Oxidation of gaseous elemental mercury in a high voltage discharge reactor

Effects of the voltage waveform, discharge tooth wheel number and CO2/NO/SO2 concentration in the simulated flue gas on Hg0 oxidation were investigated using a link tooth wheel-cylinder reactor energized by di erent high voltage power supplies. Negative DC discharge induced more ozone production and a higher Hg0 oxidation e ciency than positive DC discharge and 12 kHz AC discharge. The discharge tooth wheel number had almost no e ect on the maximum Hg0 oxidation e ciency. The allowable supplied voltage decreased with the increase of discharge tooth wheel number. CO2 could stabilize the discharge process and increase the maximum voltage for a stable discharge. It has also been found that NO consumed O3 induced by high voltage discharge, thereby decreased Hg0 oxidation e ciency; while SO2 had a slight promoting e ect on Hg0 oxidation.     

脉冲放电处理苯酚废水降解过程的分析

由于水中脉冲放电产生等离子体通道,水会发生复杂的等离子体化学反应,产生各种自由基,本文检测到放电形成的羟基自由基.对苯酚废水进行放电降解研究,利用紫外分光计、有机碳分析仪、液相质谱联用仪和气相质谱仪等仪器对降解产物进行检验.结果表明,苯酚废水在放电作用下生成的中间产物为:多羟基苯酚、酮、醛和酯等,最终产物为二氧化碳和水.此结果对苯酚废水在脉冲放电,甚至直流或交流电下的苯酚降解机理的进一步研究有参考价值.     

三种与地质灾害相关的突发性气象灾害应急预报系统研究新进展

本文介绍了在火山灰、核放射性物质和强沙尘暴引发的沙尘粒子的长距离输送数值模拟领域里近年来获得的有关新进展。其基本进展是:1)引进美国NOAA空气资源研究所的HYSPLIT-4模式。并以此为核心形成火山灰、核放射性物质和强沙尘暴的浓度与轨迹数值模拟与预报系统。2)提出一个非连续性空间分布污染场的平流输送方案。3)新发现一个数值模式中的误差污染机制。     

Hilbert C~*-模上广义g-框架的不相交性

主要研究了Hilbert C*-模上广义g-框架的不相交性.通过分析算子得到了强不相交性、不相交性及弱不相交性的有关结论.     

高压脉冲放电技术对地表水消毒杀菌的应用研究

文章提出利用高压脉冲放电技术对饮用水源地的地表水进行消毒杀菌。介绍了高压脉冲放电的工作原理,分析了高压脉冲放电技术应用于饮用水源地的地表水消毒的作用机理,总结了大肠杆菌杀灭效果随放电电极极间距离的变化规律。实验结果表明,高压脉冲放电技术对于细菌特别是大肠杆菌的杀灭率相当高,可达95％以上。     

多针-水膜电极电晕放电脱硫研究

采用不锈钢多针作为高压电极系统,水膜为低压电极.负直流高压电源供电,含二氧化硫(SO2)的污染气体从高压电极系统的轴向进入,沿着电晕放电电场从水膜上方通过,在电晕放电等离子体和水吸收共同作用下,生成硫酸使SO2得到脱除.主要研究了放电电压、气体中SO2初始浓度和气体在电极系统的停留时间对脱硫效果的影响,并测试了水中SO32-和SI42-离子浓度,分析SO2脱除机制.结果表明,电晕放电和水吸收对SO2脱除具有很好的协同作用,脱硫效果明显升高,SO2转变生成硫酸量的体积分数提高;脱硫效果随电压增加和停留时间的增加而增加,初始浓度对脱硫效果有影响.当SO2初始浓度(体积分数)为430×10-6,施加电压为14.5 kV,停留时间为7.5 s时,脱硫效率达90%以上.     

Treatment of simulated wastewater containing Reactive Red 195 by zero-valent iron/activated carbon combined with microwave discharge electrodeless lamp/sodium hypochlorite

A comparative study of treatment of simulated wastewater containing Reactive Red 195 using zero-valent iron/activated carbon (ZVI/AC), microwave discharge electrodeless lamp/sodium hypochlorite (MDEL/NaClO) and the combination of ZVI/ACMDEL/ NaClO was conducted. The preliminary results showed the two steps method of ZVI/AC-MDEL/NaClO had much higher degradation e ciency than both single steps. The final color removal percentage was nearly up to 100% and the chemical oxygen demand reduction percentage was up to approximately 82%. The e ects of operational parameters, including initial pH value of simulated wastewater, ZVI/AC ratio and particle size of ZVI were also investigated. In addition, from the discussion of synergistic e ect between ZVI/AC and MEDL/NaClO, we found that in the ZVI/AC-MEDL/NaClO process, ZVI/AC could break the azo bond firstly and then MEDL/NaClO degraded the aromatic amine products e ectively. Reversing the order would reduce the degradation e ciency.     

介质阻挡放电等离子体对亚甲基蓝的降解

研究了介质阻挡放电等离子体降解亚甲基蓝溶液过程。考察了放电电压、亚甲基蓝溶液初始浓度、初始pH值对降解率的影响和降解过程中亚甲基蓝溶液pH值的变化。结果表明:100mg/L的亚甲基蓝溶液在放电频率为10.5kHz,电压为22kV,pH值为5.68的实验条件下,降解40min后,亚甲基蓝降解率为99.8%。对降解产物进行气质联用分析,亚甲基蓝降解产物中存在甲苯、乙烷基环戊烷、苯并噻唑等物质。     

静电除尘器极板涂敷导电防腐涂料对静电除尘性能影响的研究

为了改善静电除尘器极板防腐性能、增加极板的抗污性能和提高极板清灰效果,用导电防腐涂料涂敷电除尘器极板.提出了涂层比电阻特性数学模型并用实验加以验证.推导了极板沉积粉尘层积累电荷量公式,表明电荷量多少与粉尘层放电时间常数成正比.理论研究结果表明,涂加涂层后,极板上低比电阻粉尘层放电时间常数增大,粉尘层积累电荷量增多,粉尘层与极板问静电附着力增大,有效减弱了粉尘的二次飞扬现象;通过降低涂层的比电阻和涂层厚度,使中高比电阻粉尘层的积累电荷量增加不大.实验测试了涂层对不同比电阻粉尘收尘效率的影响及涂层对极板粉尘剥离率的改善.实验结果显示,涂加涂层后,低比电阻粉尘的收集效率有显著提高,中高比电阻粉尘的收集效率变化不大;极板粉尘剥离率较不加涂层时有很大提高.极板涂敷技术有效延长了极板的使用寿命,在保证除尘效率的前提下提高了极板的清灰效果,是电除尘领域中的一项创新.     

半干式电晕放电烟气脱硫脱硝技术研究

提出了一种新的半干式电晕放电烟气脱硫脱硝方法,将含有SO2和NOX的高温烟气引入喷雾干燥塔增湿降温,然后引入电晕放电烟气净化器,施加高电压,并加入氨气,氨与电晕放电协同作用,将SO2和NOX转化为铵盐颗粒,并从烟气中分离出来,收集在极板(管)上,用水冲洗极板上的产物。将产物溶液喷入喷雾干燥塔,雾滴蒸发干燥形成较大的铵盐颗粒,加以回收,同时使烟气增湿降温。