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101.
Zongcheng Zhan Xiaojun Liu Dongzhu Ma Liyun Song Jinzhou Li Hong He Hongxing Dai 《Frontiers of Environmental Science & Engineering》2014,8(4):483-495
A novel Ultrasonic Assisted Membrane Reduction (UAMR)-hydrothermal method was used to prepare flower-like Pt/CeO2 catalysts. The texture, physical/chemical properties, and reducibility of the flower-like Pt/CeO2 catalysts were characterized by X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM), Transmission Electron Microscope (TEM), N2 adsorption, and hydrogen temperature programmed reduction (HE-TPR) techniques. The catalytic performance of the catalysts for treating automobile emission was studied relative to samples prepared by the conventional wetness impregnation method. The Pt/CeO2 catalysts fabricated by this novel method showed high specific surface area and metal dispersion, excellent three-way catalytic activity, and good thermal stability. The strong interaction between the Pt nanoparticles and CeO2 improved the thermal stability. The Ce4+ ions were incorporated into the surfactant chains and the Pt nanoparticles were stabilized through an exchange reaction of the surface hydroxyl groups. The SEM results demonstrated that the Pt/CeO2 catalysts had a typical three-dimensional (3D) hierarchical porous struc- ture, which was favorable for surface reaction and enhanced the exposure degree of the Pt nanoparticles. In brief, the flower-like Pt/CeO2 catalysts prepared by UAMR-hydrothermal method exhibited a higher Pt metal dispersion, smaller particle size, better three-way catalytic activity, and improved thermal stability versus conven- tional materials. 相似文献
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通过多壁碳纳米管-Nafion复合膜修饰电极,建立水样中痕量铅、镉、铜、锌同时测定的线性扫描溶出伏安分析法,优化支持电解质及pH值、修饰剂用量、富集电位及时间等测定条件。实验结果表明,在pH 4.0的NaAc-HAc缓冲液中,-1.20V富集5min后,在电位-1.04V、-0.72V、-0.45V及-0.16V附近分别产生锌、镉、铅、铜的灵敏溶出峰,测定各元素的线性关系良好,相对标准偏差均小于5.4%。该法已成功应用于实际水样中痕量铅、镉、铜、锌的同时测定,加标回收率在93.3%~106.7%之间,结果满意。 相似文献
104.
Pure and Mg-doped self-assembled ZnO nano-particles for the enhanced photocatalytic degradation of 4-chlorophenol 总被引:1,自引:0,他引:1
N. Clament Sagaya Selvam S. Narayanan L. John Kennedy J. Judith Vijaya 《环境科学学报(英文版)》2013,25(10):2157-2167
A novel self-assembled pure and Mg doped ZnO nano-particles (NPs) were successfully synthesized by a simple low temperature co-precipitation method. The prepared photocatalysts were characterized by X-ray diffraction, high resolution scanning electron mi- croscopy, high resolution transmission electron microscopy, diffuse reflectance spectroscopy and photoluminescence (PL) spectroscopy. The results indicated that the prepared photocatalysts showed high crystallinity with a uniform size distribution of the NPs. The degradation of cholorphenols is highly mandatory in today's scenario as they are affecting the environment adversely. Thus, the photocatalytic degradation of 4-chlorophenol (4-CP), a potent endocrine disrupting chemical in aqueous medium was investigated by both pure and Mg-doped ZnO NPs under UV-light irradiation in the present study. The influence of the Mg content on the structure, morphology, PL character and photocatalytic activity of ZnO NPs were investigated systematically. Furthermore,the effect of different parameters such as 4-CP concentration, photocatalyst amount, pH and UV-light wavelength on the resulting photocatalytic activity was investigated. 相似文献
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针对典型油气管道焊缝事故案例,基于管道断口特征和现场痕迹,推断管道轴向承载和环焊缝开裂失效过程,是揭示管道环焊缝失效机理的途径之一。本文以某X70管道环焊缝开裂事故为例,根据管道断口碰撞痕迹,采用有限元仿真分析方法,通过反演推算方式研究了管道开裂后的运动碰撞过程,确定了管道开裂前的轴向承载情况。结果表明:管道环焊缝位置断裂前的轴向应力范围约为590~640 MPa,此时环焊缝的轴向应力已超过管道自身的屈服强度。该研究为事故管道轴向承载评估提供了一种估算方法。 相似文献
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《中国环境管理干部学院学报》2010,(2):93-93
北方严寒或是全球变冷开端
美国国家冰雪数据中心数据显示,2007年以来全球夏季海冰增加了49.7万平方英里,升幅为26%,这意味着海洋在向“冷化”模式迈进。近期横扫北半球严寒气候可能只是一个可能持续20~30年的全球气候变冷趋势的开端而已。 相似文献
110.
作为一种标准的地下水污染原位修复技术,限制零价铁渗透反应格栅技术(ZVI PRB)在地下水污染修复中广泛应用的一个关键瓶颈就是ZVI表面的钝化问题.本文通过批实验,研究了反硝化细菌(DNBE)存在下ZVI表面氧化膜的变化.通过研究发现,DNBE的存在对ZVI表面成分和形态结构会产生影响,进而影响其反应活性,加速其钝化过程. 相似文献