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141.
Thermal and mechanical properties of poly(lactic Acid) and poly(ethylene/butylene Succinate) blends 总被引:2,自引:0,他引:2
In this study, blends of poly (lactic acid) (PLA) with poly(ethylene/butylene succinate) (Bionolle) have been investigated
for their thermal and mechanical properties as a function of the concentration of Bionolle. Differential scanning calorimetry
(DSC), dynamic mechanical analysis (DMA), and tensile tests were used to characterize the blends. From the results of the
DMA and DSC, it was found that this blend system was not miscible within the compositions studied. DSC results showed that
adding Bionolle aids in crystallization of PLA. It was observed that increasing the Bionolle concentration led to a slight
increase in the strain-at-break of the blends but a decrease in the Young’s modulus and ultimate tensile strength. Biaxially
oriented films showed an increase in tensile strength, modulus, and strain-at-break. 相似文献
142.
The use of pressure-volume-temperature (PVT) studies in processing of a biodegradable plastic composition made from soy protein
isolate and corn starch is described. The ability of PVT measurements to predict the combined effects of pressure, volume,
and temperature effects is demonstrated. The results show that the PVT relations of the plastic can be predicted by using
a regression analysis similar to the Tait equations of state. A change in slope of the PVT curves was observed at around 80‡C,
which is ascribed to the glass-transition process of the plastic. Evidence of onset of thermal degradation of the plastic
was observed at ca. 160‡C under 0 to 200 MPa isobaric pressure. This thermal degradation precluded determination of the crystal
melting point of the plastic. 相似文献
143.
Ken’ichiro Matsumoto Yuko Arai Rina Nagao Takaaki Murata Kazuma Takase Hideo Nakashita Seiichi Taguchi Hiroaki Shimada Yoshiharu Doi 《Journal of Polymers and the Environment》2006,14(4):369-374
In this paper, the photosynthetic production of short-chain-length/medium-chain-length polyhydroxyalkanoate (PHA) copolymers is reported. The wild-type and highly active doubly mutated PHA synthase 1 (S325T/Q481K, abbreviated ST/QK) genes from Pseudomonas sp. 61-3 were introduced into Arabidopsis thaliana. Peroxisome targeting signal 1 (PTS1) was used to target PHA synthases into the peroxisome to synthesize PHA from the intermediates of the β-oxidation pathway. The transgenic Arabidopsis produced PHA copolymers consisting of 40–57 mol% 3-hydroxybutyrate, 21–49 mol% 3-hydroxyvalerate, 8–18 mol% 3-hydroxyhexanoate, and 2–8 mol% 3-hydroxyoctanoate. The maximum PHA contents were 220μ g/g cell dry weight (cdw) in leaves, and 36μ g/g cdw in stems, respectively. The expression of the ST/QK mutated PHA synthase in leaves gene did not lead to significant difference in PHA content and monomer composition of PHAs, compared to the wild-type PHA synthase gene, suggesting that the supply of monomers may be a rate-determining step of PHA biosynthesis in the peroxisome. However, in stems, there were significant differences dependent on whether the wild-type or ST/QK mutated PHA synthase was expressed. These results suggest that tissue-specific monomer availability is important in determining the final mol% composition of PHA copolymers produced by the peroxisome in plants. 相似文献
144.
Mechanical Properties with the Functional Group of Additives for Starch/PVA Blend Film 总被引:1,自引:0,他引:1
This paper deals with the mechanical properties and degree of swelling (DS) of starch/PVA blend film with the functional groups
i.e., hydroxyl and carboxyl group, of additives. Starch/PVA blend films were prepared by using the mixing process. Glycerol
(GL) with 3 hydroxyl group, sorbitol (SO) with 6 hydroxyl group, succinic acid (SA) with 2 carboxyl group, malic acid (MA)
with 1 hydroxyl and 2 carboxyl group, tartaric acid (TA) with 2 hydroxyl and 2 carboxyl group and citric acid (CA) with 1
hydroxyl and 3 carboxyl group were used as additives. The results of measured tensile strength (TS) and elongation (%E) verified
that both hydroxyl and carboxyl group as a functional groups increased the flexibility and strength of the film. Values of
DS for GL-added and SA-added films were low. However, DS values of the films added MA, TA or CA with both hydroxyl and carboxyl
group were comparatively high. When the film was dried at low temperature, the properties of the films were evidently improved.
The reason is probably because the hydrogen bonding was activated at low temperature. 相似文献
145.
The New Jersey Toxics Reduction Workplan for Ny-Nj Harbor: Distribution of Pcdd/Fs in Ambient Waters
As part of the NJ Toxics Reduction Workplan for NY-NJ Harbor, ambient water samples were collected at fifteen locations along
the tidal portions of the Hackensack, Passaic, Raritan, Rahway and Elizabeth Rivers, and in Newark Bay, the Arthur Kill, and
Kill van Kull. A Trace Organics Platform Sampler was used to collect a total of 75 suspended sediment phase samples between
June 2000 and May 2002. These samples were analyzed for spatial and wet vs. dry weather trends in the 17 polychlorinated dibenzo-p-dioxins
and dibenzofurans (PCDD/Fs; modified USEPA Method 1613b). Mean total PCDD/F (tPCDD/F) concentrations at the sampling locations
ranged between 3.8 and 41.5 ng/g. On average, OCDD accounted for almost 80% of the tPCDD/F concentrations; mean total [PCDD/F
– OCDD] concentrations ranged between 0.84 and 5.20 ng/g at the sampling locations. Mean 2,3,7,8-TCDD concentrations ranged
between 0.003 and 0.28 ng/g, with the highest concentrations (> 0.10 ng/g) along the tidal Passaic and lower Hackensack Rivers,
and in upper Newark Bay. Mean tPCDD/F Toxic Equivalency Quotients (TEQ) ranged between 45 and 344 TEQ pg/g, with the highest
levels found in the lower Passaic River. Toxicity was primarily driven by 2,3,7,8-TCDD concentrations in the Passaic and Hackensack
Rivers, and in Newark Bay. Examples of congener distribution patterns at some of the sampling locations are also presented. 相似文献
146.
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148.
九华山风景名胜区是山岳型宗教旅游地。通过对九华山风景区的实地调查,总结了该类旅游地的土地利用特点,即统一性和协调性、难以变更性、总量有限性,并进行了土地利用沿革、变更和影响方面的分析。利用层次分析法从生存指标、发展指标、社会指标、环境指标和智力指标5个方面对九华山风景区的土地利用进行了定量讨论,认为九华山风景区土地利用问题现阶段主要集中在九华街景区、花台景区和柯村景区。在此基础上,对九华山风景区土地的可持续利用提出了相应的对策。 相似文献
149.
150.