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941.
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944.
Removal of polycyclic aromatic hydrocarbons (PAHs), e.g., naphthalene, acenaphthene, phenanthrene and pyrene, from aqueous solution by raw and modified plant residues was investigated to develop low cost biosorbents for organic pollutant abatement. Bamboo wood, pine wood, pine needles and pine bark were selected as plant residues, and acid hydrolysis was used as an easily modification method. The raw and modified biosorbents were characterized by elemental analysis, Fourier transform infrared spectroscopy and scanning electron microscopy. The sorption isotherms of PAHs to raw biosorbents were apparently linear, and were dominated by a partitioning process. In comparison, the isotherms of the hydrolyzed biosorbents displayed nonlinearity, which was controlled by partitioning and the specific interaction mechanism. The sorpfion kinetic curves of PAHs to the raw and modified plant residues fit well with the pseudo second-order kinetics model. The sorption rates were faster for the raw biosorbents than the corresponding hydrolyzed biosorbents, which was attributed to the latter having more condensed domains (i.e., exposed aromatic core). By the consumption of the amorphous cellulose component under acid hydrolysis, the sorption capability of the hydrolyzed biosorbents was notably enhanced, i.e., 6-18 fold for phenanthrene, 6-8 fold for naphthalene and pyrene and 5-8 fold for acenaphthene. The sorpfion coefficients (Kd) were negatively correlated with the polarity index [(O+N)/C], and positively correlated with the aromaticity of the biosorbents. For a given biosorbent, a positive linear correlation between logKoc and logKow for different PAHs was observed. Interestingly, the linear plots of logKoc-logKow were parallel for different biosorbents. These observations suggest that the raw and modified plant residues have great potential as biosorbents to remove PAHs from wastewater. 相似文献
945.
Multi-walled carbon nanotube(MWCNT) sheet was fabricated from a drawable MWCNT forest and then deposited on poly(methyl methacrylate) film. The film was further coated with a natural antimicrobial peptide nisin. We studied the effects of nisin coating on the attachment of Bacillus anthracis spores, the germination of attached spores, and the subsequent biofilm formation from attached spores. It was found that the strong adsorptivity and the super hydrophobicity of MWCNTs provided an ideal platform for nisin coating. Nisin coating on MWCNT sheets decreased surface hydrophobicity, reduced spore attachment, and reduced the germination of attached spores by 3.5 fold, and further inhibited the subsequent biofilm formation by 94.6% compared to that on uncoated MWCNT sheet. Nisin also changed the morphology of vegetative cells in the formed biofilm.The results of this study demonstrated that the anti-adhesion and antimicrobial effect of nisin in combination with the physical properties of carbon nanotubes had the potential in producing effective anti-biofilm formation surfaces. 相似文献
946.
Fast increasing of surface ozone concentrations in Pearl River Delta characterized by a regional air quality monitoring network during 2006-2011 总被引:1,自引:0,他引:1
Jinfeng Li Keding Lu Wei Lv Jun Li Liuju Zhong Yubo Ou Duohong Chen Xin Huang Yuanhang Zhang 《环境科学学报(英文版)》2014,26(1):23-36
Based on the observation by a Regional Air Quality Monitoring Network including 16 monitoring stations, temporal and spatial variations of ozone(O3), NO2and total oxidant(Ox) were analyzed by both linear regression and cluster analysis. A fast increase of regional O3concentrations of 0.86 ppbV/yr was found for the annual averaged values from 2006 to 2011 in Guangdong, China. Such fast O3increase is accompanied by a correspondingly fast NOx reduction as indicated by a fast NO2 reduction rate of 0.61 ppbV/yr. Based on a cluster analysis, the monitoring stations were classified into two major categories – rural stations(non-urban) and suburban/urban stations. The O3concentrations at rural stations were relatively conserved while those at suburban/urban stations showed a fast increase rate of 2.0 ppbV/yr accompanied by a NO2 reduction rate of 1.2 ppbV/yr. Moreover, a rapid increase of the averaged O3 concentrations in springtime(13%/yr referred to 2006 level) was observed, which may result from the increase of solar duration, reduction of precipitation in Guangdong and transport from Eastern Central China. Application of smog production algorithm showed that the photochemical O3production is mainly volatile organic compounds(VOC)-controlled. However, the photochemical O3production is sensitive to both NOx and VOC for O3pollution episode. Accordingly, it is expected that a combined NOx and VOC reduction will be helpful for the reduction of the O3 pollution episodes in Pearl River Delta while stringent VOC emission control is in general required for the regional O3 pollution control. 相似文献
947.
我国辐射环境自动监测系统建设的回顾与展望 总被引:1,自引:0,他引:1
辐射环境自动监测是我国辐射环境监测工作的重要内容,是核与辐射安全监管工作的重要手段.本文回顾了“十一五”以来,我国辐射环境自动监测系统建设的进展情况和在核与辐射监管工作中所发挥的作用,总结了辐射环境自动监测系统的建设和运行经验,并对今后的工作进行了展望,提出了完善系统建设和运行的合理化建议.研究指出,作为国家辐射环境监测网的重要组成部分,辐射环境自动监测系统初步具备了对我国省会城市和主要地级城市的辐射环境质量状况的实时监测能力.但由于我国辐射环境自动监测站于2008年底才开始在全国范围内建设,起步较晚、经验不足,依然存在点位数量和代表性不够、自动化程度不够高、软件系统功能不成熟、标准化和规范化问题比较突出,缺乏质量控制技术、运行维护难度大等问题.为此本文提出:第一,增加自动监测站数量,点位布设更有针对性;第二,增加自动监测站的类型;第三,加强软件系统的分析和控制能力;第四,完善相关标准、技术规范和质保体系;第五,完善运行维护体系;第六,增强国际学习和交流. 相似文献
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949.
<正>澳大利亚地处南半球,孤悬于太平洋与印度洋之间,四面环海,是世界上唯一一个独占一个大陆的国家。澳大利亚人口2327万,相当于欧洲的4/5。国土面积为769.2万平方公里,东西距离约4000千米,南北距离约3860千米,居世界第六位,而人口密度为世界上最低的国家,平均每平方千米仅有3人。全澳划分为六个州和两个地区。东部是山地,中部是平原,西部是高原。内陆为荒芜人烟的沙漠,干旱少雨,气温高,温差大;在沿海地区,雨量充沛,气候湿 相似文献
950.
通过对北京和天津地区18条土壤剖面样品中PAHs的分析检测及PAHs的土柱淋滤实验模拟研究,得出了部分反映PAHs污染源的分子标志物参数在土壤剖面(或淋滤土柱)上的纵向变化特征,分析了PAHs化合物的纵向迁移作用对这些参数的影响,讨论了部分用于识别土壤中PAHs污染源的分子标志物参数的有效性。结果表明:在土壤剖面0~50 cm范围内,An/Ph,MPI1,MP/P值均有随深度增加而逐渐降低的趋势,在深层(>50 cm)不同剖面之间这些参数值差别不大;Fl/Py随深度增大呈现一定的波动性,但总体波动范围较小,且在0~40 cm变化不大;C0/(C0+C1)P/A和C0/(C0+C1)F/P值变化较为复杂。土柱淋滤实验表明,在0~50 cm范围内,部分PAHs污染源识别参数(An/178、MPI1、MP/P、C0/(C0+C1)F/P和C0/(C0+C1)P/A等)随深度的变化趋势与自然土壤剖面中的变化趋势基本一致,在深层50~100 cm范围内,这些参数值的大小逐渐与原土中的接近。表明淋滤作用(迁移过程)对表层土及土壤剖面浅部(50 cm范围内)部分PAHs污染源参数值的大小有不同程度的影响,运用PAHs污染源识别参数时,这些参数的有效性应引起足够的注意;而剖面深部(>50 cm)PAHs参数值受表层污染物组成的影响较小,其大小主要反映原土中化合物组成及成因。不同剖面受淋滤作用影响的范围存在一定的差别,这主要取决于土壤中TOC的分布特征。 相似文献