紫外光催化氧化技术处理有机污染物的研究动态

主要介绍了北美先进的紫外光催化氧化技术对有机废水、废气的处理研究与应用，简要介绍三种类型光催化反应器的结构。该技术在国外处于研究阶段，预期应用前景很好，尤其适用于电力充沛地区有机废水、废气的处理，具有应用方便、处理效果好，投资费用低等特点。     

反挤压组合凹模的有限元优化设计方法

本文介绍反挤压组合凹模的有限元优化设计方法和对优化结果所作的光弹性实验验证。这种方法优于常规优化方法,达到了节省模具材料,提高模具承载能力的目的,也使模具的结构设计更趋合理。     

光塑性在连续挤压成形研究中的若干关键技术

分析了光塑性和连续挤压技术的特点,总结了光塑性在连续挤压成形研究中的若干关键技术,重点研究了连续挤压过程的光塑性实验建模、光塑性材料的选取、试样制取过程中存在的问题,为今后本领域工作的开展指出可能涉及到的问题.     

Photoelectrocatalytic degradation of Rose Bengal

An innovative photoelectrode, TiO2/T1 mesh electrode, was prepared by galvanostaticanodisation. The morphology and the crystalline texture of the TiO2 film on mesh electrode were examined by scanning electronic microscopy and Raman spectroscopy respectively. The examination results indicated that the structure and properties of the film depended on anodisation rate, and the anatase was the dominant component under the controlled experimental conditions. Degradation of Rose Bengal (RB) in photocatalytic (PC) and photoelectrocatalytic (PEC) reaction was investigated, the results demonstrated that electric biasing could improve the efficiency of photecatalytic reaction. The measurement results of TOC in photoelectrocatalytic degradation showed that the mineralisation of RB was complete relatively. The comparison between the degradation efficiency of RB in PEC process and that in aqueous TiO2 dispersion was conducted. The results showed that the apparent first-order rate constant of RB degradation in PEC process was larger than that in aqueous dispersion with 0.1%--0.3% TiO2 powder, but was smaller than that in aaueaus disverslon with 1.0% TiO2.     

Photocatalytic degradation of PCP-Na with TiO2 photocatalysis loaded with platinum

Titanium dioxide(TiO2) samples of different crystal forms were prepared by hydrolysis tetrbutyl titanate in various water to alkoxide ratios and sintering the hydrolysis product at different temperatures.The photocatalysts coated on hollow glass beads and loaded with platinum varying from 0.2% to 2.4% by weight.The photocatalytic degradation rate of sodium pentachlorophenolate (PCP-Na) depends on the preparing conditions such as:sintering temperatures,water to alkoxide ratios(R),platinum content and the size.The proper conditions of preparation photocatalysts are as follows:the ratio of tiO2:sodium silicate:hollow glass beads:platinum is 10:5:20:0.15(w/w),R is 100,sintering temperature is 650℃,and the size of hollow glass is 0.5-1mm.Under these conditions,the ratio between acatase and rutile of the photocatalyst is 2:1,and the photocatalytic activity is high.     

谷氨酸厂离交尾液处理工程实例

采用以光曝氧化塔和射流生化塔为主，并辅以高效混凝剂的处理工艺处理谷氨酸厂产生离交尾液的实例。该工程具有投资少、流程短、占地省、处理效果显著的特点，具有一定的试用价值。     

记忆光塑性法在包覆腔塑变区研究中的应用

记忆光塑性法是一种新的网格实验方法，文中首次应用记忆光塑性法对连续挤压包覆腔塑变区的流动特性进行研究，发现进入汇合腔的铝料大致分为三个方向流动，最后达到在芯线的四周均有材料向包覆模内流动，从而在锥形包覆模内形成轴对称挤压状态，有利于保证包覆产品的同心度。     

Continuous treatment of azo acid dyes by photo-dependent denitrifying sludge

Simultaneous removals of dye and nitrate by photo-dependent denitrifying sludge(PDDS)have been demonstrated in a continuousflow bench-scale reactor.The best C/N for the degradation of azo dyes by PDDS was 1.5.The specific removal rate of azo dye AB92 decreased with a decrease in hydraulic retention time and increased with a decrease in solids retention time.The degradation rate of TOC decreased with a decrease in hydraulic retention time.AB92,which has nitro and hydroxyl substitutions in non-para positions,was uniquely degraded.During continuous flow treatment experiments using PDDS,complete degradation of azo dyes AB92 and AO20 at influent concentrations of 40mg/L and 30mg/L,respectively,was achieved with an HRT of 16.     

LUM-F流动注射发光测量仪（化学发光液相色谱柱后检测器）

LUM-F流动注射发光测量仪主要用于进行各种化学发光或者生物发光的流动注射分析，可应用于化学发光流动注射研究和化学发光分析的连续监测；也可作为液相色谱柱后检测，应用于过渡金属离子、多环芳烃等环境有毒污染物的测定。仪器通过适当的改装，可以应用于微流控化学发光检测。（专利号：ZL02238063.9）     

激光光散射技术用于Fenton反应中Fe(Ⅲ)水解过程的研究

利用激光光散射技术，研究了不同条件下Ferton反应中Fe(Ⅲ)水解过程的粒径变化，并和一般铁盐体系中Fe(Ⅲ)水解过程进行了比较，结果表明，Fe(Ⅲ)的水解过程中，粒径变化受水解度B^*和铁盐浓度的影响，即B^*值愈大，浓度愈高，体系粒径愈大．并且在相同浓度和水解度B^*的条件下，Fenton反应生成的Fe(Ⅲ)比一般铁盐的水解聚合迅速，形成的粒径大，对采油废水进行处理的实验结果表明，Fenton体系对有机物的吸附去除效果明显优于常规铁盐体系，这可能与Fenton体系的高水解速率有关。