Influence of floc dynamic protection layer on alleviating ultrafiltration membrane fouling induced by humic substances

Cake layer formation is inevitable over time for ultrafiltration (UF) membrane-based drinking water treatment. Although the cake layer is always considered to cause membrane fouling, it can also act as a “dynamic protection layer”, as it further adsorbs pollutants and dramatically reduces their chance of getting to the membrane surface. Here, the UF membrane fouling performance was investigated with pre-deposited loose flocs in the presence of humic acid (HA). The results showed that the floc dynamic protection layer played an important role in removing HA. The higher the solution pH, the more negative the floc charge, resulting in lower HA removal efficiency due to the electrostatic repulsion and large pore size of the floc layer. With decreasing solution pH, a positively charged floc dynamic protection layer was formed, and more HA molecules were adsorbed. The potential reasons were ascribed to the smaller floc size, greater positive charge, and higher roughness of the floc layer. However, similar membrane fouling performance was also observed for the negative and positive floc dynamic protection layers due to their strong looseness characteristics. In addition, the molecular weight (MW) distribution of HA also played an important role in UF membrane fouling behavior. For the small MW HA molecules, the chance of forming a loose cake layer was high with a negatively charged floc dynamic protection layer, while for the large MW HA molecules it was high with a positively charged floc dynamic protection layer. As a result, slight UF membrane fouling was induced.     

Removal and desorption of chromium in synthetic effluent by a mixed culture in a bioreactor with a magnetic field

Two chromium removal experiments were performed in bioreactors with and without a magnetic field under the same conditions.The release of the chromium present in the biomass was tested in two experiments one with the initial pH of the medium and one with pH 4.0.The objective was to remove Cr(Ⅵ) and total Cr from the effluent,this was carried out by placing biological treatments of synthetic effluent contaminated with 100 mg/L of Cr(Ⅵ) in a bioreactor with neodymium magnets that applied a magnetic field(intensity85.4 mT) to the mixed culture.The removal of Cr(Ⅵ) was approximately 100.0% for the bioreactor with a magnetic field and 93,3% for the bioreactor without a magnetic field for9 hr of recirculation of the synthetic effluent by the bioreactor.The removal of total Cr was61.6% and 48.4%,with and without a magnetic field,respectively;for 24 hr.The desorption of Cr(VI) in the synthetic effluent was 0.05 mg/L,which is below the limit established by Brazilian legislation(0.1 mg/L) for the discharge of effluent containing Cr(Ⅵ) into bodies of water.The results obtained for the removal of chromium in synthetic effluent suggested that there was no significant influence on the viable cell count of the mixed culture.The desorption of Cr(Ⅵ) in synthetic effluent after bioadsorption of chromium by the mixed culture in the process of removal of chromium in bioreactors with and without a magnetic field was not significant in either of the experiments with different initial pHs.     

颗粒物分界层Mie散射激光雷达识别的sigmoid算法

基于成都市2013年6月~2015年5月期间由Mie散射激光雷达探测的大气消光系数廓线资料,发现混合层以上在颗粒物消光和分子消光之间一致存在一个S型的过渡区,利用sigmoid函数对此分布形态进行模拟,通过计算该函数上下曲率最大点所在的高度,据此提出了颗粒物分界层Mie散射激光雷达识别的sigmoid算法.针对该算法模拟效果的分析表明,颗粒物分界层过渡区附近大气消光系数理论廓线和实测廓线保持了高度的相关性,二者在春夏秋冬四季的相关系数（R）分别为0.9971±0.0052、0.9935±0.0167、0.9979±0.0038和0.9990±0.0021（均通过α=0.05的显著性检验）.基于sigmoid算法计算的颗粒物分界层过渡区与成都市温江站探空资料得到的逆温层之间存在很好的对应关系.     

7B04铝合金和30CrMnSiA钢短期腐蚀的电化学行为研究

目的研究7B04铝合金和30CrMnSiA合金钢试样的电化学性能。方法采用电化学实验、扫描电子显微镜(SEM)、腐蚀坑深度测试分别对7B04铝合金和30CrMnSiA合金钢试样在是否经过天然海水浸泡的情况下进行测试分析,得到微观腐蚀形貌和腐蚀坑深度以及试样表面不带锈和带锈时的电化学性能。结果随着Na Cl浓度增大,7B04铝合金和30CrMnSiA钢的自腐蚀电流变大,两者之间存在明显的电位差,接触后会发生电偶腐蚀。电偶电流与阴阳极面积比和Na Cl浓度有关,阴阳极面积比增大或Na Cl浓度升高均会导致电偶效应增强。经过海水短期浸泡后,7B04铝合金表面的锈层不仅没有起到抑制腐蚀的作用,反而使自腐蚀加重,但电偶效应确实有所减弱。结论沿海设备在使用过程中应竭力避免铝合金在锈层下工作。     

Application of CFD Methods for Modelling in Air Pollution Problems: Possibilities and Gaps

Different urban air pollution problems deal with complex structure of air flows and turbulence. For such problems the Computer Fluid Dynamics (CFD) methods become widely used. However, this approach despite a number of advantages has some problems. Experience of use of CFD tools for development of models and suggestions of their applications for a local scale air pollution over a complex terrain and stable stratification are discussed in this paper, including: Topography and complex geometry: choose of the co-ordinate system and computer grid; Turbulence closure for air pollution modelling: modified k- model for stable stratified ABL; Boundary conditions for vertical profiles of velocity for stable-stratified atmosphere; Effects of the radiation and thermal budget of inclined surfaces to dispersion of pollutants; Artificial sources of air dynamics and circulation.Some examples of CFD applications for air pollution modelling for a flat terrain, mountainous area, mining open cast and indoor ventilation are discussed. Modified k- model for stably-stratified ABL is suggested. Due to the isotropic character of the k- model a combination of it in vertical with the sub-grid turbulence closure in horizontal can be more suitable for ABL. An effective scheme of boundary conditions for velocity profiles, based on the developed similarity theory for stable-stratified ABL, is suggested. Alongside with the common studies of atmospheric dispersion, the CFD methods have also demonstrated a good potential for studying anthropogenic and artificial-ventilation sources of air dynamic and circulation in local-scale processes of air pollution.     

Mechanics Principle and Engineering Application of Split Layer and Bed Separation of Mining Overburden

<正>To control land surface subsidence caused the underground mineral exploitation and the catastrophic phenomena such as serious damage of buildings, waterbodies, cultivated lands, railways, bridges caused by land subsidence, bed separation grouting technology of overburden is put forward. To provide theoretical support for the technology, the characteristics and the mechanics mechanism of mining overburden from layer-split to formation of bed separation are studied. On the basis of elastic sheet board theory, calculation formula of rock sheet deflection is presented, and the mechanics criteria of the separation formation and the calculation formula of bed separation volume are set up. Finally, the applications and technics of bed separation grout technology of mining overburden to control land subsidence in china are introduced.     

重庆近11年大气混合层厚度研究

根据新闻颁国家标准ＧＢ／Ｔ１３２０１－９１的规定，计算了重庆地区近１１年大气混合厚度，分析结果表明，重庆地区大气混合层厚度有明显日变化和季节变化，大气稳定度是混合层厚度的主要决定因子。     

炼油污水气浮絮凝处理中试

气浮絮凝是炼油污水处理工艺中重要的一步 ,它是确保炼油污水生化处理顺利运行的关键 ,而开发和筛选优良的絮凝剂则又是提高气浮处理效果的保证。采用无机—有机复合絮凝剂进行炼油污水的中试试验 ,通过一系列条件试验 ,确定了复合絮凝剂投药剂量、投药间隔时间和投药方式 ,取得了令人满意的试验效果 ,CODCr的去除率 5 5 % ,石油类去除率 >75 % ,为后续的生化处理提供了合格的水质     

草履虫──针杆藻群落对混合印染废水净化作用的条件实验

本文对混合印染废水的静态净化过程，进行了生物群落观察和条件实验。发现废水净化初期以大量细菌和草履虫（以 Ｐ． Ｃａｕｄａｔｕｍ为主）繁殖为特征，同时伴生着少量浮游藻类。随着净化过程的进行，细菌和草履虫数量下降，以针杆藻（以 Ｓ． ａｕｃｓ为主）为建群种的浮游藻类群落占优势。化学分析表明，净化作用与温度、光照条件及废水起始浓度有关。     

宿迁3次突发性空气重污染过程对比分析

利用空气质量资料、常规观测资料、NCEP1.0°×1.0°再分析资料，应用数理统计、天气学等方法对宿迁市3次突发性重污染天气进行对比分析.结果表明：①宿迁"突发"空气重污染时，AQI级别由前一日的一、二级至第2日转为五级以上，AQI值迅速上升.②3次空气重污染过程天气背景相似，高层为宽广平直的偏西气流，地面受高压控制，中低层风向和温度平流突然转变，且都有深厚的逆温层结；持续变化较小的气压梯度、较低风速、温度日较差及相对湿度的增大（150328过程（即2015年3月28日—4月1日污染过程）除外）为颗粒物浓度迅速增长提供了条件.③大气稳定度级别迅速变高和混合层高度迅速降低并维持，对污染物快速聚集有显著影响.④物理量诊断表明，污染发生前期上空为弱上升运动，随后迅速转为下沉运动，或气流下沉运动区域迅速扩大、升高，是空气质量迅速转差的重要动力因素.⑤内蒙古地区的沙尘远距离输送形成的污染，是造成150328过程与另外两次过程明显不同的主要原因.