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1.
循环冷却水复配阻垢缓蚀剂配方的优化 总被引:2,自引:1,他引:2
阐述了循环冷却水对金属腐蚀的机理、阻垢缓蚀剂作用的原理,提出了复配缓蚀阻垢剂配方优化的原则及评价标准。并对攀钢煤化公司循环冷却水进行了复配缓蚀阻垢剂配方优化试验,通过配方优化试验,筛选出了DS—605型(浓度为100mg/L)的高效低磷有机膦阻垢缓蚀剂。该配方技术先进,其阻垢缓蚀效果优于GB/50050—95规定的指标要求,冷却水磷含量由原先的12mg/L降至6mg/L,年处理费用降低了27%,具有显著的经济效益和环保效益,目前正准备投入实际使用。 相似文献
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以某炼铁高炉妆环水为对象,对循环冷却水高PH碱性运行阻垢缓蚀进行了研究,筛选出了一复合配方。工业应用试验结果表明,此配方对A3钢的污垢附着速率,腐蚀速率和污垢热阻均低于国家规定的指标要求,说明该配方具有良好的阻垢缓蚀性能。 相似文献
3.
针对仪化热电厂将循环水用作冲灰水,导致浓缩倍率只有1.6,以及凝汽器铜管腐蚀结垢严重等问题,提出了隔断循环水与冲灰水的直接联系,实现闲路循环,对凝汽器铜管进行酸洗,并对循环水实施加缓蚀阻垢荆、杀菌剂和旁流过滤等办法,全部实施后产生了很好的效益,值得借鉴。 相似文献
4.
本文简介了循环冷却水系统的应用现状和面临的问题.同时论述了冷却水系统结垢的成因和阻垢的机理,并介绍了阻垢剂的发展历程、研究进展及其特点。最后总结概括了未来阻垢剂的发展趋势。 相似文献
5.
为了解决高温高盐矿井水对碳钢管道和设备腐蚀问题,进行了缓蚀挂片试验,研究适应该类水质的缓蚀剂种类和最佳投加量。试验结果表明:软化剂氢氧化钙和碳酸钠对碳钢均有一定缓蚀效果.其平均缓蚀率分别为17.33%、57.46%。因此药剂软化过程同时达到防腐效果有限:单独投加缓蚀剂HEDP的缓蚀效果明显,其静态缓蚀率82.46%以上,动态缓蚀率76.45%:复合配方缓蚀剂的缓蚀效果最好,最佳配方为“有机膦酸一聚环氧琥珀酸一锌盐”或“有机膦酸一磺酸基团多元共聚物一锌盐”,在投加量80mg/L时动态缓蚀率接近90%。 相似文献
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George SJ Sherbone J Hinz C Tibbett M 《Environmental pollution (Barking, Essex : 1987)》2011,159(10):2740-2749
Onshore oil production pipelines are major installations in the petroleum industry, stretching many thousands of kilometres worldwide which also contain flowline additives. The current study focuses on the effect of the flowline additives on soil physico-chemical and biological properties and quantified the impact using resilience and resistance indices. Our findings are the first to highlight deleterious effect of flowline additives by altering some fundamental soil properties, including a complete loss of structural integrity of the impacted soil and a reduced capacity to degrade hydrocarbons mainly due to: (i) phosphonate salts (in scale inhibitor) prevented accumulation of scale in pipelines but also disrupted soil physical structure; (ii) glutaraldehyde (in biocides) which repressed microbial activity in the pipeline and reduced hydrocarbon degradation in soil upon environmental exposure; (iii) the combinatory effects of these two chemicals synergistically caused severe soil structural collapse and disruption of microbial degradation of petroleum hydrocarbons. 相似文献
9.
Despite the widespread use of benzotriazoles as corrosion inhibitors in many household goods, studies on the occurrence of these compounds in indoor air are scarce. In this study, five benzotriazole derivatives were measured in 83 indoor air samples collected from various locations in Albany, New York, USA. Benzotriazoles were found in a majority of the indoor air samples, and the concentrations of their sum in bulk (vapor plus particulate phases) indoor air ranged from below the method limit of quantification to 492 ng·m?3 (geometric mean: 5.8 ng·m?3). The highest geometric mean concentration was found in air samples collected in parking garages (155 ng·m?3), followed by barbershops (13.6), public places (11.5), auto repair shops (5.2), automobiles (4.5), homes (4.5), offices (3.7), and laboratories (2.8). Inhalation exposure to benzotriazoles was calculated on the basis of the measured geometric mean concentrations and air inhalation rate. The highest exposure dose was found for teenagers, with a geometric mean inhalation exposure dose of 79 ng·day?1. The body-weight normalized exposure dose, however, was the highest for infants, at 3.2 ng·(kg bw)?1·day?1. 相似文献
10.
Propiconazole inhibits the sterol 14α-demethylase in Glomus irregulare like in phytopathogenic fungi
Calonne M Sahraoui AL Campagnac E Debiane D Laruelle F Grandmougin-Ferjani A Fontaine J 《Chemosphere》2012,87(4):376-383
The increasing concentrations impact (0.02, 0.2 and 2 mg L−1) of a Sterol Biosynthesis Inhibitor (SBI) fungicide, propiconazole, was evaluated on development and sterol metabolism of two non-target organisms: mycorrhizal or non-mycorrhizal transformed chicory roots and the arbuscular mycorrhizal fungus (AMF) Glomus irregulare using monoxenic cultures. In this work, we provide the first evidence of a direct impact of propiconazole on the AMF by disturbing its sterol metabolism. A significant decrease in end-products sterols contents (24-methylcholesterol and in 24-ethylcholesterol) was observed concomitantly to a 24-methylenedihydrolanosterol accumulation indicating the inhibition of a key enzyme in sterol biosynthesis pathway, the sterol 14α-demethylase like in phytopathogenic fungi. A decrease in end-product sterol contents in propiconazole-treated roots was also observed suggesting a slowing down of the sterol metabolism in plant. Taken together, our findings suggest that the inhibition of the both AM symbiotic partners development by propiconazole results from their sterol metabolism alterations. 相似文献