煤粉灰的粉体特性及其对减水效应的影响

通过对粉煤灰颗粒形貌，平均粒径，粒度分布等粉体特性参量的测定和计算分析，发现粉煤灰的减水效应主要来自圆球形玻璃微珠的滚珠轴承润滑作用或对水泥絮凝结构的分散作用，过细的粉煤灰大掺量取代水泥后有可能会降低其减水效应。     

人类可持续发展指数的改进及国际比较

对人类发展指数进行绿色及公平修正是可持续发展的必然要求。基于28个国家1990-2014年的面板数据,采用生态足迹改进人类可持续发展指数,并对其分解探讨变迁原因,在此基础上进行公平校正构建综合可持续发展指数。结果表明：生物质盈余发达国家排名靠前,影响其可持续发展的主要因素是高碳排放,生物质赤字国家通过转移别国资产维持发展,不平衡导致美国的综合可持续性下降;发展中国家的收入与教育快速提升,但生态消耗及不公平度持续上升,抑制作用逐渐扩大,阿联酋排名末位,发展方式最不可持续;最不发达国家的发展主要来自健康、教育及低生态消耗的贡献。分项维度间高度相关,可持续发展需在社会、经济、生态、公平间进行更好的权衡。     

湖南省能源消费碳排放驱动因素及趋势预测实证分析

基于灰色系统理论,建立STIRPAT多变量非线性模型定量研究了湖南省6个角度11个指标对能源消费碳排放的影响。将缓冲算子理论与灰色预测分析相结合,在构建灰色Verhulst模型的同时,采用幂平均弱化缓冲算子对能源消费碳排放量原始数据作优化修正处理并预测未来5年碳排放量。结果表明:产业结构对碳排放关联程度最高、能源结构因素边际贡献率最大,弹性系数为-0.2055,经过幂平均弱化缓冲算子处理的模型具有更高的预测精度。通过定性分析湖南省能源消费碳排放量变化特征,定量计算碳排放驱动因素的边际贡献度,结合其发展趋势和预测结果,可为湖南省节能减排政策的制定提供参考。     

热释放速率设定方式的几点讨论

如何结合给定的火灾场景合理地设定热释放速率的变化规律是火灾危险分析中的一个题.对现有的设定火灾热释放速率的方法进行了分析,在前人研究的基础上完善了分段平均方法和分段线性方法,并通过两个实例说明如何应用现有的方法来合理地设定出火灾热释放速率曲线,为今后火灾热释放速率曲线设定工作的发展提供了一条思路.     

上海能源消费碳排放分解研究

能源利用不仅为经济活动提供动力还大量排放二氧化碳.为分解上海市能源消费CO2排放的影响因素,明晰上海市能源消费CO2排放变化特征,采用指数分解分析方法建立了上海市能源消费碳排放的LMDI分解模型,从经济规模、产业结构、能源强度和产业碳排放系数4个影响因素着手,实证研究了1995-2005年上海分三次产业的能源消费碳排放变化机理.结果表明:经济快速增长是上海碳排放增加的主导因素,能源强度下降是抑制碳排放增长的重要因素.产业结构,能源结构优化有利于控制碳排放,而重工业化、能源结构高碳化会增加碳排放.基于实证分析结果和上海市情,提出了上海市未来控制碳排放的相关政策建议.     

西安市城市主干道路面径流污染特征研究

在西安市城市主干道南二环路建立路面径流原位采样站,利用自制流量等比例采样装置,全程收集2009年3月~2010年2月的32场降雨产生的路面径流,测试径流SS、COD、溶解性COD、NH3-N、Pb、溶解性Pb、Zn和溶解性Zn的事件平均浓度(EMC),研究路面径流污染强度、污染物赋存状态、相关关系、浓度影响因素以及季节变化规律.结果表明,城市主干道路面径流污染物EMC变异大且污染严重,SS、COD、溶解性COD、NH3-N、Pb、Zn、溶解性Zn的EMC中值分别为1543,574,129,1.86,0.042,0.219,0.111mg/L,变异系数0.41~0.8,其中SS、COD的EMC中值远大于《污水综合排放标准》三级标准,是主要污染物.路面径流中Pb主要以颗粒态存在,而47.4%的Zn、25.1%的COD呈溶解态.径流中颗粒物是许多其他污染物的载体,COD、Pb、Zn均与SS在显著性水平0.01时显著相关,相关系数分别为0.845,0.807和0.903.表征降雨特征的各因子中,降雨量、最大降雨强度与污染物浓度呈负相关,降雨历时与除NH3-N之外的其他污染物呈负相关,相关性依次为降雨量>最大降雨强度>降雨历时,前期晴天时间与溶解性Zn和溶解性COD浓度正相关,但与其它污染指标不相关.方差分析结果表明,SS、COD和NH3-N浓度随季节明显变化,而溶解态COD、重金属Pb、Zn和溶解态Zn的浓度季节差异不大.     

Passive air sampling of organochlorine pesticides in a northeastern state of India, Manipur

Thirty-six polyurethane foam disk passive air samplers (PUF-PAS) were deployed over a year during January to December, 2009 at three locations, i.e., Imphal (urban site), Thoubal (rural site) and Waithou (alpine site) of Manipur, to assess the seasonal local atmospheric emission of selected organochlorine pesticides (OCPs). The average concentration of HCHs monitored at mountain site during hot season (Mar, Apr, and May) and rainy seasons (Jun, Jul, Aug, and Sep) were 403 and 349 pg/m3, respectively. DDTs had a high concentration with 384 pg/m3 at rural site and 379 pg/m3 at urban site during hot seasons. Endosulfans and chlordane were found high in concentration during hot seasons (260 pg/m3) and low during retreating monsoon seasons (44 pg/m3) at rural site. Most of the OCPs concentrations were high during cultivation period. The OCP concentrations of rainy season were highly correlated (p < 0.01) with OCPs of hot seasons. Further, positive correlation (p < 0.05) was also obtained between cold seasons and retreating monsoon. Principal component analysis showed a significant correlation among the four seasons and distribution pattern of OCPs in air. Back trajectory analysis by using HYPSLIT model showed a long range air transport of OCPs to the present study area. Present OCP levels at Manipur is an outcome of both local emission and also movement of air mass by long range atmospheric transport.     

Levels and distribution of brominated flame retardants in the soil of Harbin in China

This study reports the presence of brominated flame retardants in the topsoil in and around Harbin, a city in northeastern China. Samples of soil were collected from 17 locations in 2006, and the levels of 9 polybrominated diphenylethers (PBDEs 17, 28, 47, 66, 99, 100, 153, 154, and 183) ranged from 2.45 to 55.9 pg/g dry weight (dw) with a mean of 26.3 pg/g dw. These levels are very low comparing with those for some cities in Europe and USA. BDE 209 and hexabromocyclododecane were the two dominant congeners, with mean concentrations of 520 pg/g dw and 1750 pg/g dw, respectively. The concentrations of the total nine PBDE congeners clearly decreased from urban areas to background, but the compositions of individual congeners di ered. Proportions of heavier congeners decreased while those of lighter congeners increased, along urban-rural-background transect, providing evidence for an urban fractionation e ect. Correlation analysis indicated similar sources for PBDEs, hexabromocyclododecane, and 1,2-bis(2,4,6-tribromophenoxy)-ethane from urban areas but pentabromoethylbenzene was probably present due to long-range atmospheric transport. Principal component analysis was used to determine the characteristics of the relationships among these brominated flame retardants in the field.     

旱作农业土壤矿质态氮随地表径流迁移特征研究

为了了解旱作农业土壤中氮素随地表径流的流失水平及规律,于野外夏玉米试验田中进行了模拟降雨与自然降雨条件下的对比试验,并通过对水量和水质的同步监测,研究了不同施肥水平下氮素的流失效应.其中,模拟降雨采用的两个降雨强度分别为40和70mm.h-1,3个尿素施肥水平分别为287、431和575kg.hm-2(以N计),每次自然降雨的试验小区布置相同.试验期间,共有20次降雨事件(包括模拟降雨),其中,4次降雨过程中产生了地表径流并有氮素流失.结果表明,次降雨径流过程中硝态氮流失浓度先迅速增大后逐步降低,而铵态氮流失浓度变化平稳,且流失浓度较低.次降雨间氮素流失平均浓度相差较大,尤其体现在硝态氮浓度上更为明显.此外,研究发现,次降雨径流过程地表氮素流失初期效应明显,且受降雨强度影响显著.通过氮素流失水平的计算发现,研究区大于25mm的降雨类型会有明显的地表径流产生及氮素流失.     

Multiple linear regression models of urban runo pollutant load and event mean concentration considering rainfall variables

Rainfall is an important factor in estimating the event mean concentration (EMC) which is used to quantify the washed-o pollutant concentrations from non-point sources (NPSs). Pollutant loads could also be calculated using rainfall, catchment area and runo coe cient. In this study, runo quantity and quality data gathered from a 28-month monitoring conducted on the road and parking lot sites in Korea were evaluated using multiple linear regression (MLR) to develop equations for estimating pollutant loads and EMCs as a function of rainfall variables. The results revealed that total event rainfall and average rainfall intensity are possible predictors of pollutant loads. Overall, the models are indicators of the high uncertainties of NPSs; perhaps estimation of EMCs and loads could be accurately obtained by means of water quality sampling or a long term monitoring is needed to gather more data that can be used for the development of estimation models.