全文获取类型
收费全文 | 904篇 |
免费 | 78篇 |
国内免费 | 121篇 |
专业分类
安全科学 | 391篇 |
废物处理 | 52篇 |
环保管理 | 62篇 |
综合类 | 392篇 |
基础理论 | 92篇 |
污染及防治 | 60篇 |
评价与监测 | 12篇 |
社会与环境 | 10篇 |
灾害及防治 | 32篇 |
出版年
2024年 | 17篇 |
2023年 | 47篇 |
2022年 | 45篇 |
2021年 | 41篇 |
2020年 | 27篇 |
2019年 | 24篇 |
2018年 | 21篇 |
2017年 | 21篇 |
2016年 | 32篇 |
2015年 | 42篇 |
2014年 | 82篇 |
2013年 | 55篇 |
2012年 | 57篇 |
2011年 | 56篇 |
2010年 | 40篇 |
2009年 | 56篇 |
2008年 | 67篇 |
2007年 | 51篇 |
2006年 | 48篇 |
2005年 | 35篇 |
2004年 | 43篇 |
2003年 | 27篇 |
2002年 | 28篇 |
2001年 | 19篇 |
2000年 | 14篇 |
1999年 | 18篇 |
1998年 | 11篇 |
1997年 | 12篇 |
1996年 | 18篇 |
1995年 | 11篇 |
1994年 | 5篇 |
1993年 | 11篇 |
1992年 | 6篇 |
1991年 | 9篇 |
1990年 | 5篇 |
1989年 | 2篇 |
排序方式: 共有1103条查询结果,搜索用时 755 毫秒
31.
32.
为有效去除水中Cd(Ⅱ),以TiO2纳米粉和NaOH为原料,调节水热反应温度分别为100、120、150和190℃,制备出了不同形貌的TNs(钛酸盐纳米材料),分别记为TNs-100、TNs-120、TNs-150和TNs-190,并对其形貌、结构、比表面积、化学组成等物理化学性能进行了表征;通过对水中Cd(Ⅱ)的静态吸附试验,考察了TNs对Cd(Ⅱ)的吸附性能.结果表明:随着合成温度的升高,TNs的形貌逐渐从纳米片演变成纳米管,管长逐渐变长,最后变成纳米棒.TNs-100的晶型结构主要是锐钛矿型;随着温度升高,结晶度逐渐增强;TNs-190出现了部分金红石相.TNs-150对Cd(Ⅱ)的吸附能力最强,最大平衡吸附量为254.66 mg/g,最佳吸附pH为5.0.再生的TNs-150对Cd(Ⅱ)循环吸附6次的去除率和解吸率均可达93%以上.TNs-150对Cd(Ⅱ)的吸附过程符合准二阶动力学方程和Langmuir吸附等温模型,吸附机制主要是TNs层间Na+和H+与溶液中Cd(Ⅱ)的离子交换.研究显示,TNs的饱和吸附量均高于同类吸附剂,能有效去除水中Cd(Ⅱ). 相似文献
33.
为研究燃气管道回填施工过程中管道的受力情况,利用岩土有限元分析软件PLAXIS 3D,构建了地基-管道-回填材料-施工荷载的动力响应数值模型,设计了多种工况情景以及对应的施工机械动力荷载的数学表达形式,并对燃气管道回填施工各结构层压实过程中多种不利工况下管道的动力响应进行了数值模拟计算与分析,提出了管道安全性的评价准则并对管道的安全性进行了评估。结果表明:按照该回填施工方案,施工过程中管道的应力范围在35 MPa以内,管道压应变竖向位移小于5mm,管道处于安全范围。通过分析不同地基土体参数以及管道参数下管道的动力响应,得到了各影响因素对管道应力和位移的影响规律,可为深入了解管道在不同荷载作用下的动力响应及回填施工方案设计提供依据。 相似文献
34.
35.
Although microbial treatments of heavy metal ions in wastewater have been studied, the removal of these metals through incorporation into carbonate minerals has rarely been reported. To investigate the removal of Fe^3+ and Pb^2+, two representative metals in wastewater, through the precipitation of carbonate minerals by a microbial flocculant (MBF) produced by Bacillus mucilaginosus. MBF was added to synthetic wastewater containing different Fe^3+ and Pb^2+ concentrations, and the extent of flocculation was analyzed. CO2 was bubbled into the mixture of MBF and Fe^3+/Pb^2+ to initiate the reaction. The solid substrates were analyzed via X-ray diffraction, transmission electron microscopy and energy dispersive spectroscopy. The results showed that the removal efficiency decreased and the MBF adsorption capacity for metals increased with increasing heavy metal concentration. In the system containing MBF, metals (Fe^3+ and Pb^2+), and CO2, the concentrated metals adsorbed onto the MBF combined with the dissolved CO2, resulting in oversaturation of metal carbonate minerals to form iron carbonate and lead carbonates. These results may be used in designing a method in which microbes can be utilized to combine CO2 with wastewater heavy metals to form carbonates, with the aim of mitigating environmental problems. 相似文献
36.
37.
38.
燃气透平发电机组是石油开采设施配置电站时常用机组,其正常运转和维保直接关系到石油生产和生活。本文介绍了始于上世纪90年代末引入设备管理领域的RCA(根本原因分析法)工具的概念和实施过程以及燃气轮机机组维保体系现状,同时通过两例详细的RCA过程实践,提出了将RCA工具引入燃气轮机维保体系中的应用策略或推广方案,构建了RCA工具参与下的维保体系模型。 相似文献
39.
Efficient dechlorination of chlorinated solvent pollutants under UV irradiation by using the synthesized TiO2 nano-sheets in aqueous phase 总被引:1,自引:0,他引:1
Landry Biyoghe Bi Ndong Murielle Primaelle Ibondou Zhouwei Miao Xiaogang Gu Shuguang Lu Zhaofu Qiu Qian Sui Serge Maurice Mbadinga 《环境科学学报(英文版)》2014,26(5):1188-1194
Titanium dioxide(TiO2), which is the widely used photo-catalyst, has been synthesized by simple hydrothermal solution containing tetrabutyl titanate and hydrofluoric acid. The synthesized product has been applied to photo-degradation in aqueous phase of chlorinated solvents, namely tetrachloroethene(PCE), trichloroethene(TCE) and 1,1,1-trichloroethane(TCA). The photo-degradation results revealed that the degradation of these harmful chemicals was better in UV/synthesized TiO2 system compared to UV/commercial P25 system and UV only system. The photo-catalytic efficiency of the synthesized TiO2 was 1.4, 1.8 and 3.0 folds higher compared to the commercial P25 for TCA, TCE and PCE degradation, respectively. Moreover, using nitrobenzene(NB) as a probe of hydroxyl radical(.OH), the degradation rate was better over UV/synthesized TiO2, suggesting the high concentration of.OH generated in UV/synthesized TiO2system. In addition,.OH concentration was confirmed by the strong peak displayed in EPR analysis over UV/synthesized TiO2system. The characterization result using XRD and TEM showed that the synthesized TiO2 was in anatase form and consisted of well-defined sheet-shaped structures having a rectangular outline with a thickness of 4 nm, side length of 50 nm and width of 33 nm and a surface 90.3 m2/g. XPS analysis revealed that ≡Ti-F bond was formed on the surface of the synthesized TiO2. The above results on both photocatalytic activity and the surface analysis demonstrated the good applicability of the synthesized TiO2 nano-sheets for the remediation of chlorinated solvent contaminated groundwater. 相似文献
40.
Removal of noxious dyes is gaining public and technological attention. Herein grafting polymerization was employed to produce a novel adsorbent using acrylic acid and carboxymethyl cellulose for dye removal. Scanning electron microscopy and Fourier-transform infrared spectroscopy verified the adsorbent formed under optimized reaction conditions. The removal ratio of adsorbent to Methyl Orange, Disperse Blue 2BLN and malachite green chloride reached to 84.2%, 79.6% and 99.9%, respectively. The greater agreement between the calculated and experimental results suggested that pseudo second-order kinetic model better represents the kinetic adsorption data. Equilibrium adsorptions of dyes were better explained by the Temkin isotherm. The results implied that this new cellulose-based absorbent had the universaiity for removal of dyes through the chemical adsorption mechanism. 相似文献