顶空气相色谱法测定水中苯系物实验研究

采用顶空气相色谱法对水中苯系物的测定方法进行了研究。在研究过程中讨论了盐,顶空平衡温度和平衡时间等因素对测定结果的影响。实验结果表明无机盐的加入可以提高苯系物的响应值,顶空平衡温度和平衡时间分别为60℃和50 min时为最优的实验分析条件。在此实验条件下,苯系物各组分回归方程的线性相关性较为显著。方法的检出限在2.5~5.9μg/L,加标回收率为93.8%～96.8%,相对标准偏差小于14.7%。该方法对于水中苯系物的测定准确、快捷、重现性好。     

国家节能中心组织2011-2012年度合同能源管理项目评审

本刊讯:在节能服务公司申报、地方初审的基础上,专家对地方上报的项目基本情况表、合同复印件、第三方节能量审核报告和效益分享证明等项目申报材料进行了评审,并出具了评审意见。从评审情况来看,合格项目的比例比去年明显提高,这表明在中心《财政奖励合同能源管理项目评审和现场核查工作指南》发布后,在地方节能主管部门严格把     

我国碳足迹盘查刚刚起步

中粮集团旗下中国粮油生化能源事业部的柠檬酸和淀粉产品分别依据PAS2050产品碳足迹标准实施了碳盘查,并顺利通过独立的第三方国际认证机构的核查。必维国际检验集团受中粮生化能源榆树有限公司委托执行碳足迹第三方核查的结果是：每吨食用玉米淀粉生命周期内产生CO2的当量是847．3千克,每40千克包装食用玉米淀粉生命周期内产生CO2的当量是33．98千克。     

浅析环保“三同时”验收工作中存在的问题及对策

从近年来的建设项目竣工环保验收情况来看,尽管逐年有所提高,但新开工的项目验收率仍不容乐观,同时遗留的历史欠账项目仍为数不少,如何依法加强建设项目环境保护验收管理,提升“三同时”验收率显得尤为重要.本文对建设项目环境保护设施验收管理的现状、存在的问题进行了阐述,并就如何进一步提高验收率提出了建议.     

QMS、EMS、OHSMS三个管理体系整合的探索

随着越来越多已经获得ISO9000质量体系(QMS)认证的组织建立和实施环境管理体系(EMS)和职业健康安全管理体系GB/T 28001-2001(OHSMS),并申请第三方认证,许多组织每年不得不投入相当大的人力、财力、时间资源维持两个或三个管理体系的运行和认证证书的注册资格.……     

氯碱企业生产过程中的重大危害分析及对策

分析了氯碱企业生产过程中的重大危害为中毒和火灾爆炸,提出了相应的对策.     

Application of magnetic particles modified with amino groups to adsorb copper ions in aqueous solution

A magnetic adsorbent can be easily recovered from treated water by magnetic force,without requiring further downstream treatment.In this research,amine-functionalized silica magnetite has been synthesized using N-[3-(trimethoxysilyl)propyl]-ethylenediamine(TPED) as a surface modification agent.The synthesized magnetic amine adsorbents were used to adsorb copper ions in an aqueous solution in a batch system,and the maximum adsorption was found to occur at pH 5.5 ± 0.1.The adsorption equilibrium data fitted t...     

韩国的生态工业园区

韩国曾经是亚洲"四小龙"之一。上世纪80年代的经济高增长创造了"韩国奇迹",人均GDP从60年代初的92美元上升到2万美元左右(数据来源:韩国银行数据库)。与中国类似,韩国的工业发展也大多集中于工业园区中。目前,韩国共设立了915个园区,其中工业同区有493个,包括国家级工业园区40家,区     

“十一五”：“三个转变”引航中国环保新道路

加快推进“三个转变”,是第六次全国环保大会的标志性成果,具有举旗定向之功,从思想观念、工作思路、管理手段等三个方面明确了“十一五”时期我国环境保护的核心举措。而“十一五”时期我国环保工作的成功经验则告诉我们,“三个转变”是真经,是环保工作的切实抓手,是科学发展观在环保工作中的具体体现,是探索中国环保新道路的指路航标。     

Unregulated emissions from diesel engine with particulate filter using Fe-based fuel borne catalyst

The alteration and formation of toxic compounds and potential changes in the toxicity of emissions when using after-treatment technologies have gained wide attention. Volatile organic compound（VOC）, carbonyl compound and particle-phase polycyclic aromatic hydrocarbon（PAH） emissions were tested at European Steady State Cycle（ESC） to study unregulated emissions from a diesel engine with a fuel-borne catalyst and diesel particulate filter（FBC–DPF）. An Fe-based fuel-borne catalyst was used for this study. According to the results, brake specific emissions of total VOCs without and with DPF were 4.7 and4.9 mg/kWh, respectively, showing a 4.3% increase. Benzene and n-undecane emissions increased and toluene emission decreased, while other individual VOC emissions basically had no change. When retrofitted with the FBC–DPF, total carbonyl compound emission decreased 15.7%, from 25.8 to 21.8 mg/kWh. The two highest carbonyls, formaldehyde and acetaldehyde, were reduced from 20.0 and 3.7 to 16.5 and 3.3 mg/kWh respectively. The specific reactivity（SR） with DPF was reduced from 6.68 to 6.64 mg/kWh. Total particle-phase PAH emissions decreased 66.4% with DPF compared to that without DPF. However, the Benzo[a]pyrene equivalent（BaPeq） with DPF had increased from 0.016 to 0.030 mg/kWh.Fluoranthene and Pyrene had the greatest decrease, 91.1% and 88.4% respectively. The increase of two- and three-ring PAHs with DPF indicates that the fuel-borne catalyst caused some gas-phase PAHs to adsorb on particles. The results of this study expand the knowledge of the effects of using a particulate filter and a Fe-based fuel-borne catalyst on diesel engine unregulated emissions.