全文获取类型
收费全文 | 5755篇 |
免费 | 513篇 |
国内免费 | 1652篇 |
专业分类
安全科学 | 799篇 |
废物处理 | 245篇 |
环保管理 | 510篇 |
综合类 | 4605篇 |
基础理论 | 624篇 |
污染及防治 | 813篇 |
评价与监测 | 248篇 |
社会与环境 | 37篇 |
灾害及防治 | 39篇 |
出版年
2024年 | 48篇 |
2023年 | 186篇 |
2022年 | 230篇 |
2021年 | 271篇 |
2020年 | 208篇 |
2019年 | 212篇 |
2018年 | 132篇 |
2017年 | 159篇 |
2016年 | 230篇 |
2015年 | 283篇 |
2014年 | 500篇 |
2013年 | 317篇 |
2012年 | 347篇 |
2011年 | 415篇 |
2010年 | 332篇 |
2009年 | 339篇 |
2008年 | 381篇 |
2007年 | 366篇 |
2006年 | 388篇 |
2005年 | 329篇 |
2004年 | 308篇 |
2003年 | 309篇 |
2002年 | 231篇 |
2001年 | 192篇 |
2000年 | 151篇 |
1999年 | 166篇 |
1998年 | 135篇 |
1997年 | 135篇 |
1996年 | 131篇 |
1995年 | 129篇 |
1994年 | 90篇 |
1993年 | 67篇 |
1992年 | 46篇 |
1991年 | 58篇 |
1990年 | 51篇 |
1989年 | 41篇 |
1988年 | 2篇 |
1987年 | 4篇 |
1986年 | 1篇 |
排序方式: 共有7920条查询结果,搜索用时 484 毫秒
911.
本文通过黑云母的电子探针方法测试,分析闽西南地区才溪岩体、四方岩体及罗卜岭岩体中黑云母的地球化学特征及其成因意义。测试结果表明,才溪二长花岗岩中的黑云母为高铁黑云母,而四方花岗闪长岩及罗卜岭花岗闪长斑岩中的黑云母为高镁黑云母,在由黑云母成分确定的物质来源图上,它们均落入壳-幔混合源区域,表明其成因类型都是壳-幔混源型花岗岩,但随着形成时代的逐渐变新,其物质组成成分中幔源组分逐渐增多。 相似文献
912.
《安全.健康和环境》2010,(11):54-54
什么是工艺安全信息(PSI)?它是工厂里与工艺化学、设备以及技术有关的信息。通过多种渠道收集而得,包括研究和开发、设计施工、运行操作以及原材料、工艺技术和设备的供应商。如果你是一个操作人员或维修人员,你最先接触到的工艺安全信息就是工艺危害分析(PHA)。工艺安全信息就是一大摞提供给工艺危害分析小组的图纸、 相似文献
913.
电化学法测定化学需氧量的研究及应用动态 总被引:1,自引:0,他引:1
总结了近年来的电化学法测定化学需氧量的研究进展及在线自动监测领域的应用现状。介绍了电化学法快速、准确和低耗、无二次污染的特点,指出了电化学法是实现化学需氧量快速检测和在线自动监测的发展方向之一,具有广阔的应用前景和深入研究的价值。 相似文献
914.
600MW机组锅炉化学清洗 总被引:1,自引:0,他引:1
600MW机组运行锅炉本体采用盐酸清洗、檬酸漂洗、双氧水钝化的清洗工艺。通过有效的过程控制,达到了理想的清洗效果。清洗结果表明:采用盐酸大范围直接清洗的、柠檬酸漂洗和复合双氧水钝化工艺用时短,系统简单,清洗质量优良、安全可行。 相似文献
915.
A novel biphenyl-degrading bacterial strain LA-4 was isolated from activated sludge. It was identified as Dyella ginsengisoli according to phylogenetic similarity of 16S rRNA gene sequence. This isolate could utilize biphenyl as sole source of carbon and energy, which degraded over 95 mg/L biphenyl within 36 h. The major metabolites formed from biphenyl, such as 2-hydroxy-6-oxo-6-phenylhexa-2,4-dienoic acid (HOPDA) and benzoic acid, were identified by LC-MS. The crude cell extract of strain LA-4 exhibited the activity of 2,3-dihydroxybiphenyl 1,2-dioxygenase (2,3-DHBD) and the kinetic parameters were Km= 26.48 μmol/L and Vmax= 8.12 μmol/mg protein. A conserved region of the biphenyl dioxygenase gene bphA1 of strain LA-4 was amplified by PCR and confirmed by DNA sequencing. 相似文献
916.
Combined fluorescence and electrochemical investigation on the binding
interaction between organic acid and human serum albumin 总被引:1,自引:1,他引:0
Human serum albumin (HSA) is a plasma protein responsible for the binding and transport of fatty acids and a variety of exogenous chemicals such as drugs and environmental pollutants. Such binding plays a crucial role in determining the ADME (absorption, distribution, metabolism, and excretion) and bioavailability of the pollutants. We report investigation on the binding interaction between HSA and acetic acid (C2), octanoic acid (C8) and dodecanoic acid (C12) by the combination of site-specific fluorescent probe, tryptophan intrinsic fluorescence and tyrosine electrochemistry. Two fluorescent probes, dansylamide and dansyl-L-proline, were employed in the displacement measurement to study fatty acid interaction with the two drug-binding sites on HSA. Intrinsic fluorescence of tryptophan in HSA was monitored upon addition of the fatty acids into HSA. Electrocatalyzed response of the tyrosine residues in HSA by a redox mediator was used to investigate the binding interaction. Qualitatively, observations made by the three approaches are very similar. HSA did not show any change in either fluorescence or electrochemistry after mixing with C2, suggesting there is no significant interaction with the short-chain fatty acid. For C8, the measured signal dropped in a single-exponential fashion, indicative of independent and non-cooperative binding. The calculated association constant and binding ratio is 3.1×106 L/mol and 1 with drug binding Site I, 1.1×107 L/mol and 1 with Site II, and 7.0×104 L/mol and 4 with the tryptophan site. The measurement with C12 displayed multiple phases of fluorescence change, suggesting cooperativity and allosteric effect of C12 binding. These results correlate well with those obtained by the established methods, and validate the new approach as a viable tool to study the interactions of environmental pollutants with biological molecules. 相似文献
917.
Development and application of a two-dimensional water quality model for the
Daqinghe River Mouth of the Dianchi Lake 总被引:1,自引:1,他引:0
Water quality models are important tools to support the optimization of aquatic ecosystem rehabilitation programs and assess their efficiency. Basing on the flow conditions of the Daqinghe River Mouth of the Dianchi Lake, China, two-dimensional water quality model was developed in the research. The hydrodynamics module was numerically solved by the alternating direction iteration (ADI) method. The parameters of the water quality module were obtained through the in situ experiments and the lab analyses that were conducted from 2006 to 2007. The model was calibrated and verified by the observation data in 2007. Among the four modelled key variables that were water level, CODcr, NH3-N and PO4-P, the minimum value of the coefficient of determination (CoD) was 0.69, which mean the model performed reasonably well. The developed model was then applied to simulate the water quality changes at the downstream cross-section assuming that the designed restoration programs were implemented. According to the simulated results, the restoration programs could cut down the loads of CODcr and PO4-P about 15%, however, they would have very little effect on the NH3-N removal. Besides, the water quality at the outlet cross-section would be still in class V (3838-02), indicating more measures should be taken to further reduce the loads. The study demonstrated the capability of water quality models to support aquatic ecosystem restorations. 相似文献
918.
Influence of temperature on the characteristics of aerobic granulation in
sequencing batch airlift reactors 总被引:2,自引:1,他引:1
Aerobic granular sludge was cultivated in sequencing batch airlift reactors(SBAR) at 25,30,and 35°C,respectively.The effect of temperature on the granules characteristics was analyzed and the microbial community structures of the granules were probed using scanning electron microscope(SEM) and polymerase chain reaction-denaturing gradient gel electrophoresis(PCR-DGGE).The results showed that 30°C is optimum for matured granule cultivation,where the granules had a more compact structure,better settling abili... 相似文献
919.
Alkaline and ultrasonic sludge disintegration can both be used as pretreatments of waste activated sludge (WAS) for improving the subsequent anaerobic or aerobic digestion. The pretreatment has been carried out using different combination of these two methods in this study. The effect was evaluated based on the quantity of soluble chemical oxygen demand (SCOD) in the pretreated sludge as well as the degradation of organic matter in the following aerobic digestion. For WAS samples with combined pretreatment, the released COD was in high level than those with ultrasonic or alkaline treatment. When combined with the same ultrasonic treatment, NaOH treatment resulted in more solubilization of WAS than Ca(OH)2. For combined NaOH and ultrasonic treatments with different sequences, the released COD were in the order: simultaneous treatment > ultrasonic treatment following NaOH treatment > NaOH treatment following ultrasonic treatment. For simultaneous treatment, low NaOH dosage (100 g/kg dry solid), short duration (30 min) of NaOH treatment, and low ultrasonic specific energy (7 500 kJ/kg dry solid) were beneficial for sludge disintegration. Using combined NaOH and ultrasonic pretreatment with the optimium parameters, the degradation efficiency of organic matter was increased from 38.0% to 50.7%, which is much higher than with ultrasonic (42.5%) or with NaOH pretreatment (43.5%) in the subsequent aerobic digestion at the same retention time. 相似文献
920.