物质废弃物利用和衍生功能材料的研究进展主要包括以下两个方面:①提取天然聚合物并增值应用;②直接制备新型碳基材料,包括吸附、催化、储能电极和复合功能材料等. 农业生物质废弃物转化功能材料已逐步实现且应用范围广泛;未来的研究需要评估农业生物质废弃物衍生产品的质量和安全性,并开发高度可行且具有成本效益的生物质废弃物转化方法,以期实现规模化工业生产. 相似文献
496.
497.
Impediments to refractory recycling decision-making 总被引:1,自引:0,他引:1
This paper focuses on organizational impediments to the successful implementation of industrial recycling programs. Even if a technologically viable and mutually beneficial solution were to exist, there are a number of organizational impediments that make it unlikely to succeed unless the benefits are very large and apparent. These impediments stem from the difficulty in identifying potential partners and involving the appropriate individuals within the firms that understand the technical requirements, value the strategic benefits and are receptive towards establishing the industrial recycling relationship. This dilemma applies to many industrial recycling opportunities, but solutions do exist. One way to avoid some of these obstacles is to use a middleman, or broker, who can play several crucial roles to establish the relationship. This paper describes the impediments and key broker roles, and provides a case study dealing with refractory recycling. It provides a case study that documents a recycling relationship between an aluminum-manufacturing firm that produces a large volume of spent refractories and a regional portland cement producer that is using the spent refractories as an alternative raw material source. This paper also provides a thorough literature search in the area of refractory recycling. Finally, the case study provides an opportunity for analysis and reflection on the implications of these findings to industrial firms, industrial societies and governmental agencies that seek to encourage successful recycling operations. 相似文献
498.
Eiji?FujimoriEmail author Kazuaki?Minamoto Seiko?Iwata Koichi?Chiba Hiroki?Haraguchi 《Journal of Material Cycles and Waste Management》2004,6(1):73-79
The elemental composition of the industrial waste incineration bottom ash (IWIBA) samples collected from three different types of incinerator with different kinds of wastes were compared. The major-to-ultratrace elements in the IWIBA samples were determined by inductively coupled plasma atomic emission spectrometry (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). As a result, ca. 40 elements in the concentration range from milligrams per gram to submicrograms per gram could be determined with relative standard deviations of less than 5%. The IWIBA sample from petrochemical wastes contained lower concentrations of the elements, because fewer mineral constituents were contained in the input waste materials. On the contrary, the elemental concentrations in the IWIBA sample from industrial solid wastes provided the highest values for most elements, while the elemental compositions of the IWIBA sample from food wastes were similar to those of municipal solid waste incineration bottom ash. In addition, it was found from the analytical results that the levels of various heavy metals such as Cr, Mn, Fe, Ni, Cu, As, Zr, Mo, Sb, Ba, and Pb were higher in the IWIBA samples than in municipal solid waste incineration bottom ash. The enrichment factors of the elements in the IWIBA samples were estimated from the analytical results to compare the elemental distributions in incineration bottom ashes in relation to their mining influence factors, which are the indices for human use of the elements. 相似文献
499.
500.
通过厌氧发酵4阶段动力学实验、产甲烷抑制实验及单一VFA的产甲烷动力学实验,探明了厨余和污泥共发酵过程中,典型组分对其潜在的酸积累类型以及甲烷化过程的影响。结果表明,不同基质组分在厌氧发酵过程中的VFA组成比例以及单一VFA的产甲烷化动力学特性,对其产甲烷潜能及速率有着决定性影响。乙酸的甲烷化速率高达44.80 mL·d-1,丁酸略慢于乙酸,而丙酸和戊酸的甲烷化速率不足乙酸的1/2,其中丙酸的延滞期长达1.76 d。因此,产酸类型以乙酸为主的污泥、菜类在产甲烷阶段不存在延滞期;而蛋肉类及油的产甲烷速率受到丙酸、戊酸动力学特性的影响相对较慢。通过调整共发酵基质配比不仅能够提高发酵潜能,还能够优化VFA组成比例,实现较高的甲烷产率及甲烷化速率。 相似文献