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121.
122.
Experiments on CH4/Cl2/O2/N2 oxidation were conducted in an atmospheric pressure flow reactor to understand the influence of
chlorine on hydrocarbon oxidation in hazardous waste incineration. The reaction temperature varied from 973 to 1273 K and the
chlorine to hydrogen mole ratio (Cl/H) of the inlet mixture varied from 0 to 0.44. The species produced in the reaction were measured
online with Fourier transform infrared spectroscopy (FT-IR). It was found that the destruction and removal e ciency of CH4 increased
with Cl/H mole ratio. Increasing Cl/H favored COCl2 and CO formation and inhibited the CO oxidation process. As Cl/H approached
0.44, the concentrations of CH2Cl2 and CH3Cl first increased, and then declined. Reaction temperature greatly a ected the reaction
system. Increasing temperatures raised the destruction removal e ciency of CH4 and decreased the concentrations of CH3Cl and
CH2Cl2. With a certain ratio of Cl/H, the concentrations of CO and COCl2 first increased and then declined. The CO and COCl2
concentration peak was observed around 1100 K and 1023 K, respectively. When the reaction temperature exceeded 1273 K, carbon in
CH4 was mostly converted to CO2. It could be concluded that the presence of chlorine enhanced the destruction of CH4, but resulted in
the more toxic incomplete combustion products emission such as COCl2 when the reaction temperature was not high enough. 相似文献
123.
CUI Huxiong CHENG Tiantao YU Xingn CHEN Jianmin XU Yongfu FANG Wen 《环境科学学报(英文版)》2009,21(8):1103-1107
The variations of sulfate formation and optical coe cients during SO2 heterogeneous reactions on hematite surface under di erent
SO2 concentrations were examined using in situ di use reflectance infrared Fourier transform spectroscopy (DRIFTS) and ion
chromatograph (IC). Laboratory experiments revealed that within ambient SO2 of 0.51–18.6 ppmv, sulfate product, producing velocity,
absorption and backward scattering coe cients showed an increasing trend with SO2 concentration. Under given SO2 concentration,
the velocity of sulfate producing performed an evolution of initial increasing, midterm decreasing and final stabilizing. The reactive
uptake and Brunauer-Emmett-Teller (BET) uptake coe cients of heterogeneous reactions rose with SO2 and exhibited high reactivities.
Considering global warming, this result is important for the knowledge of heterogeneous reactions of SO2 on mineral particle surface
in the atmosphere and the assessment of their impacts on radiative forcing. 相似文献
124.
废聚氨酯硬泡热处理特性及产物检测分析 总被引:1,自引:1,他引:0
利用热重分析仪和管式炉研究了废弃聚氨酯硬泡热处理特性并对热处理产物进行了检测分析。研究结果表明,废聚氨酯硬泡热处理过程呈单一剧烈失重峰,热失重主要发生在200~440℃之间,600℃热分解基本完成;FTIR谱图初步分析发现加热分解过程中有大量CO和CO2产生,且热处理过程中可能有O-H、C-H、C=O及带有苯环的物质生成。通过GC/MS检测分析结果显示热处理液体产物中检出多元醇以及苯胺、p-苯胺、苯甲腈等多种芳香类化合物,气体产物以低碳的烷烃和烯烃为主,可见FTIR和GC/MS分析结果有很好的一致性。研究结果显示,气体产物检测出有机氯化合物,这可能是聚氨酯硬泡生产过程中加入的氟利昂类发泡剂所致。 相似文献
125.
纳米TiO_2的溶胶-微波法合成及其光催化性能研究 总被引:1,自引:0,他引:1
以钛酸四正丁酯为原料,采用溶胶-凝胶法、溶胶-水热法及溶胶-微波法三种方法合成出纳米TiO2,借助XRD、UV-Vis吸收光谱等测试手段对其进行了表征,并以甲基橙为模型污染物,考察了样品的光催化性能。物相分析表明,所得样品均为锐钛矿相TiO2,与其它两种方法相比,溶胶-微波法合成的样品衍射峰明显宽化,强度明显降低,说明该法合成出纳米TiO2粒径较小;UV-Vis吸收光谱表明,溶胶-微波法合成的样品在可见光区和紫外光区对光均呈现更强的吸收,说明该法合成的粉末对光具有更高的利用率。光催化实验表明,溶胶-微波法合成样品的光催化活性高于另两种方法,紫外灯连续照射5h,甲基橙溶液脱色率为99.06%。此外,将该样品用于延安卷烟厂蒸叶车间废水的光催化氧化处理,效果较好,太阳光照射3d后COD去除率为77.4%。 相似文献
126.
为明确工业噪声对大脑认知的负面影响,采集火电厂球磨机的工业噪声,征集10名在校大学生在90 dB(A)的稳态工业噪声状态下及安静状态下的32导联脑电图(EEG)。采用傅里叶变换方法进行频域分析,提取δ频段、θ频段、α1频段、α2频段和β频段功率谱,并进行统计分析。结果表明:噪声环境与静音环境相比较,被试在δ频段、θ频段功率谱值明显增加,在α1频段内,噪声状态的功率谱值高于静音状态,在α2频段内正好相反。生产性噪声刺激可导致被试注意力分散,可通过各波段功率谱值或比率参数等评估噪声对认知的影响程度大小。 相似文献
127.
128.
The article investigated the adsorption of Hg(II) on Macrocystis pyrifera and Undaria pinnatifida in monometallic system and in the presence of Zn(II), Cd(II) and Ni(II). 相似文献
129.
We report on the effects of forest management practices of understory removal and N-fixing species (Cassia alata) addition on soil
CO2 fluxes in an Eucalyptus urophylla plantation (EUp), Acacia crassicarpa plantation (ACp), 10-species-mixed plantation (Tp), and
30-species-mixed plantation (THp) using the static chamber method in southern China. Four forest management treatments, including
(1) understory removal (UR); (2) C. alata addition (CA); (3) understory removal and replacement with C. alata (UR+CA); and (4)
control without any disturbances (CK), were applied in the above four forest plantations with three replications for each treatment.
The results showed that soil CO2 fluxes rates remained at a high level during the rainy season (from April to September), followed by
a rapid decrease after October reaching a minimum in February. Soil CO2 fluxes were significantly higher (P < 0.01) in EUp (132.6
mg/(m2·hr)) and ACp (139.8 mg/(m2·hr)) than in Tp (94.0 mg/(m2·hr)) and THp (102.9 mg/(m2·hr)). Soil CO2 fluxes in UR and CA
were significantly higher (P < 0.01) among the four treatments, with values of 105.7, 120.4, 133.6 and 112.2 mg/(m2·hr) for UR+CA,
UR, CA and CK, respectively. Soil CO2 fluxes were positively correlated with soil temperature (P < 0.01), soil moisture (P < 0.01),
NO3?-N (P < 0.05), and litterfall (P < 0.01), indicating that all these factors might be important controlling variables for soil CO2
fluxes. This study sheds some light on our understanding of soil CO2 flux dynamics in forest plantations under various management
practices. 相似文献
130.
Leaf litterfall plays an important role in transporting atmospheric mercury to soil in forests area. 相似文献